• 제목/요약/키워드: Chemical spill

검색결과 82건 처리시간 0.032초

3차원 수리모델을 이용한 한강 상수원구간 지류영향 분석 및 수질오염사고 시나리오 모의 (Impact Analysis of Tributaries and Simulation of Water Pollution Accident Scenarios in the Water Source Section of Han River Using 3-D Hydrodynamic Model)

  • 김은정;박창민;나미정;박현;김복순
    • 한국물환경학회지
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    • 제34권4호
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    • pp.363-374
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    • 2018
  • The Han River serves as an important water resource for the city of Seoul, Korea and in the neighboring metropolitan areas. From the Paldang dam to the Jamsil submerged weir, the 4 water intake stations that are located for the Seoul metropolitan population were under review in this study. Therefore the water quality management in this section is very important to monitor, analyze and review to rule out any safety concerns. In this study, a 3-D hydrodynamic model, EFDC (Environmental Fluid Dynamics Code), was applied to the downstream of the Paldang Dam in the Han River, which is about 23 km in length, to determine issues related to water resource management. The 3-D grid was composed of 2,168 horizontal grids and three vertical layers. In this case, the hydrodynamic model was calibrated and verified with an observed average daily water surface elevation, water temperature and flow rate data for 3 years (2013~2015). The developed EFDC model proved to reproduce the hydrodynamics of the Han River well. The composition ratios of the noted incoming flows at the monitored intake stations for 3 years and their flow patterns in the river were analyzed using the validated model. It was found that the flow of the Wangsuk Stream depended on the Paldnag dam discharge, and it was noted that the composition ratios of the stream at the intake stations changed accordingly. In a word, the Wangsuk Stream moved mainly along the right bank of the Han River under the condition of a normal dam flow. As can be seen, when the dam discharge rate was low, the incidence of lateral mixing was often seen. The scenario analyses were also conducted to predict the transport of conservative pollutants as in the case of a chemical spill accident. Generally speaking, when scenarios were applied, the arrival time and concentration of pollutants at each intake station was thus predicted.

화학물질 운반차량 누출사고 처리절차에 관한 연구 (A Study on Investigation Procedure of Chemical Spill by Vehicle Transporting Chemicals)

  • Kim, Sungbum;Lee, Sangjae;Jeong, Seongkyeong;Lim, Myunghee;Song, Youngil;Ahn, Euisan;Jeong, Hoyong;Kim, Najin;Lee, Hyunjoo;Choi, Sungwoon
    • 한국재난정보학회 논문집
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    • 제13권1호
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    • pp.1-5
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    • 2017
  • 지난 3년('13~'15)간 화학물질사고는 301건이 발생하였으며, 연평균 약 100건이 집계됐다. 이와 같은 화학사고는 인명과 환경에 많은 피해를 가져왔다. '13년~'15년에 발생한 운반차량 화학사고는 연평균 21건으로 전체 화학사고의 약 21%를 차지한다. 화학물질 운반차량의 사고는 지역에 관계없이 도로상에서 발생하고 있기 때문에, 관계기관의 대응 및 사후처리 등 체계적인 현장조사가 필요하다. 또한 화학물질 운반업자 및 화물주 등의 협조가 절대적으로 필요한 상황이다. 따라서, 본 논문에서는 화학물질 운반차량의 사고발생에 대한 현장조사 및 처리 절차를 조사 분석하였다. 이를 통해 운반차량의 화학사고에 대한 원인을 분석하고 현장조사와 처리절차를 체계적으로 마련하는 기초자료가 될 것으로 판단된다.

사고대비물질 개인보호구 선정에 관한 연구(1): 물질유해성 및 작업위해성 분석 (A Study on Selecting Personal Protective Equipment for Listed Hazardous Chemicals (1): Analysis of Hazard Ranks and Workplace Exposure Risks)

  • 한돈희;정상태;김종일;조용성;이청수
    • 한국환경보건학회지
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    • 제42권6호
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    • pp.419-429
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    • 2016
  • Objectives: According to the new Chemical Control Act from the Korean Ministry of Environment (2014-259), workers handling hazardous chemicals should wear personal protective equipment (PPE). However the act simply states in basic phrases that every worker handling one or more of the 69 listed chemicals should wear PPE and does not consider the unique hazard characteristics of chemicals and work types. The main purpose of this study is to provide basic data to revise the act to suit particular work processes and situations. Methods: The hazard rank of the substances was classified based on hazardous characteristics such as LC50 and vapor pressure using matrix analysis. The workplace exposure risk of the substances was also determined through a matrix analysis based on the previously determined hazard ranks and the demands of manual handling together with the likelihood of accident frequency of the operation combined with the exposure of workers during spill accidents. Results: To meet the demands for developing subsequent guidelines for the risk-based application of PPE in hazardous workplaces, this study sorted the 69 listed chemicals into five hazardous categories based on their LC50 and vapor pressures, and also assigned exposure categories according to exposure vulnerability for various types of work which are frequently performed throughout the life cycle of the chemicals. Conclusion: In the next study, an exposure risk matrix will be produced using the hazard rank of chemicals and workplace exposure risk, and then PPE will be selected to suit the categories of the exposure risk matrix.

해상 유해액체물질(NLS) 유출사고대비 물질군 선정에 관한 연구 (Prioritizing Noxious Liquid Substances (NLS) for Preparedness Against Potential Spill Incidents in Korean Coastal Waters)

  • 김영윤;최정윤;손민호;오상우;이문진;이상진
    • 해양환경안전학회지
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    • 제22권7호
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    • pp.846-853
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    • 2016
  • 해상 유통되는 유해액체물질(NLS)의 유출사고대비 물질군 선정을 위해 596종의 NLS를 대상으로 위해성 DB를 구축하고 우선 순위 선정시스템을 통해 전체 우선순위를 선정하였다. 우선순위 목록을 바탕으로 2014-2015년 해상유통물질 158종을 추출한 뒤 물질군 구분 기준을 적용하여 0~3순위의 4개 물질군을 제시하였다. 국가차원의 NLS 유출사고대비를 위해서는 물동량 및 유해성이 높은 0~1순위 물질군의 집중관리와 함께 2~3순위 물질군의 정보 구축작업이 지속되어야 한다. 항만별로는 NLS 유통 유형이 다르므로 각 항만의 물질별 유통특성을 파악한 뒤 0~1순위 물질군 위주로 관리하는 것이 효율적일 것으로 판단된다. 또한, 동해남부권역(울산, 부산), 남해중부권역(광양, 여수), 서해중부권역(평택, 대산, 인천)을 NLS 사고대비를 위한 특별관리구역으로 지정하여 해상유통되는 NLS 의 감시 감독을 강화하고 방제 장비, 자재 및 약제를 집중 배치해야 할 것으로 판단된다. 향후, 위해성 DB의 구축과정에서 나타난 위해성 정보 부재 물질들의(만성독성) 지속적인 생산 및 보완이 필요하며, 특히 수생태 독성의 경우 해양생물종을 대상으로 한 자료 생산 및 확보가 지속되어야 할 것이다. 또한, 해상 HNS 사고 관리를 위해서는 HNS 해상유통에 대한 정보를 확인할 수 있는 시스템이 조속히 구축되어야 한다.

낙동강 유역에서의 독성오염물 배출에 따른 수질해석 모형의 개발 (Water Quality Model for the Toxic Pollutant Transport Analysis in the Nakdong River)

  • 한건연;김광섭
    • 물과 미래
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    • 제28권1호
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    • pp.57-70
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    • 1995
  • 낙동강 유역에서의 독성오염물 배출에 따른 수질해석을 위하여 부등류해석과 1차원 Lagrangian 해석기법을 이용한 RIV-LAGI 모형을 개발하였다. 균일하도에 대한 적용결과는 해석해와 잘 일치되고 있었다. 1991년 3월 낙동강 페놀오염시에 대하여 본 RIV-LAGI 모형을 적용한 결과 계산치는 당시의 실측치와 비교하여 일치되고 있었다. 낙동강 유역의 구미-물금 구간에 대한 월별 평균 및 최소유량자료를 기초로 하여 구미공단에서의 독성오염물 방류사고에 따른 하류부 주요 취수장에서의 오염물 유하시간을 계산하여 제시하였다. 본 연구 모형은 낙동강 유역에서의 독성오염물 배출에 따른 수질관리에 기여할 수 있을 것으로 사료된다.

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산전 초음파검사로 진단된 범발성 태변성 복막염 2예보고 (Generalized Meconium Peritonitis Diagnosed with Antenatal Ultrasonography)

  • 김성철;황신;유시준;김인구
    • Advances in pediatric surgery
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    • 제1권1호
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    • pp.59-62
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    • 1995
  • Meconium peritonitis is defined as an aseptic, chemical or foreign-body peritonitis caused by spill of meconium in the abdominal cavity related to the prenatal perforation of the intestine. Perforation is usually caused by obstruction from meconium ileus, intestinal atresia, stenosis, volvulus, internal hernia, congenital peritoneal bands, intussusception, or gastroschisis. Less commonly, no evidence of distal obstruction exists. Here, we present two cases of generalized meconium peritonitis of antenatal diagnosis. The first case, detected at 8 months of gestational age, had a perforation of the proximal blind pouch of jejunal atresia, associated with respiratory distress due to severe abdominal distension. This case was successfully treated with resection and anastomosis and brief period of postoperative ventilatory support. The second case had a distal ileal perforation with thick meconium in the terminal ileum. In this case, there was no dilatation of ileum proximal to the perforation site. Resection and anastomosis was performed and postoperative course was uneventful.

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1차원 비정상상태 하천수질모의를 위한 KORIV1-WIN 개발 (Development of One-Dimensional Unsteady Water Quality Model for River)

  • 정세웅;고익환;김남일
    • 한국수자원학회:학술대회논문집
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    • 한국수자원학회 2004년도 학술발표회
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    • pp.563-567
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    • 2004
  • During drought season, the self-purification capacities of the four major rivers in Korea are significantly controlled by environmental maintenance flows supplied from the mid- or upstream large dams. Therefore, it is obviously important to operate the dams considering not only water quantity aspects but also conservation of downstream water quality and aquatic ecosystems. Mathematical water quality models can be efficiently used to serve as a decision support tool for evaluating the effects of operational alternatives of upstream dams on the downstream aquatic environment. In this study, an unsteady one-dimensional water quality model, KORIV1-WIN was developed based on the theoretical and numerical algorithms for hydrodynamics and water quality simulations of CE-QUAL-RIV1. It consists of hydrodynamic(KORIV1H) and water quality(KORIV1Q) modules, and pre- and post-processors for input data preparations and output displays. The model can be used to predict one-dimensional hydraulic and water quality variations in rivers with highly unsteady flows such as dam outflow change, rainfall-runoff, and chemical spill events.

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유기 다공성 소재의 흡유 효과 (Oil Absorption Effects of Organic Porous Materials)

  • 강영구;한상범
    • 한국안전학회지
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    • 제21권1호
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    • pp.86-91
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    • 2006
  • Oil spills caused by the accidents have been occurred from house and factory waste, grounded tanker, the rupture of storage tank and oil pipelines, the deterioration of various industrial facilities, etc. Many oil spills result in contamination of shorelines and workplace. Fire and explosion may happen from these spills. There are several technologies used for clean-up application, which include use of oil dispersing agents, absorbents, solidifiers, booms and skimmers by physical, chemical, and biological methods. Methods for oil spill clean-up operation are classified into the absorption type, gel type and self-swelling type. Porous materials with oil absorptive properties are classified into micropore, mesopore, and macropore depending on their pore sizes. Recently, new porous materials with smaller size have been developed, but the selective oil absorption in water-in-oil interface demonstrates the macro pore size. In this study oil absorption effects were evaluated using the organic porous materials with a complex function of gel type and swelling type. Samples were subjected to analysis by FT-IR spectroscopy and were characterized in terms of gel formation and morphologies. Oil sorption capacity, pressure retention force and gel strength were also measured. From these results, the physicochemical reactivity before and after gelation was verified and the industrial applications of clean-up operation were suggested.

벨트식 유회수기를 사용한 디젤유 회수에 관한 실험적 연구 (An experimental study on the recovery of diesel oil using a belt type skimmer)

  • 송동업;윤경환
    • 한국해양공학회지
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    • 제11권3호
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    • pp.132-143
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    • 1997
  • Removal of spilled oil over the sea and the river has become one of the urgent problem in these days. Removing oil using mechanical devices are recommended because chemical dispersion can cause the secondary contamination in the environment. In the present study a series of experiments were carried out to study the effect of working conditions of a belt type skimmer on the rate of recovery for the spilled oil. The oil chosen for the present experiment was diesel oil. Three different situations, namely, upward, downward, up-and-downward pickup have been investigated for various contact angles, belt speeds and oil thicknesses. The results show that the rate of oil recovery for the case of downward pickup with a contact angle of 45.deg. shows the highest among all the conditions. For the removal of spilled diesel oil the optimal belt speed can be found as the critical value to reach the saturated pickup rate for a given oil thickness. The recovery rate of bunker C oil shows 4-6 times higher than that for diesel oil. And the optimal belt speed for bunker C oil can be found less than that for diesel oil for the same slick thickness.

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사고 누출 화학물질의 지하수 및 토양 환경 내 거동 및 환경 독성 특성 II: 인화성 물질을 중심으로 (Fate and Toxicity of Spilled Chemicals in Groundwater and Soil Environment II: Flammable)

  • 조은혜;신도연
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제23권6호
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    • pp.1-8
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    • 2018
  • In this study, formaldehyde and benzene were selected as the arbitrary chemicals in accidental leakage to environment, and their physicochemical and biological characteristics and toxicity were studied. Also, the fate of these chemicals in soil and groundwater was studied based on the results of previous studies. They can be released into the atmosphere as gas or vapor phase, which then can be photochemically degraded. Since they have relatively high water solubility, they are likely to have high mobility in water and soil. Volatilization of these chemicals from soil is affected by the soil moisture content. Biodegradation of formaldehyde and benzene is one of the important pathways as well. Therefore, it is necessary to study the environmental impacts of leakage accidents of flammable chemicals such as formaldehyde and benzene. Further research on the fate of flammable chemicals in the environment is needed to take appropriate response actions to leakage accidents of flammable chemicals, and this will contribute to the development of practical guidelines to cope with leakage accidents.