• Title/Summary/Keyword: Chemical spills

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Confirmation of the Efectiveness of Remote Chemical Spills and Leak Monitoring System through Acetone Pool Evaporation Experiments (아세톤 풀 증발 실험을 통한 원격 유·누출 모니터링 시스템의 효용성 확인)

  • Eun Hee, Kim;Seul Gi, Lee;Byung Chol, Ma
    • Journal of the Korean Society of Safety
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    • v.37 no.6
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    • pp.25-31
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    • 2022
  • In this study, the spill and leak system is developed to provide real-time remote monitoring of industrial complexes where chemical accidents have been occurring every year. The spill and leak monitoring system uses IR-RCD equipment mounted on a 70m-high steel tower to detect chemical substances, thereby detecting chemical accidents such as leaks, fires, and explosions in real time. If IR-RCD equipment can actually detect chemical substances at a long distance, accurate and rapid initial response can be expected. Therefore, in order to confirm that IR-RCD equipment can detect chemical leakage accidents occurring at a long distance, acetone was selected as the experimental substance and a detection experiment was designed. The experiment was conducted using the acetone pool evaporation method at the wharf which was located 1.5 km away from IR-RCD equipment, and it was confirmed whether IR-RCD equipment could detect acetone in real time through the control monitor.

Oil Absorption Effects of Organic Porous Materials (유기 다공성 소재의 흡유 효과)

  • Kang, Young-Goo;Han, Sang-Bum
    • Journal of the Korean Society of Safety
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    • v.21 no.1 s.73
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    • pp.86-91
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    • 2006
  • Oil spills caused by the accidents have been occurred from house and factory waste, grounded tanker, the rupture of storage tank and oil pipelines, the deterioration of various industrial facilities, etc. Many oil spills result in contamination of shorelines and workplace. Fire and explosion may happen from these spills. There are several technologies used for clean-up application, which include use of oil dispersing agents, absorbents, solidifiers, booms and skimmers by physical, chemical, and biological methods. Methods for oil spill clean-up operation are classified into the absorption type, gel type and self-swelling type. Porous materials with oil absorptive properties are classified into micropore, mesopore, and macropore depending on their pore sizes. Recently, new porous materials with smaller size have been developed, but the selective oil absorption in water-in-oil interface demonstrates the macro pore size. In this study oil absorption effects were evaluated using the organic porous materials with a complex function of gel type and swelling type. Samples were subjected to analysis by FT-IR spectroscopy and were characterized in terms of gel formation and morphologies. Oil sorption capacity, pressure retention force and gel strength were also measured. From these results, the physicochemical reactivity before and after gelation was verified and the industrial applications of clean-up operation were suggested.

Development of Oil Spills Model and Contingency Planning ill East Sea (유류확산모델 개발 및 동해의 유류오염 사고대책)

  • RYU CHEONG-RO;KIM HONG-JIN
    • Journal of Ocean Engineering and Technology
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    • v.19 no.4 s.65
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    • pp.35-41
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    • 2005
  • There has been increasing offshore oil exploration, drilling, and production activities, as well as a huge amount of petroleum being transported by tankers and pipelines through the ocean and costal environment. Assessment must be made of the potential risk of damage resulting from the exploration, development and transportation activities. This is achieved through predictive impact evaluations of the fate of hypothetical or real oil spills. VVhen an oil spill occurs, planning and execution of cleanup measures also require the capability to forecast the short-term and long-term behavior of the spilled oil. A great amount of effort has been spent by government agencies, oil industries, and researchers over the past decade to develop more realistic models for oil spills. Numerous oil spill models have been developed and applied, most of which attempt to predict the oil spill fate and behavior. For an actual contingency planning, the oil fate and behavior model should be combined with an oil spill incident model, an environmental impact and risk model and a contingency planning model. The purpose of this review study is to give an overview of existing oil spill models that deal with the physical, chemical, biological, and socia-economical aspects of the incident, fate, and environmental impact of oil spills. After reviewing the existing models, future research needs are suggested. In the study, available oil spill models are separated into oil spill incident, oil spill fate and behavior, environmental impact and risk, and contingency planning models. The processes of the oil spill fate and behavior are reviewed in detail and the characteristics of existing oil spill fate and behavior models are examined and classified so that an ideal model may be identified. Finally, future research needs are discussed.

Groundwater Contamination (지하수 오염)

  • Jeon, Hyo-Taek
    • 수도
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    • v.25 no.1 s.88
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    • pp.25-35
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    • 1998
  • Factors controlling water quality, water-quality standards, and normal ranges of concentrations in unpolluted fresh water and the sources of elements were explained in this paper. In particular, the sources of groundwater contamination such as the disposal of domestic waste water, landfills, chemical spills and leaking underground tanks, and agricultural and mining activities were discussed.

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A Note on in-Situ Burning of Marine Oil Spills (해상누유 현장소각 기술에 대한 소고)

  • Sung H.G.
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.3 no.3
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    • pp.58-65
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    • 2000
  • Responses to marine oil spills can be classified Into categories; 1) mechanical treatment using booms and skimmers, 2) chemical one utilizing dispersants, 3) controlled in-situ burning of spilled oils. In the present paper, characteristics, history, present issues, advantages and disadvanteges, and future applicability of in-situ burning technology which is nowadays winning much attention are summarized on the basis of a survey of related papers and other resources.

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Effect of the Fate Mechanisms of Phenol on the Remediation Efficiency of In-Situ Capping Applied to Sediment Contaminated by Phenol Chemical Spills (페놀 화학사고 발생으로 오염된 퇴적물에서 페놀의 거동 기작이 원위치 피복의 정화 효율에 미치는 영향)

  • Lee, Aleum;Choi, Yongju
    • Journal of Soil and Groundwater Environment
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    • v.27 no.1
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    • pp.60-70
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    • 2022
  • We evaluated the performance of in-situ capping to prevent the release of phenol, one of hazardous chemicals of concern for their impact on sediment. Sediment near the estuary of Hyeongsan River, Korea, and commercially-available sand were collected to evaluate their physical properties and phenol sorption characteristics. Biodegradation kinetics of phenol spiked into the sediment was evaluated under freshwater and estuarine salinity conditions. These experimental measurements were parameterized and used as input parameters for executing CapSim, a software predicting the performance of in-situ capping. The CapSim simulation demonstrated that capping with 50-cm sand reduced the phenol release by several orders of magnitude over 0.25- and 1-year duration for almost all simulation scenarios. The variables tested, i.e., cap thickness, pore-water movement, and biodegradation rate, showed high correlation to each other to influence the extent of phenol release from sediment to the water column. The findings and the framework employed to evaluate the performance of in-situ capping in this study can be adopted to determine whether in-situ capping is appropriate remedial approach at sediment sites impacted by hazardous chemicals due to accidental spills.

Changes in Soil Properties Related to Soil Function due to Chemical Spills with Strong Acid and Base (강산 및 강염기 토양 유출에 따른 토양의 생태기능 관련 토양특성 변화)

  • Jeon, Inhyeong;Jung, Jae-Woong;Nam, Kyoungphile
    • Ecology and Resilient Infrastructure
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    • v.4 no.4
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    • pp.193-199
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    • 2017
  • In this study, changes of soil properties including soil texture, specific surface area, organic matter content, pH, cation exchange capacity and exchangeable cations content were investigated in response to strong acid or base accident. The properties changed significantly when the soil reacted with 10 M HCl or 1 M NaOH (i.e., when one gram of soil received 50 and 5 mmol of HCl or NaOH), respectively. When the soil reacted with 10 M HCl or 1 M NaOH solution, soil texture changed from sandy loam to loamy sand and specific surface areas decreased from $5.84m^2/g$ to 4.85 and $1.92m^2/g$, respectively. The soil organic matter content was reduced from 3.23% to 0.96 and 0.44%, and the soil pH changed from 5.05 to 2.35 and 10.65, respectively. The cation exchange capacity decreased from 10.27 cmol/kg to 4.52 and 5.60 cmol/kg, respectively. Especially, high concentrations of $Al^{3+}$ or $Na^+$ were observed in acidic or basic spills, respectively, which is likely to cause toxicity to terrestrial organisms. The results suggest that restoration of soil properties, as well as soil remediation, needs to be carried out to maintain the soil function in chemical spill sites.

A Study on Improved Emergency Management System - Focused on Response to Diffusion of Oil Spilled in Marine - (재난안전관리 체계 개선 방안 연구 - 해양오일유출 확산방지기술 중심으로 -)

  • Yoo, Byungtae;Oh, Keumho;Baek, Jong-bae
    • Journal of the Korean Society of Safety
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    • v.30 no.2
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    • pp.83-89
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    • 2015
  • In Korea for 20 years(1993-2012), total number and average annual number of oil spills were 6,608 cases and total volume and average annual volume of oils spilt were $57,328k{\ell}$ and nearly $2,866k{\ell}/year$, respectively. The annual number of oil spills and annual amount of oil spilt tended to decrease with the lapse of year in Korea. As oil transportation worldwide continues to increase, many communities are at risk of oil spill disasters and must anticipate and prepare for them. Factors that influence oil spill consequences are myriad and rage from the biophysical to the social. In this paper, we analysed the emergency response systems and recovery apparatuses for oil spill accident in marine and proposed a developed oil diffusion apparatus which can be used to initial response stage by crew, and to extend golden times. This system can be minimized casualties for rescued people in disaster.

Oilspill Damage Assessment of Natural Fisheries Resources by Ecological Models (생태학적 모델을 이용한 유류유출 사고에 의한 자연 수산자원 피해의 추정)

  • YOO Sin jae;SHIN Kyoung Soon
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.29 no.2
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    • pp.174-190
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    • 1996
  • Damage assessment based on in situ surveys for oil spills in marine environment is limited by fundamental difficulties as well as tremendous expenses. Except for intertidal zones, the damage is not preserved well. Also such surveys are usually confined to adult organisms. To overcome these limitations a computer model, NRDAM/CME, was developed in the case of USA (Reed et al., 1989), where an acute toxicity data base was used to assess indirect damages through food webs and loss due to recruitment as well as adult losses. In the present study damage assessment of natural biological resources for hypothetical oil spills is attempted using a computer model for hypothetical spills of Bunker C and heavy crude oil. In the model, the logical structure of NRDAM/CME was adopted, and biomass and productivity database were compiled for the Korean waters. The results showed that the damage increased in a nonlinear fashion as the spill amount increased. The magnitude of the damage depended upon the chemical properties of oil viscosity and solubility in particular, which implies that usage of oil dispersant might increase the damage by dispersing oil. The results also indicate that long term damage due to recruitment loss could be greater than short term damage.

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