• 제목/요약/키워드: Chemical strengthening

검색결과 103건 처리시간 0.02초

New Glaze Composition for Chemical Strengthening of Bone China

  • Kim, Hyeong-Jun;Han, Yoon Soo;Park, Hyung-Bin;Park, Jewon;Na, Hyein;Choi, Sung-Churl
    • 한국세라믹학회지
    • /
    • 제55권3호
    • /
    • pp.299-306
    • /
    • 2018
  • In order to improve the hardness of commercial bone china, we suggested a chemical strengthening process and new glaze for its process. New glaze contained about two times more $Na_2O$ and $Al_2O_3$ and had a higher transition temperature than that of commercial frit. Chemical strengthening enhanced the hardness of the new glaze-coated bone china by over 30% compared to that of commercial product. The change of glaze composition influenced potassium ion diffusion distance and depth of strengthened layer during chemical treatment. After chemical strengthening of new glaze-coated bone china, the residual compressive stress inside the glaze was measured and found to be greater than 160 MPa.

Micro-Crack Healing on Soda-Lime Glass by Chemical Strengthening

  • Kim, Hyeong-Jun;Lee, Sung-Min;Maeng, Jeehun;Kim, Dong-hwan
    • 한국세라믹학회지
    • /
    • 제56권5호
    • /
    • pp.483-488
    • /
    • 2019
  • We studied whether chemical strengthening can heal the flaws on soda-lime silicate glass. Artificial surface cracks were introduced on the glass by sharp indentation with various loads of 0.1 to 10 N. Then, the glasses with flaws were treated by ion-exchanging in KNO3 melt. The change in the dimension of the crack on glass was measured by a digital microscope and a scanning electron microscope. The chemical strengthening treatment enhances the strength of the glass with flaws. It is thought that the melted KNO3 not only forms the depth of the compressed layer of 7.5 ㎛, but also heals the cracks by infiltrating them and expanding the glass on both sides of the cracks. The critical length (2c) of the cracks on soda-lime glass that can be healed by chemical strengthening is 50 ㎛ or less.

Improvement of Glaze Hardness in Commercial Bone China

  • Kim, Hyeong-Jun;Han, Yoon Soo;Kim, Dong-Hwan;Kim, Da-Mi;Choi, Jae-Ho;Lee, Sung-Min;Kim, Yoojin;Kim, Hyung-Tae
    • 한국세라믹학회지
    • /
    • 제52권6호
    • /
    • pp.508-513
    • /
    • 2015
  • In order to improve the hardness of commercial bone china, we attempted to control the glost firing temperature and apply a chemical strengthening process. When the glost firing time was longer or its temperature was higher than normal conditions, the hardness was improved by approximately 5%. The chemical strengthening process also enhanced the hardness of the glaze by more than 13% compared with bone china. It is believed that the enhancement of the hardness of the glaze was related to the development of residual compressive stress in the glaze due to 1) the increase in the calcium phosphate phase in the interface layer between the body and the glaze after firing, and 2) the increase of the $K^+$ concentration on the glaze surface during the chemical strengthening process.

화학적 보강 방법에 따른 열화 종이의 보강 특성 (Strengthening Performance of Aged Papers with Chemical Strengthening Treatments)

  • 이혜윤;이제곤;김민수;심규정;윤혜정
    • 펄프종이기술
    • /
    • 제46권5호
    • /
    • pp.35-42
    • /
    • 2014
  • Many historical archives have been deteriorated by aging with time. Various kinds of defects such as worm-hole, yellowing, brittleness are observed and their severity was dependent on raw material type, storage condition, and so on. For a long-term use and storage, a proper preservation treatment is required. Many studies on preservation and conservation have been carried out on hanji which was made from mulberry fiber, but there are few concerns on foreign paper. Therefore, aging and chemical strengthening treatment was done on paper made of bamboo and wood fibers depending on aging condition, the type and pickup weight of chemicals and treatment method. When methyl cellulose was treated with impregnation or brushing, the aged paper was strengthened effectively. The strengthening effect by chemicals was dependent on the aged condition of the paper.

이온강화법을 이용한 소다라임 글라스 강화에 관한 연구 (A study on the strengthening of Sodalime glass using ion exchange method)

  • 안해원;오재호;권수근;최성대
    • 한국기계가공학회지
    • /
    • 제13권6호
    • /
    • pp.145-151
    • /
    • 2014
  • The glass used for mobile display windows is required to have high strength. Chemical strengthening by means of ion exchange is widely used glass. The depth of the layer and the compressed stress are affected by tempering temperature and time. The purpose of this study is to investigate the range of DOL and CS, which to less breakage during reliability tests such as the ball drop test, hole drop test, 3-point bending test, drop test, and tumble test with Soda-lime Glass.

수중 구조물의 보수·보강을 위한 수중 접착제, 에폭시와 섬유복합재의 개발 (Development of Underwater Adhesive, Epoxy, and FRP Composite for Repair and Strengthening of Underwater Structure)

  • 김성배;이나현;남진원;변근주;김장호
    • 콘크리트학회논문집
    • /
    • 제22권2호
    • /
    • pp.149-158
    • /
    • 2010
  • 현재 육상 노출 콘크리트 구조물의 보수 및 보강공법에는 많은 신기술이 개발되었고 연구도 많이 진행되고 있으나, 수중에 존치되어 있는 구조물, 즉 교각, 부두 잔교 및 강관파일과 같이 해수 및 수중에 잠겨 있으며, 지속적인 하중을 받는 콘크리트 및 강재의 보수보강 기술에 대한 연구는 많지 않다. 그러므로 이 연구에서는 해수나 수중에 있는 구조물의 보수 보강 공법에 사용할 수 있는 수중 에폭시를 개발하였고, 이 에폭시 재료와 보강섬유을 이용하여 수중용 FRP 복합재를 개발하였다. 개발된 재료의 성능을 검증하기 위하여 다양한 기초물성에 대한 시험을 수행하였다. 성능시험 결과, 개발된 에폭시는 수중에서도 풀림이 거의 없고 부유물질이 발생하지 않는다. 또한 수중이라는 제약 조건 속에서도 30,000 cps 이상의 높은 점성을 갖기 때문에 우수한 작업성을 보이며, 수중에서도 육상에서와 거의 유사한 2 MPa 이상의 부착성능을 발휘하는 것으로 나타났다. 내화학성 시험 결과에서도 중량변화율은 약 0.5~1.0% 이내로 측정되어 우수한 내염 저항성을 확인하였다.

화학적 프리스트레싱에 의한 노후화 전신주 FRP 보강기법 개발 (Development of the Strengthening Method of Telegraph Pole using Chemically Prestressed Fiber Reinforcement Polymer)

  • 한재원;홍기남;한상훈;우상균
    • 한국콘크리트학회:학술대회논문집
    • /
    • 한국콘크리트학회 2009년도 춘계 학술대회 제21권1호
    • /
    • pp.501-502
    • /
    • 2009
  • 본 논문에서는 현존하는 노후된 콘크리트 전신주를 위한 경제적인 보강기법으로서 화학적 프리스트레싱을 적용하기 위해 팽창재가 사용되었다. 이 보강기법은 콘크리트 실험체의 내하력과 연성을 증가 시켰을뿐만 아니라 FRP 재료의 제한성 및 활용도가 증대 될 수 있음을 보였다. 보강된 실험체의 화학적 프리스트레싱력과 내력을 실험적으로 수행하여 측정하였다. 이 결과로부터 팽창재의 사용 양을 조절함으로써 화학적 프리스트레싱의 적용 정도를 조절하는 것이 가능하고, 또한 내력은 기준 실험체와 비교하여 3배 이상까지 증가되는 것으로 분석되었다.

  • PDF

Chemical Strengthening Involving Outward Diffusion Process of Na+ Ion in Iron-containing Soda-lime Silicate Glass

  • Choi, Hyun-Bin;Kang, Eun-Tae
    • 한국세라믹학회지
    • /
    • 제52권2호
    • /
    • pp.133-136
    • /
    • 2015
  • The outward diffusion of $Na^+$ ions in iron-bearing soda lime silicate glass via oxidation heat treatment before the ion exchange process is artificially induced in order to increase the amount of ions exchanged during the ion exchange process. The effect of the addition process is analyzed through measuring the bending strength, the weight change, and the inter-diffusion coefficient after the ion exchange process. The glass strength is increased when the outward diffusion of $Na^+$ ions via oxidation heat treatment before the ion exchange process is added. For the glass subjected to the additional process, the weight change and diffusion depth increase compared with the glass not subjected to the process. The interdiffusion coefficient is also slightly increased as a result of the additional process.

중소사업장 화학물질 관리에 영향을 미치는 사업주의 인식과 태도 요인 분석 (A Study on Important Factors for Chemical Risk Management in Small & Medium Enterprises)

  • 김신범;최영은;정태진;이정화;최시몬;강성주;최재영;최종경;김성민;임종호;민경두;윤간우;김현옥
    • 한국산업보건학회지
    • /
    • 제25권3호
    • /
    • pp.285-293
    • /
    • 2015
  • Objectives: This study was conducted in order to ascertain the important factors for SMEs in managing the risks of chemicals and to suggest a government role in strengthening the responsibility of small and medium enterprises(SMEs) as employers. Methods: About 100 enterprises were surveyed in Incheon. A questionnaire for employers and walk-through surveys by occupational hygienists were performed at each enterprise. Results: The results showed that most employers thought chemicals were not hazardous but chemical management was needed. When employers determine how to manage chemicals, they rely heavily on personal experience and rather less on information from the government or experts. However, if employers think the chemicals are hazardous, they do more to manage the chemicals. Conclusions: When employers think chemicals are hazardous, risk assessment would be an effective tool to control chemical hazards in SMEs. Employers' position on chemical hazards is very important. Since the government is the initiator, it is the government who develops messages for SMEs, such as "Chemicals are hazardous and management can reduce the risk of chemicals." Governmental messages can play an invaluable role in strengthening the responsibility of SME employers to manage chemical hazards.

건조수축 해석을 통한 종이의 벌크 및 강직성 향상 (Improvement of Paper Bulk and Stiffness by Using Drying Shrinkage Analysis)

  • 이진호;박종문
    • 펄프종이기술
    • /
    • 제43권4호
    • /
    • pp.49-58
    • /
    • 2011
  • The maximum drying shrinkage velocity was proposed to verify bulk and stiffness improvement mechanism during drying according to papermaking parameters. It was based on the wet-web shrinkage behavior without the restraint of wet-web during drying, so intact drying impact could be measured. Bulking agent reduced the drying shrinkage and the maximum drying shrinkage velocity, so paper bulk increased and paper strength decreased. When adding cationic starch to stock with the bulking agent for strengthening, the bulk was increased further with additional decreasing of the drying shrinkage and the maximum drying shrinkage velocity. Paper strength also increased except tensile stiffness index with decreasing the drying shrinkage and the maximum drying shrinkage velocity. When using additional strength additives for strengthening of fiber interfaces extended by bulking agent and cationic starch, amphoteric strength additive increased paper stiffness without loss of paper bulk. It was considered that the added amphoteric strength additives were cross-linked to the stretched cationic starch and this cross-linking increased elasticity of fiber-polymer-fiber interfaces without changing the drying behavior. Paper bulk could be increased with decreasing the maximum drying shrinkage velocity. The drying shrinkage of paper also could be controlled by fiber-to-fiber bonding interfaces by the bulking agent. In this case, paper strength including stiffness was decreased by reducing fiber-to-fiber bonding but it could be improved by strengthening fiber-to-fiber interfaces with polymer complex without loss of bulk.