• 제목/요약/키워드: Chemical test

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400MPa급 건축구조용 열간압연 H형강(SHN400)의 소재 특성 (Material Properties of 400MPa Grade Hot Rolled H-beam(SHN400) for Building Structure)

  • 김희동;최병정;김상섭;김철환;오영석
    • 한국강구조학회 논문집
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    • 제23권4호
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    • pp.515-522
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    • 2011
  • 본 연구의 목적은 시험적 방법을 통해 SHN400 강재의 소재 특성이 건축구조용 강재로 적합한지를 평가하는 것이다. 이를 위해 국내에서 생산되는 열간 압연 H형강 중 최대 춤 및 최대 플랜지 두께의 H형강과 SHN400 강종의 주요 사용처가 될 보부재로 수요가 많은 H형강 규격을 대상으로 화학성분 평가, 인장강도, 매크로, 미크로 및 샤르피 충격 시험을 실시하였다. 각 시험은 관련 KS 규격에서 요구하는 시험 조건하에서 수행되었으며, 시험 결과 화학성분 및 기계적 특성과 관련된 모든 시험에서 SHN400 강종은 KS 규격(KS D 3866)의 요구 조건과 내진설계시 강재에 요구되는 조건들을 만족하는 것으로 나타났다. 특히 용접성과 관련된 탄소당량(Ceq)과 비탄성 변형능력과 관련된 항복비의 경우 KS 규격을 상회하는 결과를 나타내었다. 따라서 SHN400 강재는 소재 특성 측면에서 건축구조용 강재에 적합한 것으로 판단된다.

Effect of Electrochemical Redox Reaction on Growth and Metabolism of Saccharomyces cerevisiae as an Environmental Factor

  • Na, Byung-Kwan;Hwang, Tae-Sik;Lee, Sung-Hun;Ahn, Dae-Hee;Park, Doo-Hyun
    • Journal of Microbiology and Biotechnology
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    • 제17권3호
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    • pp.445-453
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    • 2007
  • The effect of an electrochemically generated oxidation-reduction potential and electric pulse on ethanol production and growth of Saccharomyces cerevisiae ATCC 26603 was experimented and compared with effects of electron mediators (neutral red, benzyl viologen, and thionine), chemical oxidants (hydrogen peroxide and hypochlorite), chemical reductants (sulfite and nitrite), oxygen, and hydrogen. The oxidation (anodic) and reduction (cathodic) potential and electric pulse activated ethanol production and growth, and changed the total soluble protein pattern of the test strain. Neutral red electrochemically reduced activated ethanol production and growth of the test strain, but benzyl viologen and thionine did not. Nitrite inhibited ethanol production but did not influence growth of the test strain. Hydrogen peroxide, hypochlorite, and sulfite did not influence ethanol production and growth of the test strain. Hydrogen and oxygen also did not influence the growth and ethanol production. It shows that the test strain may perceive electrochemically generated oxidation-reduction potential and electric pulse as an environmental factor.

Synthesis and Flame Retardant Improvement of PU Coatings Containing Trichloro Modified Polyester/IPDI-Isocyanurate

  • Kim, Ji-Hyun;Keun, Jang-Hyoun;Jung, Choong-Ho;Kim, Seung-Jin;Kim, Young-Geun;Kim, Seong-Kil;Park, Hong-Soo
    • 한국응용과학기술학회지
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    • 제25권3호
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    • pp.332-340
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    • 2008
  • Two component polyurethane (PU) flame retardant coatings were prepared by blending trichloro modified polyesters (TCMPs) and isophorone diisocyanate isocyanurate. TCMPs were synthesized by polycondensation of trichlorobenzoic acid (TCBA), a flame retardant component, with adipic acid, 1,4 butanediol, and trimethylolpropane. The content of TCBA was varied in 10, 20, and 30 wt% for the reaction. Theses new flame retardant coatings showed various properties comparable to other non flame retardant coatings. Moreover, we carried out the combustion test and the flammability test for our flame retardant coatings. The results of vertical burning test for the coatings containing more than 20 wt% of TCBA were determined as no burn. The results of flammability test for the coatings with 20 wt% and 30 wt% of TCBA contents indicated the limiting oxygen index (LOI) values of 26% and 29% respectively, which implied relatively good flame retardancy.

Effect of Co-agent on Cure, Mechanical Properties of NBR Compounds in Peroxide System

  • Seo, Eun Ho;Kim, Gi Hong;Kim, Do Young;Lee, Dong Won;Seo, Kwan Ho
    • Elastomers and Composites
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    • 제52권3호
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    • pp.187-193
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    • 2017
  • In this study, the effect of the cure, mechanical properties, and oil resistance of NBR (acrylonitrile-butadiene rubber)/peroxide compounds were investigated for various co-agents. NBR compounds were characterized using a swelling test, a rheometer (MDR), and a compression set test. Mechanical properties were tested with original compounds, heated in air and exposed to the ASTM No.1, IRM 903 oil. NBR compounds were prepared using peroxide as the crosslinking agent. Trimethylolpropane trimethacrylate (TMPTMA), triallyl isocyanurate (TAIC), and 1,2-polybutadiene (HVPBD) were used as co-agents. The NBR compounds containing TMPTMA and HVPBD lowered the scorch time, while the addition of TAIC did not significantly change the scorch time. NBR compounds containing TMPTMA increased the crosslinking density, while the addition of TAIC and HVPBD lowered the crosslinking density. Moreover, the addition of TMPTMA improved the oil resistance of the NBR compound.

도로 제설제 권장 살포량 산정식의 적정성 평가 (Evaluation of Reasonableness of the Recommended Spraying Amount Equation for De-icing Chemicals)

  • 김진국;양충헌
    • 한국도로학회논문집
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    • 제19권4호
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    • pp.9-18
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    • 2017
  • PURPOSES : This study evaluates the reasonableness of the recommended amount of deicing chemicals based on historical data for snow removal. The result can be used to aid decision-making for the reservation of cost-effective de-icing chemicals. METHODS : First, the recommended amount of de-icing chemical to use and historical usage data were evaluated to identify specific usage characteristics for each region. Road maintenance length and snow-removal working days were analyzed over the past five winter seasons. Next, differences in the recommended amount of chemical to use and actual use were compared using the Kolmogorov-Smirnov test. Last, the two types of data were analyzed using a chi-square test to verify if the two distributions of variation pattern are statistically significant. We found that there are significant differences between the data from each region during the past five winter seasons. RESULTS : The results showed that the equation for calculating the amount of de-icing chemical to use appears to be revised. CONCLUSIONS : The results imply that the equation for calculating the amount of de-icing chemical to apply as a national standard is very important when the public agency makes decisions related to snow-removal.

다제품 생산을 위한 최적 테스트 스케줄링 모델 개발 (Development of a Model for the Optimal Test Scheduling Considering Multiple Products)

  • 손홍록;류준형;이인범
    • Korean Chemical Engineering Research
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    • 제47권6호
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    • pp.695-699
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    • 2009
  • 경쟁력을 유지하기 위해 기업은 다양한 신제품들을 동시 다발적으로 개발해야 한다. 이런 제품들은 시장에 출시되기 전에 품질, 안정성, 내구성 등 다양한 시험(test)들을 거쳐야 한다. 여러 시험 수행 일정을 조정함으로 그로 인한 전체 발생 비용을 고려한 신제품의 순현재 가치(NPV, net present value)가 변하게 되며 이를 최대로 하기 위한 시스템적 방법이 필요하다. 이러한 필요성에 따라서 본 연구에서는 현실적 자원 제약이 고려된 상황에서 다제품(multiple products)들의 최적 시험 순서를 결정할 수 있는 모델을 제시하였다. 또한 수학적 예제를 통해서 테스트 수행 시간이 확률적으로 주어진 경우에도 적용할 수 있다는 것을 검증하였다.

Yield stress measurements in suspensions: an inter-laboratory study

  • Nguyen, Q. Dzuy;Akroyd, Timothy;Kee, Daniel C. De;Zhu, Lixuan
    • Korea-Australia Rheology Journal
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    • 제18권1호
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    • pp.15-24
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    • 2006
  • The first international inter-laboratory study, involving six laboratories, has been conducted to examine issues associated with yield stress measurements in suspensions. The initial focus of the project was to evaluate the reliability and reproducibility of several common yield stress measuring techniques employed in different laboratories and with different instruments. Aqueous suspensions of colloidal $TiO_2$ at concentrations of 40-70 wt% solids were used as the test fluids. A wide range of instruments and techniques employing both direct and indirect methods were used to determine the yield stress of the samples prepared according to a prescribed procedure. The results obtained indicated that although variations of results existed among different techniques, direct yield stress measurements using static methods produced more reliable and repeatable results than other methods. Variability of the yield stress measured using different techniques within any laboratory however was less significant than variability of the results among different laboratories. The nature and condition of the test suspensions was identified as the most likely factor responsible for the poor reproducibility of yield stress measurements from different laboratories.

DL-Aminoalkyl Phosphonic Acid와 그 유도체들의 합성 (제3보) (Synthesis of DL-Aminoalkyl Phosphonic Acids and Their Derivatives (III))

  • 노만균;김용준
    • 대한화학회지
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    • 제17권2호
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    • pp.136-141
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    • 1973
  • Curtius reaction을 이용하여 pentanoic acid로부터 DL-1-aminobutylphosphonic acid를 합성하였고, pyruvic acid 로부터 DL-2-carboxyethylphosphonic acid를 합성하였다. 아직 발표된 바 없는 이들의 N-acyl유도체들을 Schotten Bauman방법 등으로 합성하였다. 그 화합물들은 다음과 같다. N-acetyl-DL-1-aminobutylphosphonic acid N-benzoyl-DL-1-aminobutylphosphonic acid N-benzoyl-DL-2-amino-2-carboxyethylphosphonic acid N-p-chlorobenzoyl-DL-2-amino-2-carboxyethylphosphonic acid. 이 유도체들은 원소분석, I${\cdot}$R spectra, ninhydrin test 및 중화당량으로 확인하였다.

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