• 제목/요약/키워드: Chloride Ion

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콘크리트 침투성 표면보호재의 자기세정 및 내구특성 (Self Cleaning and Durability of Silicate Impregnant of Concrete)

  • 송훈;추용식;이종규
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2008년도 추계 학술발표회 제20권2호
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    • pp.433-436
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    • 2008
  • Silicate계 표면보호재는 Sodium silicate 혹은 Lithium 및 Potassium silicate를 주성분으로 하는 수용액이며 탄산화한 부분의 알칼리 부여와 성능저하가 예상되는 부위의 강화 등 콘크리트 성능회복에 주로 이용된다. Silicate계는 콘크리트에의 침투성을 향상시키기 위해 계면활성제나 콘크리트 중의 Calcium hydroxide와의 반응을 개선하기 위한 반응촉진제, 경화제 등이 첨가된다. Sodium silicate계는 습윤 바탕에 적용하며 Lithium silicate계는 건조바탕에 도포하여 양생을 실시하는 것이 일반적이다. 콘크리트 구조물 외관의 손상없이 비교적 간편하게 시공할 수 있으며 미세기공을 완전하게 메우지 않으므로 콘크리트 본래의 호흡성을 손상하지 않는다. 본 연구에서는 콘크리트 침투성 표면보호재로서 가격이나 시공성에서 우수한 Lithium 및 Potassium silicate를 이용하여 부유 오염원 제거를 위한 친수성 표면형성과 상온경화가 가능한 표면보호재를 제조하였으며, 제조된 표면보호재의 탄산화 저항성 및 Cl- 침투저항성, 동결융해 저항성 등의 내구성능에 대해 검토하고자 한다.

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프리믹스 혼합시멘트를 사용한 콘크리트의 품질편차에 관한 연구 (An Experimental Study on the Quality Deviation of Concrete Using Premixed Cement and Non-Premixed Cement)

  • 배준영;김종백;조성현;노현승;김정환;박승범
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2008년도 추계 학술발표회 제20권2호
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    • pp.569-572
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    • 2008
  • 본 연구에서는 시멘트와 광물질 혼화재인 고로슬래그미분말과 플라이애시를 미리 혼합한 프리믹스 혼합시멘트와 이들 재료를 각각 투입하여 제작한 콘크리트에 대하여 보통강도 및 고강도 영역에서의 압축강도와 염화물 확산계수를 측정하고 각각에 대한 품질편차를 검토하였다. 검토 결과 프리믹스 혼합시멘트를 사용한 콘크리트가 재료를 각각 투입하여 제조한 콘크리트에 비하여 보통강도 및 고강도 영역 모두에서 압축강도 평균값은 증가하고 표준편차는 감소하는 것으로 나타났으며, 염화물 확산계수의 경우 평균값과 표준편차가 모두 감소하는 경향을 나타냈다. 향후 고강도 영역에서의 압축강도 변동폭 및 보통강도 영역에서의 내구성 변동폭을 감소시키기 위해 프리믹스 혼합시멘트를 사용하는 것이 바람직한 것으로 판단된다.

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Self-cleaning 침투성 함침제의 적용에 따른 타일 및 콘크리트 표층부의 개질특성 (Reforming Property of Tile and Concrete Surface layer Using Self-cleaning Concrete Impregnant)

  • 송훈;전찬수;김영호
    • 한국디지털건축인테리어학회논문집
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    • 제13권4호
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    • pp.61-68
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    • 2013
  • Concrete structure is not the only material vulnerable to physical and chemical processes of deterioration associates with severe conditions. Deterioration of the concrete structure, however, occurs more progressively from the outside of the concrete exposed to severe conditions. Especially, Carbonation, chloride ion attack is more important factor of concrete durability. This study is interested in manufacturing the self-cleaning concrete surface impregnant including TEOS, lithium silicate for the repair of the exposed concrete surface and the color concrete requiring the advanced function in view of the concrete appearance. Form the results, TEOS and lithium silicate are very effective that increasing the concrete durability using self-cleaning concrete impregnant. Self-cleaning concrete impregnant specimens is satisfied with performance requirement of KS standard in adhesion test in tension but the reinforcement of concrete substrate is slight. So, the self-cleaning concrete impregnant of this study is more desirable for the improvement of durability rather than the reinforcement.

Fibrinolytic Enzyme Production by Bacillus subtilis KH-4 Isolated from Deonjang

  • Kim, J.M.;Suh, H.J.;Ahn, S.W.;Kim, M.S.;Oh, S.H.
    • Preventive Nutrition and Food Science
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    • 제7권4호
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    • pp.417-420
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    • 2002
  • A strong fibrin-specific fibrinolytic enzyme was produced from Bacillus subtilis KH-4 isolated from Deonjang, a Korean fermented soybean paste similar to Japanese miso. The addition of glucose as a carbon source resulted in the highest levels of caseinolytic and fibrinolytic activities. Likewise, the addition of yeast extract as the nitrogen source resulted in the highest caseinolytic and fibrinolytic activities (3473.2 unit and 47.4 munit, respectively), It was observed that out of all metal ion sources only calcium (chloride) enhanced caseinolytic and fibrinolytic activities, with increases of 4949.3 unit and 58.2 unit/mg, respectively. The optimal temperature for the production of the enzyme was found to be 4$0^{\circ}C$ in the optimal medium (glucose 20 g, yeast extract 5 g, CaCl$_2$l g, and NaCl 2 g). The maximum fibrinolytic activity was observed at the late stationary phase. B. subtilis KH-4 produced a fibrinolytic enzyme at 4$0^{\circ}C$, after 30 h growth, which increased up to 54 h and then remained constant. These results suggest that Deonjang has potential as a source of physiologically active anti-thromotic enzymes.

Ion dependent cellular uptake of taurine in mouse osteoblast cell lines

  • Naomi Ishido;Emi Nakashima;Kang, Young-Sook
    • 한국응용약물학회:학술대회논문집
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    • 한국응용약물학회 2003년도 Annual Meeting of KSAP : International Symposium on Pharmaceutical and Biomedical Sciences on Obesity
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    • pp.109-109
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    • 2003
  • Taurine is present in a variety of tissue and exhibits many important physiological functions in many tissues. Although it is known that many tissues mediate taurine transport, its functions of taurine transport in bone have not been identified yet. In the present study, we investigated the expression of taurine transporter (TauT) and taurine uptake using mouse stromal ST2 cells and osteoblast-like MC3T3-El cells, which is bone related cells. Detection of TauT mRNA expression in these cells were performed by reverse transcription polymerase chain reaction (RT-PCR). The activity of TauT was assessed by measuring the uptake of [$^3$H]taurine in the presence or absence of inhibitors. TauT mRNA was detected in these cells. [$^3$H]Taurine uptake was dependent upon the presence of extracellular sodium, chloride and calcium ions, and inhibited by cold-taurine and ${\beta}$-alanine. These results suggest that taurine has biological functions in bone and some effect on the bone cells.

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질소종류 ならび 질소시비량の 상위が 생육 , 생리 , 수량병びに 각 엑끼스 ( エキス ) , Ligustilide , Butylidene phthalide 함량に급ぼす영향 (Effect of various kind and amount of nitrogen fertilizers on the Plant growth , physiological , yield and extracts .ligustilide, butylidene phthalie contents of crude drug 'Tou-Ki' (Angelica acutiloba Kitagawa))

  • 홍리앙
    • 한국자원식물학회지
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    • 제5권1호
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    • pp.57-68
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    • 1992
  • The effects of various kind and amount of nitrogen fertilizers on the plant grorth. physiological , yield and extracts. ligustilide, butylidene phthalide contents of curdsdrug "Tou-ki" (AnTelica acutiloba Kitagawa) were investigated in 1989. Five plots variouskind of nitrogen fertilizers. Namely, no nitrogen, urea. ammonium nitrate, ammoniumchloride and control plot of ammonium sulfate. The other, by providing five plotsdifferent composed ratio of nitrogenous fertilizers. containing no nitrogen (No. o) .0.5-fold nitrogen (No s), control plot of 1.0-fold nitrogen(Nl.o). 1.5-fold nitrogen(Nl s)and 2.0-fold nitrogen Na. o), but nitogen was used the ammonium sulfate. The results showedthat the crude drug "Tou-ki" can ammonium chloride be produced in good yield, displayingboth good plant growth and remarkable physiologically-active conditions, and it can beproduced such that the extracts is maximized. Additionally, using methods of gaschromatography (GC) , it was established that ligustilide and butylidene phthalide, majorcomponents in the crude drug was recovered in a good yield from the fully grown plants.The other, the plant growth, the physiologically-active, the weight of whole plant, theyield of extracts and ligustilide, butylidene phthalide were seen to be best at the plotof 2.0-fold nitrogen and according to the increase or decrease of nitrogen decreasedgradually. Therefore. about 2 fold of standard quantity seems to be the most suitablequantity of nitrogen for "Tou-ki" cultivation .uot;Tou-ki" cultivation .ion .

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Semi-pilot Study of Electrokinetic Process for Phenanthrene Removal from Kaolinite

  • Lee, You-Jin;Park, Ji-Yeon;Kim, Sang-Joon;Lee, Young-Cheol;Yang, Ji-Won
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2004년도 임시총회 및 추계학술발표회
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    • pp.215-218
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    • 2004
  • The electrokinetically enhanced soil flushing had a great potential to improve the removal efficiency of polycyclic aromatic hydrocarbons (PAHs) from low permeable soils. A semi-pilot study of surfactant-enhanced electrokinetic process was investigated for the removal of phenanthrene from kaolinite. A nonionic surfactant, Tergitol 15-S-12 at 10 g/L was introduced as a flushing agent and 0.001M of sodium chloride was used as an electrolyte. When the constant voltage of 100 V was applied to the system for 25 days, only 0.66 kWh of electric power was consumed and the amount of electroosmotic flow was 6.9 L. The removal efficiency of phenanthrene was about 40 % and it can be improved by increasing the ion concentration of the flushing solution or the applied voltage.

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Purification and Characterization of A Cell Wall Hydrolyzing Enzyme Produced by An Alkalophilic Bacillus sp. BL-29

  • Hong, Soon-Duck;Kim, Tae-Ho;Hong, Soon-Duck
    • Journal of Microbiology and Biotechnology
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    • 제5권4호
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    • pp.206-212
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    • 1995
  • A strain BL-29, which produces a extracellular lytic enzyme on E. coli was isolated from the soil. The strain was identified as belonging to the genus Bacillus sp. The lytic enzyme was purified to homogeneity by ion exchange chromatography and gel filtration. Specific activity of the purified enzyme was 28, 850 U/mg protein and yield of the enzyme was 5$%$. The purified enzyme showed a single band on SDS-PAGE and its molecular weight was estimated to be 31, 000 by SDS-polyacrylamide gel electrophoresis and gel filtration column chromatography. The optimum temperature and pH were $55^{\circ}C$ and pH 10.0, respectively. The enzyme was stable at $45^{\circ}C$ but enzyme activity was reduced by up to 50$%$ when the temperature was raised to $55^{\circ}C$ for 15 min. Stable range of pH was from 5.0 to 11.0. but Enzyme activity was inhibited by lead-acetate, mercuric chloride, ethylene glycol-bis-[$\beta$-aminoethyl ether]-N, N, $N^1, $N^1$-tetraacetic acid (EGTA), and ethylenediamine tetraacetic acid (EDTA), but not affected considerably by treatment with other chemical reagents.

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430 스테인리스강의 틈부식 발생기구에 대한 연구 (A Study on the Mechanism of Crevice Corrosion for 430 Stainless Steel)

  • 백신영;나은영
    • Journal of Advanced Marine Engineering and Technology
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    • 제27권3호
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    • pp.447-452
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    • 2003
  • Crevice corrosion is localized form of corrosion usually associated with a stagnant solution on the micro-environmental level. Such stagnant micro environments tend to occur in crevices (shielded areas) such as those formed under gaskets washers insulation material. fastener heads. surface deposits. disbonded coatings. threads. lap joints and clamps. Crevice corrosion is initiated by changes in located electrochemical reaction within the crevice such as a) depletion of inhibitor in the crevice b) depletion of oxygen in the crevice c) a shift to acid conditions in the crevice and d) build-up of aggressive ion species (e.g chloride) in the crevice. In this study. the mechanism of crevice corrosion for Type 430 stainless steel is investigated undercondition that the size of specimen is $15{\times}20\{times}3mm$, in 1N $H_2SO_4$ + 0.05N NaCl solution. and the artificial crevice gap size of 3 x 0.2 x 15 mm. Crevice corrosion is measured under applied potential -300mV(SCE) to the external surface. The obtained result of this study showed that 1) the induced time for initiation of crevice is 750 seconds. 2) potential of the crevice was about from -320mV to -399mV. which is lower than that of external surface potential of -300mV It is considered that potential drop in the crevice is one of mechanisms for the crevice corrosion

La(III) Selective Membrane Sensor Based on a New N-N Schiff's Base

  • Ganjali, Mohammad Reza;Matloobi, Parisa;Ghorbani, Maryam;Norouzi, Parviz;Salavati-Niasari, Masoud
    • Bulletin of the Korean Chemical Society
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    • 제26권1호
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    • pp.38-42
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    • 2005
  • Bis(2-methylbenzaldehyde)butane-2,3-dihydrazone(TDSB) was used as new N-N Schiff's base which plays the role of an excellent ion carrier in the construction of a La(III) membrane sensor. The best performance was obtained with a membrane containing, 30% poly(vinyl chloride), 60% benzyl acetate, 6% TDSB and 4% sodium tetraphenyl borate. This sensor reveals a very good selectivity towards La(III) ions over a wide variety of cations, including alkali, alkaline earth, transition and heavy metal ions. The proposed electrode exhibits a Nernstian behavior (with slope of 19.8 mV per decade) over a wide concentration range (1.0 ${\times}$ 10$^{-5}$-1.0 ${\times}$ 10$^{-1}$ M). The detection limit of the sensor is 7.0 ${\times}$ 10$^{-6}$ M. It has a very short response time, in the whole concentration range ($\sim$5 s), and can be used for at least twelve weeks in the pH range of 3.0-9.4. The proposed sensor was successfully applied as an indicator electrode for the potentiometric titration of a La(III) solution, with EDTA. It was also successfully applied in the determination of fluoride ions in three mouth wash preparations.