• Journal of the Korean Ceramic Society
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• v.55 no.4
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• pp.392-399
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• 2018

$C_f/SiC$ composites were prepared via a process combining chemical vapor infiltration (CVI) and precursor infiltration pyrolysis (PIP), wherein silicon carbide matrices were infiltrated into 2.5D carbon preforms. The obtained composites exhibited porosities of 20 vol % and achieved strengths of 244 MPa in air at room temperature and 423 MPa at $1300^{\circ}C$ under an Ar atmosphere. Carbon fiber pull-out was rarely observed in the fractured surfaces, although intermediate layers of pyrolytic carbon of 150 nm thickness were deposited between the fiber and matrix. Fatigue fracture was observed after 1380 cycles under 45 MPa stress at $1000^{\circ}C$. The fractured samples were analyzed by transmission electron microscopy to observe the distributed phases.

• Carbon letters
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• v.4 no.4
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• pp.163-167
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• 2003

The "Film boiling" Chemical Vapor Infiltration (CVI) process is a rapid densification one developed in particular for the elaboration of carbon/carbon composite materials. In order to optimize this new thermal gradient process, we have carried out several studies, on one hand, about the nature of the complex chemical reactions in a confined medium, and on the other hand, relative to the role of heat and mass transfers inside the preform. We show in this study that the introduction of a permeable sheath around the preform leads to hybrid liquid/gas CVI process which presents the advantages of very high densification rates associated with a moderate input energy.

• Journal of the Korean Ceramic Society
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• v.30 no.12
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• pp.993-998
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• 1993

Nicalon-fiber-reinforced SiC composites were fabricated via polymer solution infiltration/chemical vapor infiltration (PSI/CVI) and CVI. Specifically, data were taken and compared for flexural strength, fracture toughness, and processing time. The two process resulted in comparable mechanical properties, and PSI/CVI process resulted in significantly reduced infiltration time.

• Journal of the Korean Ceramic Society
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• v.51 no.5
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• pp.453-458
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• 2014

SiC and its composites have been considered for use as nuclear fuel cladding materials of pressurized light water reactors. In this study, a $SiC_f$/SiC composite as a constituent layer of SiC triplex fuel cladding was fabricated using a chemical vapor infiltration (CVI) process in which tubular SiC fiber preforms were prepared using a filament winding method. To enhance the matrix density of the composite layer, winding patterns, deposition temperature, and gas input ratio were controlled. Fiber arrangement and porosity were the main parameters influencing densification behaviors. Final density of the composites decreased as the SiC fiber volume fraction increased. The CVI process was optimized to densify the tubular preforms with high fiber volume fraction at a high $H_2$/MTS ratio of 20 at $1000^{\circ}C$; in this process, surface canning of the composites was effectively retarded.

• Composites Research
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• v.18 no.5
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• pp.27-33
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• 2005

In this research, the mathematical modelling of the pulse-CVI (Chemical Vapor Infiltration) for the preparation of siliconcarbide/carbon composite. Each pulse consists with the gas injection time, the reaction time and the evacuation time. Effects of the reaction time and the evacuation time were studied. Additionally, the effects of the reactant concentration and the pressure were observed. The benefits of the pulse-CVI such as the uniform infiltration of siliconcarbide into the carbon preform and the short reaction time were certified.

• Journal of the Korean Ceramic Society
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• v.33 no.8
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• pp.935-941
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• 1996

Two-dimensional carbon/carbon preforms made of PAN-based carbon yarn and phenolic resin were densified with pyrolysis of propane by pulse chemical vapor infiltration where repeated the cycle of gas introduction residence and evacuation. Maximim density increment was 14% when infiltration temperature and time were 100$0^{\circ}C$ and 21.25 hrs respectively. The distribution of deposits of pyrocarbon by this process has been occurred uniformly in the bottom middle and top of carbon/carbon composite preform Pulse CVI with residence is most effective in increasing density and shortening infiltration time among isothermal CVI and pulse CVI with and without residence.

• Carbon letters
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• v.25
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• pp.25-32
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• 2018

In this study, a thermal-gradient chemical vapor infiltration (TG-CVI) process was numerically studied in order to enhance the deposition uniformity within the preform. The computational fluid dynamics technique was used to solve the governing equations for heat transfer and gas flow during the TG-CVI process for two- and three-dimensional (2-D and 3-D) models. The temperature profiles in the 2-D and 3-D models showed good agreement with each other and with the experimental results. The densification process was investigated in a 2-D axisymmetric model. Computation results showed the distribution of the SiC deposition rate within the preform. The results also showed that using two-zone heater gave better deposition uniformity.

• Composites Research
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• v.32 no.1
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• pp.56-64
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• 2019

In this paper, a model is developed to simulate carbon/carbon composite fabrication using chemical vapor infiltration, considering density and porosity change in the preform and multi-step hydrocarbons reactions. The model considers the preform as a porous medium whose diffusion and flow properties changes due to the porosity. To verify the theoretical model, two numerical analyses were performed for the case that the flow inside the preform is zero and the case that the flow inside the preform is calculated by fluid mechanics. The numerical results showed good agreement with the experimental data.

• Journal of the Semiconductor & Display Technology
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• v.14 no.2
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• pp.61-65
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• 2015

SiC composite materials are usually used to very high temperature condition such as thermal protection system materials at space vehicles, combustion chambers or engine nozzles because they have high specific strength and good thermal properties at high temperature. One of the most widely used fabrication methods of SiC composites is the chemical vapor infiltration (CVI) process. During the process, chemical gases including Si are introduced into porous preform which is made by carbon fibers for infiltration. Since the processes take a very long time, it is important to reduce the process time in designing the reactors and processes. In this study, both the gas flow and heat transfer in the reactors during the processes are analyzed using a computational fluid dynamics method in order to design reactors and processes for uniform, high quality SiC composites. Effects of flow rate and heater temperature as process parameters to the infiltration process were examined.

• Korean Journal of Materials Research
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• v.4 no.3
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• pp.259-267
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• 1994

The effect of processing parameters, temperature, gas concentration, gas flow rate and pressure, were studied on the densification of carbon/carbon composites using a Robust design method in isothermal low-pressure chemical vapor infiltration with a gas system of $C_3H_8-N_2$ After one time of isothermal low-pressure chemical vapor infiltrat.ion, the bulk density of carbon/carbon composites in creased up to 1-9% and apparent porosity of the composites decreased down to 20-50%. ANOVA analysis of the experiment.al data revealed that the important parameters of isothermal lowpressure chemical vapor infiltration were temperature, gas concentration and gas flnw rate. 'There was almost no ~ f f e c t on densification by pressure and interaction between each parameters. In t, he present experimental conditions, the highest bulk density was obtained at $1100^{\circ}C$ temperature, 100% $C_3H_8$, concentration, 100 SCCM flow rate and 5 torr pressure.