• Title/Summary/Keyword: Chemicals

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Development of feasible program of exchange period for chemical cartridge in the workplace (II) - Method of using odor threshold (작업장에서 사용 가능한 방독마스크 정화통 교체주기 프로그램의 개발(II) - 냄새 서한도(odor threshold)를 이용하는 방법)

  • Han, Don-Hee;Kang, Min-Sun;Yi, Gwang Yong
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.19 no.2
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    • pp.102-112
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    • 2009
  • The greatest concern of vapor/gas respirators is when to exchange chemical cartridges, but it is very difficult to estimate the breakthrough time of them in the workplace spot due to so many factors influencing on breakthrough. There needs to study on estimating cartridge exchange period available practically in the spot, even if it is not precise. In the previous study, authors suggested the method on estimating service-life of chemical cartridges using cartridges discarded after use. This followed study was to estimate exchange period for chemical cartridges using comparison of concentrations between Korean Occupational Exposure Limits (KOELs) and odor thresholds of chemicals. Chemicals were divided into four groups, I, II, III and IV groups. Group I chemicals are relatively safe if cartridges are just or slightly delayed exchanged when smelling since odor thresholds were less than 0.5 times KOELs. Odor threshold of Group II chemicals are 0.5~2.0 times KOELs and potentially hazardous if cartridges are exchanged when smelling. Those chemicals should be conducted program on estimating service-life of cartridges, which was just previously published (J Kor Soc Occup Environ Hyg 2008;18(3) 204-215). Group III chemicals (odor thresholds are more than 2.0 times KOELs) and Group IV chemicals (odorless or no data for smelling) must be performed the above mentioned program before cartridges. Even if this method on cartridge exchange using odor threshold is practically widely used in the workplace spot in the present, program on estimating service-life of cartridges is recommended for all chemicals to reduce potentially hazards.

Synthesis and Characterization of Water-borne Pressure Sensitive Adhesives Polymerized using Styrenated Phenol Type Surfactants (스티렌페놀계 계면활성제 기반 친환경 수계 점착제 합성 및 특성 분석)

  • Song, Young Kyu;Lee, Sang-Ho;Park, Young Il;Kim, Jin Chul
    • Journal of Adhesion and Interface
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    • v.21 no.4
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    • pp.156-161
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    • 2020
  • Waterborne pressure sensitive adhesives (PSA) has been received much attentions from both academia and industries as an environmental friendly-technology because it can significantly reduce use of hazardous organic volatile solvents. However, in the process of the mass production of waterborne PSAs, hazardous phenol type amphiphilic compounds have essentially been used as surfactants for the emulsion polymerization. For the reason, tremendous research efforts have been made to develop environment-friendly organic surfactant which can replace the phenol type surfactants. In this study, we verify the potential of a new class of surfactants based on the styrenated phenol derivatives as an alternative to the phenol type surfactants.

Prenatal Exposures to Environmental Chemicals and Children's Neurodevelopment: An Update

  • Bellinger, David C.
    • Safety and Health at Work
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    • v.4 no.1
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    • pp.1-11
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    • 2013
  • This review surveys the recent literature on the neurodevelopmental impacts of chemical exposures during pregnancy. The review focuses primarily on chemicals of recent concern, including phthalates, bisphenol-A, polybrominated diphenyl ethers, and perfluorinated compounds, but also addresses chemicals with longer histories of investigation, including air pollutants, lead, methylmercury, manganese, arsenic, and organophosphate pesticides. For some chemicals of more recent concern, the available literature does not yet afford strong conclusions about neurodevelopment toxicity. In such cases, points of disagreement among studies are identified and suggestions provided for approaches to resolution of the inconsistencies, including greater standardization of methods for expressing exposure and assessing outcomes.

Resistance to Chemicals and Water of Epoxy Resin Cured with Phosphazene Derivatives (포스파젠 유도체에 의해 경화된 에폭시수지의 내수.내약품성)

  • 윤흥수;최경식
    • Textile Coloration and Finishing
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    • v.13 no.3
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    • pp.188-196
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    • 2001
  • 1, 1-diamino-3, 3, 5, 5-tetrachlorocyclotriphosphazene, 1, 1-diami-no3, 3, 5, 5-tetra-(p-bromophenoxy)cyclotriphosphazene, and 1, 1-diamino-3, 3, 5, 5-tetra-(p-chlorophenoxy) cyclotri-phosphazene(ACPP) was prepared from hexachlorocyclotriphosphazene and used for the curing agent of bisphenol A type epoxy resin and phenol novolak. The resistance to chemicals and water of the cured epoxy resins were examined by DMTA and compared with those of the epoxy rosins cured with phosphazene derivatives and 4, 4'-diaminodiphenylmethane. The effect of the curing agent on resistance to chemicals and water of the cured epoxy resins were investigated. The epoxy resins cured with 1, 1-diamino-3, 3, 5, 5-tetrachlorocyclotriphosphazene and 1, 1- diamino-3, 3, 5, 5-tetra- (p-bromophenoxy)cyclotriphosphazene showed superior resistance to chemicals and water to those of 1, 1-diamino-3, 3, 5, 5-tetra- (p-chlorophenoxy)cyclotriphosphazene and 4, 4'-diaminodiphenylmethane. It is an effective curing agent for epoxy resins to enhance the resistance to chemicals, water and tome proofing.

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LIPID-SOLUBLE VC DERIVATIVE ASCORBIC ACID TETRA-2-HEXYLDECANOATE (VC-IP) AS AN ANTI-AGING AGENT

  • Obayashi, K.;Ochiai, Y.;Ochiai, Y.;Masaki, H.;Kurata, Y.
    • Proceedings of the SCSK Conference
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    • 2003.09a
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    • pp.313-319
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    • 2003
  • It is well known that ascorbic acid (VC) is an important factor for several physiological reactions. In the skin, VC works as an anti-aging agent due to removing of oxidative stress generated by UV irradiation and stimulation of collagen synthesis. Thus, developing more effective VC derivatives is an important issue in creating anti-aging skin care products. Our study succeeded to develop a novel ascorbic acid derivative, ascorbic acid tetra-2-hexyldecanoate (VC-IP), which is a lipid-soluble pro-VC. The purpose of this study was to indicate the effects of VC-IP as pro-VC and anti-aging agent. First, it was examined whether VC-IP is converted to VC in physiological conditions. Since VC was detected from the cell extracts treated with VC-IP, it was indicated that VC-IP is a pro- VC.(omiited)

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ANTI-AGING EFFECTS OF UBIQUINONE-10 (CoQ-10) ON HUMAN SKIN CELLS

  • Okano, Y.;Kurihara, K.;Obayashi, K.;Masaki, H.;Kurata, Y.
    • Proceedings of the SCSK Conference
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    • 2003.09a
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    • pp.320-326
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    • 2003
  • Recently several studies have indicated that ubiquinone-l0 (CoQ-10) decrease with aging in various organs of the human body. The decrease of ubiquinone-10 in the aging process suggests the reduction of both energy production in mitochondria and anti-oxidation with aging. Based on these findings, Ubiquinone-10 is being focused at as an anti-aging agent in the cosmetic market.(omitted)

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Control of Large Patch Catch by Rhizoctonia solani AG2-2 by Combined Application of Antagonists and Chemicals (길항균과 농약의 조합처리에 의한 갈색퍼짐병(라지패취) 방제)

  • 심규열;김희규
    • Asian Journal of Turfgrass Science
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    • v.13 no.3
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    • pp.131-138
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    • 1999
  • A synergistic effect of biocontrol agent and chemicals on control of the large patch on turfgrass caused by Rhizoctonia solani AG2-2 was evaluated. Chemicals; mepronil, toclofos-methyl and iprodione inhibited 90∼100% mycelial growth of R. solani AG1 and AG2-2 in vitro. While on the other, the chemicals inhibited only 0∼5%, 18∼46% and 30∼67% of mycelial growth of the antagonists, respectively. In field application, toclofos-methyl was the best to suppress the disease in single application, however, the combination of mepronil and T. viride 41D showed highest disease control effect among combinations of antagonists and chemicals. Effect of the combination of mepronil and T. viride 41D was similar to that of toclofos-methyl and T. viride 41D stage of disease development, but became higher in six week late. Results indicated that the combined application of selected antagonistic agent and chemical increased control efficasy of turgrass large patch.

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Structure-Related Cytotoxicity and Anti-Heaptofibric Effect of Asiaticoside Derivatives in Rat Hepatic Stellate Cell Line, Hsc-T6

  • Kim, Jeong-Ran;Jung, Seung-Hyun;Lee, Eung-Seok;Lee, Eun-Joo;Yi, Jung-Bum;Lee, Namkyu;Cho, Yong-Baik;Kwak, Wie-Jong;Park, Young-In
    • Proceedings of the Korean Society of Toxicology Conference
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    • 2003.10b
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    • pp.171-171
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    • 2003
  • Asiaticoside, a biologically active triterpenoid present in Centella asicatica, has been known to exert a variety of biological effect such as wound-healing, hepatoprotective, anti-inflammatory. In this study, we observed the effect of asiatic acid asiaticoside and its 16 derivatives on the cytotoxicity and the content of hydroxyproline in rat hepatic stellate cell line, HSC-T6 cell as a preliminary study for screening the anti-hepatofibrotic effect.(omitted)

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Ultrasonic Spray Nozzle System with Piezoelectric Device for Chemicals Dispersion (압전체를 이용한 약품 분사용 초음파 분사 노즐 시스템)

  • 고재석;김용현;김형수;조순행;최승철
    • Journal of the Microelectronics and Packaging Society
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    • v.10 no.4
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    • pp.65-71
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    • 2003
  • A new type of ultrasonic spray nozzle was fabricated employing a piezoelectric device. The spray nozzle was designed to disperse chemicals in a water treatment mixing tank. The piezoelectric properties in ultrasonic spray nozzles were optimized to improve the dispersion of chemicals. The piezoelectrics were packaged in an aluminum case with silicone resin for the aqueous solution proof packaging. Chemicals were dispersed with high efficiency and the chemicals consumption was reduced by the ultrasonic fine particle spraying. The concentration of Escherichia coli in mixing tank was decreased remarkably using ultrasonic spray nozzle dispersion compared to the conventional methods.

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