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http://dx.doi.org/10.5012/bkcs.2004.25.8.1202

Chemiluminescent Properties of Novel Biphenyl Analogue Blue Fluorophores  

Cheon, Jong-Woo (Department of Chemistry, Dankook University)
Lee, Chil-Won (Department of Chemistry, Dankook University)
Geum, Neri (Department of Chemistry, Dankook University)
Gong, Myoung-Seon (Department of Chemistry, Dankook University)
Publication Information
Bulletin of the Korean Chemical Society / v.25, no.8, 2004 , pp. 1202-1206 More about this Journal
Abstract
Novel naphthyl-containing biphenyl analogues were prepared by Suzki reaction for the chemiluminescent blue fluorophores. UV-Vis absorption, photoluminescence, chemiluminescence and CIE chromaticities were measured. The fluorophores displayed blue photoluminescence in solution with a maximum intensity around 378-415 nm. Sodium salicylate-catalyzed reaction of them with bis(2 carbopentyloxy-3,5,6-trichlorophenyl)-oxalate with hydrogen peroxide provided a strong chemiluminescent red light emission with wavelengths of 398-427 nm; these were similar to the photoluminescent spectra. The chemiluminescent intensity decayed exponentially and the glow of chemiluminescence, which was visible with naked eyes, was maintained for more than 4 h.
Keywords
4,4'-Di(1-naphthyl)biphenyl; 2,7-Di(1-naphthyl)fluorene; 3,6-Di(2-naphthyl)carbazole; Blue fluorophore; Chemiluminescence;
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