• Title/Summary/Keyword: Chloride

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Investigation on Electrochemical Characteristics of Battery Housing Material for Electric Vehicles in Solution Simulating an Acid Rain Environment with Chloride Concentrations (산성비 환경을 모사한 수용액에서 염화물 농도에 따른 전기자동차 배터리 하우징용 재료의 전기화학적 특성 연구)

  • Shin, Dong-Ho;Kim, Seong-Jong
    • Corrosion Science and Technology
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    • v.21 no.2
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    • pp.147-157
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    • 2022
  • Electrochemical characteristics and damage behavior of 6061-T6 aluminum alloy used as a battery housing material for electric vehicles were investigated in solution simulating the acid rain environment with chloride concentrations. Potentiodynamic polarization test was performed to analyze electrochemical characteristics. Damage behavior was analyzed through Tafel analysis, measurement of damage area, weight loss, and surface observation. Results described that corrosion current density was increased rapidly when chloride concentration excceded 600 PPM, and it was increased about 7.7 times in the case of 1000 PPM compared with 0 PPM. Potentiodynamic polarization experiment revealed that corrosion damage area and mass loss of specimen increased with chloride concentrations. When chloride concentration was further increased, the corrosion damage area extended to the entire surface. To determine damage tendency of pitting corrosion according to chloride concentration, the ratio of damage depth to width was calculated. It was found that the damage tendency decreased with chloride concentrations. Thus, 6061-T6 aluminum alloy damage becomes larger in the width direction than in the depth direction when a small amount of chloride is contained in an acid rain environment.

Service Life Variation Considering Increasing Initial Chloride Content and Characteristics of Mix Proportions and Design Parameters (초기 염화물량의 증가와 배합 및 설계 변수 특성을 고려한 콘크리트 내구수명의 변동성)

  • Park, Sun-Kyung;Kwon, Seung-Jun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.3
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    • pp.236-245
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    • 2021
  • It is very important for structure designer to understand the service life variation since a wide range of service life is evaluated with changing exposure conditions and design parameters. Recently, for zero-carbon, waste plastic has been used for fuel for clinker production and this yields increase in chloride content in cement. This study is for evaluation of changing service life in the concrete with increasing initial chloride content due to usage of plastic-SRF(Solid Refuse Fuel) considering various exposure conditions and design parameters. For this, 4 levels of initial chloride content were assumed, and the service life was assessed using LIFE 365 program considering various environmental conditions including 3 levels of surface chloride content. As for analysis parameters, critical/initial chloride content, blast furnace slag powder replacement ratio, W/B(Water to Binder) ratio, cover depth, and unit mass for binder are adopted. Service life decreases with increasing initial chloride content and a significant reduction of service life is not evaluated permitting up to 1,000ppm of initial chloride content. With increasing slag replacement ratio, a longer service life can be secured since blast furnace slag powder has the effect of reducing the diffusion of external chloride ions and fixing the free chloride. It is thought that increasing initial chloride content up to European standard is helpful for enhancing sustainability and reducing carbon emission. Though the reduction in service life due to an increase in the initial chloride content is not significant in slag-concrete with low surface chloride content, careful consideration for mixing design should be paid for the exposure environment with high surface chloride content.

Changes of Chemical Components During the Storage of Fresh Red Pepper Homogenates (파쇄(破碎) 생(生)고추의 밀봉(密封) 저장중(貯藏中) 품질(品質) 성분(成分)의 변화(變化))

  • Lee, Gye Hee;Oh, Man Jin
    • Korean Journal of Agricultural Science
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    • v.13 no.1
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    • pp.130-138
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    • 1986
  • In order to obtain the basic data for development of raw pepper homogenates as instant spice, effects of preservatives, packaging materials, storage temperature and period on chemical components of raw pepper homogenates were investigated during storage after sealing up. The results are as follows: 1. Raw pepper homogenates added 15% sodium chloride was effective prominently than raw pepper homogenates on residual contents of acidity, capsanthin and capsaicin. 2. P. V. D. C film was effective than P. E film in sealing of raw pepper homogenates. 3. Decomposition of capsanthin was exceeded at high temperature during the sealed storage of raw pepper homogenates and decomposition of capsaicin was accelerated at initial stage of storage and also it was decreased prominently by adding of sodium chloride. 4. Decomposition of vitamin C during the storage was exceeded at high temperature and it was prominently suppressed by adding of sodium chloride. 5. Increase of total viable cell count and lactic acid bacteia count was prominently suppressed by adding of sodium chloride and its difference for storage temperature was disregarded.

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Effect of Browning Inhibitors on Quality Property of Fresh-Cut Strawberries (갈변억제제 처리가 신선 절단 딸기의 품질 특성에 미치는 영향)

  • Chung, Hun-Sik;Moon, Kwang-Deog
    • Food Science and Preservation
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    • v.19 no.1
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    • pp.26-30
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    • 2012
  • The effect of browning inhibitors on quality properties of fresh-cut strawberries was investigated. Half-cut strawberries were treated with dipping solutions alone and with combinations of 1% ascorbic acid, 1% citric acid, 1% sodium chloride, and 1% magnesium chloride, were packaged with low density polyethylene bags, and were kept for 24 hours at $4^{\circ}C$. The levels of oxygen and carbon dioxide in the packages of the samples treated with the combined solutions were the highest and the lowest, respectively. The loss of L value and flesh firmness of fresh-cut strawberries was retarded by the combined solutions than by the dipping solutions alone. The soluble solids and pH were not affected by the browning inhibitor. These results suggest that mixture of ascorbic acid, citric acid, sodium chloride, magnesium chloride may prevent browning and softening of fresh-cut strawberries.

Analysis Technique for Chloride Penetration in High Performance Concrete Behavior Considering Time-Dependent Accelerated Chloride Diffusivity (촉진염화물 확산계수의 시간의존성을 고려한 고성능 콘크리트의 염화물 침투 해석기법)

  • Kwon, Seung-Jun;Park, Sun-Gyu
    • Journal of the Korea Concrete Institute
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    • v.25 no.2
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    • pp.145-153
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    • 2013
  • Recently, accelerated chloride diffusion coefficients are used for an evaluation of chloride behavior. Similar as apparent diffusion coefficients, accelerated diffusion coefficients decrease with time. In this study, decrease in diffusion coefficient with time is simulated with porosity. Utilizing DUCOM-program, porosities from 15 mix proportions are obtained and diffusion coefficients are modelled with regression analysis of porosity for 270 days. Considering non-linear binding capacity which means the relation between free and bound chloride ion, chloride behavior in high performance concrete is evaluated. Through utilizing the previous test results for concrete under chlorides for 180 days, the applicability of the proposed technique is verified. The proposed technique is evaluated to reasonably predict the chloride behavior in concrete with various w/c (water to cement) ratios and mineral admixtures (GGBFS and FA). It is also shown that decrease in chloride diffusion should be considered for chloride prediction in concrete with mineral admixture since it has very clear decrease in diffusivity with time.

A Study on the Chloride ion Penetration Characteristic of Concrete containing Ground Granulated Blast Furnace Slag (고로슬래그미분말 치환 콘크리트의 염화물 침투특성에 관한 연구)

  • 김현수;지남용
    • Proceedings of the Korea Concrete Institute Conference
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    • 2001.05a
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    • pp.997-1002
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    • 2001
  • There are two types of chloride in concrete; one is added as concrete materials' chloride when concrete's mixing, and .the other is penetrated from the air and sea water in the sea-shore area. These chlorides penetrate into concrete, and they are accumulated inside the concrete with aging. This study aimed to evaluate the chloride ion penetration resistance of concrete containing GGBFS in the sea-shore area. Therefore, the specimens made with the replacement ratios(0, 0.30, 0.45, 0.60) of GGBFS were put into 3% NaCl solution according to the chloride accelerating test of JCI-SC3, and then investigated the weight changes, compressive strength, chloride ion with the depths of the specimens by aging. The result is that the diffusion coefficient of chloride ion is decreased with the increase of replacement ratios when compared to OPC

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A Study on the Comparative Analysis of Chloride Penetration Durability Design Program of Reinforced Concrete Structures. (RC구조물 염해 내구성 설계 평가 프로그램 문헌 비교연구)

  • Lee, Hyung-Min;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2012.11a
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    • pp.259-260
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    • 2012
  • As RC structures in the marine environment rapidly increase, the interest and the importance of Chloride Penetration durable design have been growing. However, there is hardly any domestic Chloride Penetration durability of RC structures designed analysis programs. Currently, Chloride Penetration durable design method is studied and launched actively as a program in the United States, Europe, Japan and etc., but it is limited to Chloride Penetration durability of RC structures excluded from maintenance construction. Also, the level of dependence on the foreign technology is high; the foreign program is imported and used when needed. The main objective is to compare and to evaluate with the durability assessment program and several conditions when considering the design of Chloride Penetration durability through the programs developed abroad.

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A Study for the Calculation of the Surface Chloride on the concrete by using Colorimetric method (비색판별법을 이용한 콘크리트의 표면염화물량 산정)

  • 이진우;이문환;서치호
    • Proceedings of the Korea Concrete Institute Conference
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    • 2001.11a
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    • pp.815-820
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    • 2001
  • This study is to set a new standard for using of the colorimetric method through grasping the character of the colorimetric method, and measuring the chloride concentration at the place of the change of color. Also, to predict chloride concentration around rebar and time reaching limit chloride concentration through measuring the chloride concentration of concrete surface by the colorimetric method and this study presents the new program of concrete degradation and diagnosis of the durability by salt damage. First the use of the colorimetric method was examinated, second the chloride concentration through slicing concrete submerged in artificial seawater for 6 months was measured. And the chloride concentration at the place of the change of color was calculated by using colorimetric method. Finally, the cloride concentration of the concrete surface was calculated.

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An Evaluation of Reinforced Concrete Durability in Chloride Attack Environment under Sustained Load (염해 환경하에서 지속하중을 받는 철근콘크리트 부재의 내구성 평가)

  • Hong, Jun-Seo;Im, Chang-Hun;Yoon, Sang-Chun;Jee, Nam-Yong
    • Proceedings of the Korea Concrete Institute Conference
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    • 2001.11a
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    • pp.1045-1050
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    • 2001
  • This study was performed to evaluate reinforced concrete durability in chloride attack environment under sustained load by the corrosion of reinforcing bars and the permeation of chloride ion. Generally, it is regarded that permeability of chloride ion is determined by the properties of concrete, but the effects of load which make alternation of concrete inner structure such as crack and so on should not neglected. In this study, it is shown that the relation between bending load on RC beam, deflection and crack of specimen, permeation of chloride ion, rating of re-bar corrosion, and the relation between compression load and permeation of chloride ion. Therefore the effects of load on permeation of chloride ion and re-bar corrosion are evaluated.

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Behavior of Chloride Binding in Hardened Cement Pastes (Forcused on $C_3A$ content) (시멘트 경화체내 염화물의 고정화 성상 ($C_3A$ 함유량을 중심으로))

  • 임순지;소형석;소승영;박홍신;소양섭
    • Proceedings of the Korea Concrete Institute Conference
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    • 1994.10a
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    • pp.87-92
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    • 1994
  • The main objective of this study is to determine the critical chloride ion concentrations in the pore solutions causing depassivation of steel reinforcement in concrete made with cements of different $C_3A$ contents. Cement pastes with water-ratio of 0.5 were prepared using four cements with $C_3A$ contents of 0.46, 5.97, 9.14, and 9.65 percent. The pastes were allowed to hydrate in sealed containers for 28days and then objected to pore solution expression. The expressed pore fluids were analyzed for chloride and hydroxyl ion concentrations. It was found that the free cholride concentration in the pore solution decreases significantly with an increase in the $C_3A$ content of the cement. With increasing level of chloride addition, although the alsolute amount of bound chloride increase, the ratio of bound to total chlorides decreases.

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