• Journal of the Korean Society of Safety
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• v.7 no.4
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• pp.23-32
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• 1992

Surface treatment and chemiluminescence characteristics of the polymer film. It was studied that the Intensities and rates of treatments are in proportional to condition of the treatment, considering the results of study on treatments to polymer film with discharge and ultraviolet irradiation through the methods such as surface resistance, contact angle, dyeing method, solace ten-sion and so on. It was also studied that the said has a nice correlation with the concerned result studied by chemiluminescence. Since the chemiluminescence will enable the Investigators to grasp a eertain condition caused by quitely slight deterioration with high sensitivity, it can be also used as a way for getting an information regarding the decision for degradation-condition and life-estimating of insulation material basically related to some security matters as well as surface condition of treatments through the above method.

• Journal of Mechanical Science and Technology
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• v.18 no.11
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• pp.2058-2065
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• 2004

A light collecting probe named Multi-color Integrated Cassegrain Receiving Optics (MICRO) is applied to spark-ignited spherical spray flames to obtain the flame propagation speed in freely falling droplet suspension produced by an ultrasonic atomizer. Two MICRO probes are used to monitor time-series signals of OH chemiluminescence from two different locations in the flame. By detecting the arrival time difference of the propagating flame front, the flame propagation speed is calculated with a two-point delay-time method. In addition, time-series images of OH chemiluminescence are simultaneously obtained by a high-speed digital CCD camera to ensure the validity of the two-point delay-time method by the MICRO system. Furthermore, the relationship between the spray properties measured by phase Doppler anemometer (PDA) and the flame propagation speed are discussed with three different experimental conditions by changing the fuel injection rate. It was confirmed that the two-point delay-time method with two MICRO probes is useful and convenient to obtain the flame propagation speed and that the flame propagation speed depends on the spray properties.

• Bulletin of the Korean Chemical Society
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• v.23 no.2
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• pp.291-294
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• 2002

The reactions of triplet oxygen atom with halomethanes as a potential fire extinguisher were studied by a discharge flow-chemiluminescence imaging method. The experiments were carried out under second order conditions. The bimolecular atom-molecule reaction rate constants were determined in terms of the initial rate method. The initial concentration of oxygen atom was also determined under second order rate law instead of the pseudo-first order conditions with $[O(^3P)]_0{\ll}[sample]_0$. The second order conditions were more reliable than pseudo-first order conditions for the determinations of rate constants. The rate constants of the reactions $CF_3I\;+\;O(^3P)$, $CH_3PI\;+\'O(^3P)$, and $CHBrCl_2\;+\;O(^3P)$ were determined to be $5.0\;{\times}\;10^{-12}$ , $1.1\;×\;0^{-11}$ , and $1.9\;{\times}\;10^{-14}cm^3molecule^{-1}s^{-1}$, respectively.

• YAKHAK HOEJI
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• v.42 no.6
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• pp.567-571
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• 1998

The phagocytic activity of murine peritoneal macrophage, was determined by lucigenin chemiluminescence and engulfment of fluorescein-conjugated E. coli particle. The acti vity-guided fractionation upon the methylenechloride fraction of Aurantii immaturi pericarpium led to the isolation of a flavonoid, isosinensetin, as a suppressive component of phagocytosis. Isosinensetin suppressed the lucigenin chemiluminescence and the engulfment of fluorescein-conjugated E. coli particles and enhanced the production of nitric oxide in murine peritoneal macrophage.

• Bulletin of the Korean Chemical Society
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• v.25 no.8
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• pp.1202-1206
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• 2004

Novel naphthyl-containing biphenyl analogues were prepared by Suzki reaction for the chemiluminescent blue fluorophores. UV-Vis absorption, photoluminescence, chemiluminescence and CIE chromaticities were measured. The fluorophores displayed blue photoluminescence in solution with a maximum intensity around 378-415 nm. Sodium salicylate-catalyzed reaction of them with bis(2 carbopentyloxy-3,5,6-trichlorophenyl)-oxalate with hydrogen peroxide provided a strong chemiluminescent red light emission with wavelengths of 398-427 nm; these were similar to the photoluminescent spectra. The chemiluminescent intensity decayed exponentially and the glow of chemiluminescence, which was visible with naked eyes, was maintained for more than 4 h.

• Bulletin of the Korean Chemical Society
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• v.11 no.3
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• pp.224-227
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• 1990

The excitation mechanism of polycyclic aromatic amines (amino-PAHs) and polycyclic aromatic hydrocarbons(PAHs) for the chemiluminescence arising from the reaction between oxalate ester, bis(2,4,6-trichlorophenyl)oxalate (TCPO) or bis(2,4-dinitrophenyl)oxalate (DNPO) and hydrogen peroxide has been studied in terms of the excitation efficiencies to singlet excitation energies and the oxidative half-wave potentials. As a results of the study, the excitations of both amino-PAHs and PAHs appear to involve the charge transfer type of energy transfer. However the chemiluminescence efficiency corrected for fluorescence quantum yield of the amino-PAHs are varied more sensitively to the oxidative half-wave potential than that of PAHs possibly due to the large difference in solvation energy between the compounds and their ions.

• Food Science of Animal Resources
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• v.32 no.1
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• pp.98-102
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• 2012

The aim of this study was to investigate the relationship between a simple method for measuring lipid peroxidation by using a chemiluminescence analyzer and traditional methods, such as 2-thiobarbituric acid reactive substances or peroxide value of solid food samples. Freeze-dried egg yolk powder was kept on $25^{\circ}C$, under dark condition. The peroxidation value was measured during certain storage period by using 3 methods, and the chemiluminescence value was compared with 2-thiobarbituric acid reactive substances or peroxide value. For comparison, 3 kinds of freeze-dried egg yolk were prepared from whole eggs purchased from a local market. The chemiluminescence value was significantly correlated with both the peroxide value and the 2-thiobarbituric acid related substances during storage, and showed a high correlation to the real sample test. It showed a little higher correlation with peroxide value. These results suggest that using a chemiluminescence analyzer may provide the ability to measure the lipid peroxidation of high lipid content solid-food samples, instead performing both the 2-thiobarbituric acid reactive substances test and measuring the peroxide value.

• Journal of Photoscience
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• v.9 no.2
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• pp.290-292
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• 2002

The intermediate M420 formed in a solution of firefly luciferin in deoxygenated dimethyl-sulfoxide added potassium f-butoxide was observed to emit yellow-green and red light by filter-photometry. By H-NMR, M420 was found to be deprotonated at the site where luciferin reacts with oxygen.

• Proceedings of the KSME Conference
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• 2005.11a
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• pp.36.2-36.2
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• 2005

• Bulletin of the Korean Chemical Society
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• v.31 no.4
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• pp.1031-1034
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• 2010