• Title/Summary/Keyword: Chemicals Transportation

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Identifying Characteristics of Incidents at Hazardous Material Facilities

  • Kim, Geun-Young;Kim, Sang-Won;Won, Jai-Mu
    • Journal of the Korean Society of Hazard Mitigation
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    • v.9 no.6
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    • pp.51-56
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    • 2009
  • Safety and quality assessment systems are very important in manufacture, storage, transportation, and handling of hazardous materials(hazmat) to prevent hazmat disasters. At present, hazardous materials exist everywhere in our daily lives with various forms of plastics, household products of cleaning and washing detergents, fertilizers or petroleum-related products. However, hazardous materials are dangerous substances when they are released to human or environment. Hazardous materials become very widely used substances in the age of oil-based industrial economy. The Korean Ministry of Environment (KMOE) describes about one hundred thousand types of chemicals are produced and used worldwide. Over four hundred new chemicals are introduced in every year. A crucial question for the Korean hazardous material management may have been raised: Will you be safe from hazardous material incidents? The gas leak disaster at Union Carbide's Bhopal, India in 1984 that made over 6,400 people killed and 30,000 to 40,000 people seriously injured is the representative case for the safety of hazmat. Korea becomes vulnerable to hazmat disaster due to the development of high-tech industry. Thus, the risk assessment system is required to Korea for transferring abandoned hazmat management systems to self-correcting safety systems. This research analyzed characteristics of various hazmat incidents applying statistical analysis methods including frequency analysis or analysis of category data to hazmat incidents for ten years. All of three analyses of category data indicate the significance of causality between hazmat incident site groups and seasons, regional groups, and incident casualty groups.

Thermal and Electrochemical Stability of Morpholinium Ionic Liquids (모폴린계 이온성 액체의 열 및 전기화학적 안정성)

  • Kim, Hyun-Taek;Hong, Yeon Ki;Kang, Jeong Won;Lee, Young-Woo;Kim, Ki-Sub
    • Korean Chemical Engineering Research
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    • v.50 no.4
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    • pp.702-707
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    • 2012
  • During the last few decades, toxic chemicals used in various industries have caused global pollution and the side products such as carbon dioxide and methane gas have contributed to global warming. Thus, it is desirable to develop new alternative solvents. It is well known that ionic liquids display a variety of environmentally friendly physical properties: nonvolatile, nonflammable, wide electrochemical windows, high inherent conductivities, wide thermal operating ranges, chemically inert, and limited miscibilities with organic solvents. Because of these characteristics, ionic liquids are promising candidates as solvents for synthetic chemistries, catalysis, and gas separations. In this study, we synthesized morpholiunium salts as N-ethyl-N-methylmorpholine Bromide, N-butyl-N-methylmorpholine Bromide, N-octyl-N-methylmorpholine Bromide, N-ethyl-N-methylmorpholine Tetrafluoroborate, N-butyl-N-methylmorpholine Tetrafluoroborate, N-octyl-N-methylmorpholine Tetrafluoroborate, N-ethyl-N-methylmorpholine Hexafluorophosphate, N-butyl-N-methylmorpholine Hexafluorophosphate, and N-octyl-N-methylmorpholine Hexafluorophosphate. The melting points, decomposition temperatures and electrochemical stabilities of the salts were measured by DSC, TGA, and CV, respectively. The salts with halide anion showed high melting points ($150{\sim}200^{\circ}C$), low decomposition temperatures ($200{\sim}230^{\circ}C$), narrow electrochemical stabilities (3.4~3.6 V). The synthesized salts with inorganic anions, on the other hand, presented low melting point ($50{\sim}110^{\circ}C$), high decomposition temperatures ($250{\sim}380^{\circ}C$), wide electrochemical stabilities (6.1~6.3 V). We also found that the properties depend on the length of the carbon chain.

Prioritization of National R&D Investment Using Estimation Results by CGE Model (CGE모형 추정결과를 이용한 국가 R&D 투자 우선순위 설정)

  • Lim, Byung-In;Ahn, Seung-Ku
    • Journal of Technology Innovation
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    • v.19 no.3
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    • pp.57-83
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    • 2011
  • We suggested industry-specific priorities of R&D investment with R&D investment elasticity to GDP calculated from the ripple effect of 28 large-sized industry R&D investment, using a Computable General Equilibrium(CGE) Model. Priority orders apply to only 12 industries, because 16 industries with less than 1% of total investment have been excluded. First, R&D investment elasticity to GDP says that priorities are ordered as Basic metal products, Chemicals, drugs and medicines, Food, beverages and tobacco products, Electronic and electrical equipment, Transportation equipment, Precision instruments, Electrictity, gas, steam and water supply, General machinery and equipment, Communications and broadcasting, Construction, Other services, and Real estate and business services. These priorities show the status quo of Korean industry structures well. The GDP growth rate to 2030 year reference equilibrium, which is an auxiliary index, says a similar priority to results from R&D investment elasticity to GDP. In the end, two criteria of priority order can be functioned as a good index for National Science and Technology Commission deciding what industry to invest and what budget to allocate.

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해저 오염 퇴적층 복원 처리를 위한 BMP 패키지 기술 개발

  • Bae, Jun-Hong;Ha, Mun-Geun;Eo, Gyeong-Hae;Kim, Seung-Hyeok;Park, Chan-Hu;Kim, Byeong-U;Gu, Geun-Hoe;Yun, Cheol-Won
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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    • 2002.05a
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    • pp.12-16
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    • 2002
  • Soil, ground water and sea bed are exposed to continuous accumulation of polluted materials causing serious environmental damage. It has been reported that such pollution causes a massive mortality of fish stock in rivers by the resuspension of toxic chemicals during strong wind conditions. Therefore, it becomes apparent that there is an immediate demand for the restoration treatment of polluted river bed (or sea bed) sediment layers. Pollution levels of major rivers and ports such as Pal-dang, Kyung-an rivers, Ma-san port are becoming public concern and are posing a serious environmental threat. In particular, the pollution of Shi-hwa river has become a nation wide issue for last few years. In spite of such public concern, the pollution level of such rivers or port are getting worse everyday. In this study, an environmentally sound engineering package is introduced which helps to restore the polluted river bed or sea bed sediments. This engineering package is consisted of a suction facility followed by a series of mechanical, chemical as well as biological treatment units. The suction facility is designed to minimize the secondary pollution due to the resuspension of toxic materials during suction. The sea bed cleaning engineering package is designed to be installed on the top of a floating barge. Such combination of environmental plant and shipbuilding technology provides a cost-effective solution, minimizing the cost involved in the transportation between suction and treatment facilities.

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Human Toxicity Index and Toxic Substances Emissions in Korea Industries (한국의 산업별 독성물질 배출과 인체유해도 측정 -산업연관분석의 응용-)

  • Rhee, Hae-Chun;Kim, Ik;Hur, Tak
    • Environmental and Resource Economics Review
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    • v.15 no.4
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    • pp.643-672
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    • 2006
  • This study has assessed the industrial human toxicity index by means of toxic substances emissions in South Korean industry. The data used in analysis are the 146 kinds of the toxic chemicals emissions and final demands, total outputs in the input-output table. As a results, human carcinogenic index was $11.86198{\times}10^3$ for overall industries, and $0.26360{\times}10^3$ for average. The industries of higher human toxicity index can be ranked as follows: Mother vehicles and parts (7.85033) > Pig iron and crude steel(4.57409) > Primary iron and steel products(4.36668) > Other transportation equipments and parts(3.43293) > Inorganic basic chemical products(2.64379), etc. Such result can be considered as the priority order of regulation based on industrial characteristics, when the demand and industrial policies should be carried out for the deduction fof toxic substances.

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A Study of the Evaluation of Combustion Properties of Tetralin (테트랄린의 연소특성치 평가에 관한 연구)

  • Ha, Dong-Myeong
    • Journal of the Korean Society of Safety
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    • v.33 no.4
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    • pp.8-14
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    • 2018
  • In the industrial chemical process involving combustible materials, reliable safety data are required for design prevention, protection and mitigation measures. The accurate combustion properties are necessary to safely treatment, transportation and handling of flammable substances. The combustion parameters necessary for process safety are lower flash point, upper flash point, fire point, lower explosion limit(LEL), upper explosion limit(UEL)and autoignition temperature(AIT) etc.. However, the combustion properties suggested in the Material Safety Data Sheet (MSDS) are presented differently according to the literatures. In the chemical industries, tetralin which is widely used as a raw material of intermediate products, coating substances and rubber chemicals was selected. For safe handling of tetralin, the lower and flash point, the fire point, and the AIT were measured. The LEL and UEL of tetralin were calculated using the lower and upper flash point obtained in the experiment. The flash points of tetralin by using the Setaflash and Pensky-Martens closed-cup testers measured $70^{\circ}C$ and $76^{\circ}C$, respectively. The flash points of tetralin using the Tag and Cleveland open cup testers are measured $78^{\circ}C$ and $81^{\circ}C$, respectively. The AIT of the measured tetralin by the ASTM E659 apparatus was measured at $380^{\circ}C$. The LEL and UEL of tetralin measured by Setaflash closed-cup tester at $70^{\circ}C$ and $109^{\circ}C$ were calculated to be 1.02 vol% and 5.03 vol%, respectively. In this study, it was possible to predict the LEL and the UEL by using the lower and upper flash point of tetralin measured by Setasflash closed-cup tester. A new prediction method for the ignition delay time by the ignition temperature has been developed. It is possible to predict the ignition delay time at different ignition temperatures by the proposed model.

A Study on the Amelioration of the Standard of estimated Unit Manpower & Material' in the Landscape Planting Work (造景植栽工事 標準품셈의 改善方案에 關한 硏究)

  • Sohn, Chang-Ku;Kim, Kwi-Gon;Yoon, Keun-Young;Kang, Tae-Ho;Kim, Ik-Soo
    • Journal of the Korean Institute of Landscape Architecture
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    • v.18 no.3 s.39
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    • pp.23-37
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    • 1990
  • The purpose of this study was to suggest, an ameliorated, 'standard of estimated unit manpower & material' in the Landscape Planting Work. To achieve this goal of this study, following process was performed to reach more advanced results. First, relevant domestic & foreign references were gathered & analyzed with a viewpoint of the system & contents within, Second, most similar foreign country‘s relevant 10 forms & actual site were surveyed, Third, actual site data were collected from the 17 selected landscape Planting sites Fourth, the collected data from reference study & actual site survey were analyzed and calculated. And Finally, analyzed data were reorganized & rearranged in good order with 3 principles to produce more ameliorated 'Standard of estimated unit manpower & material' in the landscape Planting Work. The suggested main results of this study include, 1. Reorganization of current system to transplanting(includes excavation & root ball wrapping), planting(includes tree & shrub), turfing & maintenance 2. Deletion of the Range of 'account of labor' & simultaneous distribution of 'account of labor' with a proposed regular ratio 3. Adjustment of the range of the plant's size 4. Amelioration of the level of 'Account of labor' 5. New establishment in maintenance items as Watering, Fertilizing & spraying chemicals on turf area. 6. Readjustment & new establishment of the backfill volume. 7. Actualization, readjustment & new establishment of the transportation amount.

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A Study on Improvement of Damage Impact Range Assessment for Field-Based Response Against Chemical Terrorism and Accidents (현장 중심의 화학테러·사고 대응을 위한 피해 영향 범위 평가 개선 방안 연구)

  • Lee, Deok-Jae;Song, Chang Geun
    • Journal of Convergence for Information Technology
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    • v.10 no.8
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    • pp.127-136
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    • 2020
  • Chemical terrorism and accidents using chemicals are continuously occurring and attempted in and out of the country. In Korea, the National Institute of Chemical Safety affiliated with Ministry of Environment employs the CARIS(Ver. 2018) to assess the damage impact range for field-based response against chemical terrorism and accidents. However, the current version of CARIS can not consider the effects of closed space such as indoor and underground, so it is difficult to provide accurate evaluation results for damage impact range required for field response, on top of the limited information available. The limitations and directions for improvement were studied by comparing and reviewing the evaluation results of the damage impact range obtained by driving CARIS (Ver. 2018) and the domestic and foreign literature. Proposed improvements also included the direction of information provided to residents, including the need to build modeling for special points, such as underground, indoor, etc., and on-site response personnel. It is expected that through the continuous supplementation and correction of CARIS, chemical terrorism and accident response capability system will be advanced further.

Centrality Analysis of Industry Sector for National Flagship Industry Selection (국가주력산업 선정을 위한 산업의 중심성 분석)

  • Kim, Sung-Rok;Lee, Jong-Sang
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.1
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    • pp.615-621
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    • 2016
  • The selection of a flagship industry is based on whether the industry's developmental impact is great and whether the industry can be the center of the national economy. Here, a ripple effect may be derived by analyzing the forward and backward linkage effects, but in the case of industries that are the centerpieces of the national economy, each researcher reported different results. Consequently, they could not agree on their flagship industry despite belonging to the same time. This study presents a prestige centrality of network analysis as a way of analyzing an industry, which was the center of the national economy, and performed empirical analysis utilizing the 2013 I-O Table. The analysis showed that the industries classified as those with high centrality include the energy industry, which is essential for economic development, can create a synergy effect with other industries, such as the transportation industry, industries with a high level of export and employment, such as electronics and chemicals, and industries for domestic demand, such as wholesale and retail, food services and accommodation.

Inventory Levels of KOSPI-Listed Manufacturing Firms Between 2000 and 2019 (코스피 상장 제조기업의 2000-2019년 재고수준 변화에 대한 고찰)

  • Seungrae Lee;Seung-Jae Park
    • Asia-Pacific Journal of Business
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    • v.14 no.2
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    • pp.1-15
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    • 2023
  • Purpose - This study investigates whether the inventory levels of Korean manufacturing firms increased or decreased from 2000 to 2019. We also explore the relationship between inventory levels and firm performance. Design/methodology/approach - We use panel data on KOSPI-listed firms in the manufacturing industry. We measure days in inventory as a proxy for inventory levels, and firm performance is measured by return on assets, return on sales, and EBITDA ratio. The panel data regression method is employed in our analysis. Findings - We find that days in inventory of Korean manufacturing firms significantly increased from 2000 to 2019, especially for raw materials and finished goods inventory. In addition, while days in inventory of large- and medium-sized firms were less than those of small-sized firms, the change in days in inventory of large- and medium-sized firms was positively significant over time. Moreover, the increase in days in inventory was more prevalent among industries related to foods, clothes, chemicals, and transportation. Finally, we show that the days in inventory are negatively related to firm performance. Research implications or Originality - While the Korean manufacturing industry has enormously grown over the last 20 years and managing inventory is critical in the manufacturing industry, our findings counter-intuitively show that the days in inventory of the Korean manufacturing industry had been gradually increased. We speculate that the increase in days in inventory is due to the Korean manufacturing firms' heavy reliance on global supply chains.