• 제목/요약/키워드: Chemical properties

검색결과 14,304건 처리시간 0.039초

장기저장시 가공 원료잎담배의 이화학성 변화 (The Change of Physical and Chemical Properties of Processed Leaf Tobacco During Long-term Storage)

  • 김상범;안동명;이종철;이경구;조수헌
    • 한국연초학회지
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    • 제23권1호
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    • pp.31-39
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    • 2001
  • This study was carried out to investigate the changes of physical and chemical properties and the usability of long-term stored leaf tobacco. The physical chemical properties of the flue-cured and burley leaves produced in 1993, processed in 1994 were analysed from Nov. 1996 to Nov. 1999. The pH and moisture content in leaf decreased slowly until 4 years’storage after processing, while those of leaf changed little thereafter. However, total sugar content continuously decreased until 5 years after processing. The filling capacity increased and shatter resistance index decreased in long-term stored leaf. The sensory test, cilia stasis and the chemical components of cigarette smoke had no significant differences between short and long-term stored leaves. When the processed leaves were stored till 5 years after processing, there were no deteriorative effects on quality and usability of leaf tobacco. Therefore, it is considered that the processed leaf may be stored for 5 years or more under the inevitable situation.

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Assessing Changes in Selected Soil Chemical Properties of Rice Paddy Fields in Gyeongbuk Province

  • Park, Sang-Jo;Park, Jun-Hong;Won, Jong-Gun;Seo, Dong-Hwan;Lee, Suk-Hee
    • 한국토양비료학회지
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    • 제50권3호
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    • pp.150-161
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    • 2017
  • This study was conducted with the data of monitoring on soil chemical properties of rice paddy soils in Gyeongbuk Province. The selected soil chemical properties were analyzed every 4 year from 1999 to 2015. The soil pH measured in 2015 was higher than pH 6.0, which was 0.3-0.4 pH unit higher than data until 2007 survey year. The mean content of organic matter was greater than $24g\;kg^{-1}$ since 2003, but 35% of soil samples remained below the recommended level ($20-30g\;kg^{-1}$) in 2015. The mean concentration of available phosphate was maintained at $40mg\;kg^{-1}$ higher than the upper recommendation level ($80-120mg\;kg^{-1}$), and more than 40% of paddy soils tested were found to have less than the recommendation level during the survey period. The exchangeable K concentration ranged from 0.25 to $0.39cmol_c\;kg^{-1}$. Exchangeable Ca showed an average at the optimum range ($5.0-6.0cmol_c\;kg^{-1}$) during the monitoring period. Exchangeable Mg decreased linearly ($0.02cmol_c\;kg^{-1}\;year^{-1}$) from $1.55cmol_c\;kg^{-1}$ as of 1999 to below the lower level of the recommendation range ($1.5-2.0cmol_c\;kg^{-1}$). The amount of available $SiO_2$ was increased significantly from 2011 to over the recommendation level (${\geq}157mg\;kg^{-1}$). It was revealed that the soil chemical properties of rice paddy fields was influenced by topology, soil texture, type and region as result of principal component analysis or cluster analysis. Therefore, an assessment on chemical properties of rice paddy soils should be performed to consider various soil physical conditions and agronomic practices such as fertilization, cropping system, and so on. Because of the high variability of nutrient levels across Gyeongbuk Province, nutrient management based on soil fertility test is required by respective farm land unit.

석문 간척지에서 돈분액비 및 석고처리가 여름철 사료작물 수량 및 토양이화학성에 미치는 영향 (Effects of Soil Amendment Application on Soil Physico-chemical Properties and Yields of Summer Forage Crops in the Sukmoon Reclaimed Tidal Land in Korea)

  • 최기춘;윤세형;신재순;김동관;한효심;수판자니;이경동
    • 한국환경농학회지
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    • 제29권4호
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    • pp.354-361
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    • 2010
  • Soil physico-chemical properties and microbial densities are affected by organic sources and soil amendment applied to improve soil environments or quality. Generally organic fertilizer effects on forage crops yield and soil properties are partly due to changes of soil composition. We investigated the effects of swine slurry (SS), swine slurry composting-biofilteration(SCB) and chemical fertilizer(F) with gypsum(G) combinations on soil physico-chemical properties and yields of summer forage crop in the Sukmoon reclaimed tidal land in Korea. The forage crops used in this experiment were corn and sorghum$\times$sudangrass hybrid(hereafter sorghum). Our results showed that the soil physico-chemical properties in the combined (F+G, SS+G, SCB+G) treatments increased contents of organic matter and exchangeable $Ca^{2+}$, but exchangeable $Na^+$, $K^+$ and $Mg^{2+}$ reduced to 1-10% for two forage crops, compared to non-combined (F, SS, SCB) treatment. The density of soil microorganism such as bacteria, actinomycetes and fungi, increased significantly by SS+G and SCB+G treatments. This means that treatment of combined organic fertilizer with G lowered salinity levels and improved with microbial growth. The combined treatments also increased the total yields 2.3-6.2% for corn and 2.0-8.7% for sorghum, compared with non-combined treatment. This experiment suggests the combined treatments could increase the total yields of summer forage crops and change of soil physico-chemical properties in the Sukmoon reclaimed tidal land in Korea.

탄화규소의 첨가가 탄소섬유 강화 복합재료의 열안정성 및 기계적 계면특성에 미치는 영향 (Influence of SiC on Thermal Stabilities and Mechanical Interfacial Properties of Carbon Fibers-reinforced Composites)

  • 오진석;박수진;이재락;김영근
    • 한국복합재료학회:학술대회논문집
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    • 한국복합재료학회 2004년도 춘계학술발표대회 논문집
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    • pp.182-185
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    • 2004
  • In this work, the effect of chemical treatments on surface properties of SiC was investigated in mechanical interfacial properties of carbon fibers-reinforced composites. The surface properties of the SiC were determined by acid/base values and contact angles. The thermal stabilities of carbon fibers-reinforced composites were investigated by thermogravimetric analysis (TGA). Also, the mechanical interfacial properties of the composites were studied in interlaminar shear strength (ILSS) and critical strain energy release rate mode II $(G_{IIC})$ measurements. As a result, tile acidically treated SiC (A-SiC) had higher acid value than that of untreated SiC (V-SiC) or basically treated SiC (B-SiC). According to the contact angle measurements, it was observed that chemical treatments led to an increase of surface free energy of the SiC surfaces, mainly due to the increase of the specific (polar) component. The mechanical interfacial properties of the composites, including ILSS and $(G_{IIC})$, had been improved in the specimens treated by chemical solutions. These results were explained that good wetting played an important role in improving the degree of adhesion at interfaces between SiC and epoxy resin matrix.

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Spatial Analyses of Soil Chemical Properties from a Remodeled Paddy Field as Affected by Wet Land Leveling

  • Jung, Ki-Yuol;Choi, Young-Dae;Lee, Sanghun;Chun, Hyen Chung;Kang, Hang-Won
    • 한국토양비료학회지
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    • 제49권5호
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    • pp.555-563
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    • 2016
  • Uniformity and leveled distributions of soil chemicals across paddy fields are critical to manage optimal crop yields, reduce environmental risks and efficiently use water in rice cultivation. In this study, an investigation of spatial distributions on soil chemical properties was conducted to evaluate the effect of land leveling on mitigation of soil chemical property heterogeneity from a remodeled paddy field. The spatial variabilities of chemical properties were analyzed by geostatistical analyses; semivariograms and kriged simulations. The soil samples were taken from a 1 ha paddy field before and after land leveling with sufficient water. The study site was located at Bon-ri site of Dalseong and river sediments were dredged from Nakdong river basins. The sediments were buried into the paddy field after 50 cm of top soils at the paddy field were removed. The top soils were recovered after the sediments were piled up. In order to obtain the most accurate spatial field information, the soil samples were taken at every 5 m by 5 m grid point and total number of samples was 100 before and after land leveling with sufficient water. Soil pH increased from 6.59 to 6.85. Geostatistical analyses showed that chemical distributions had a high spatial dependence within a paddy field. The parameters of semivariogram analysis showed similar trends across the properties except pH comparing results from before and after land leveling. These properties had smaller "sill" values and greater "range" values after land leveling than ones from before land leveling. These results can be interpreted as land leveling induced more homogeneous distributions of soil chemical properties. The homogeneous distributions were confirmed by kriged simulations and distribution maps. As a conclusion, land leveling with sufficient water may induce better managements of fertilizer and water use in rice cultivation at disturbed paddy fields.

Isosorbide가 함유된 바이오 기반 PET와 polycarbonate 블렌드의 제조 및 특성 연구 (Preparation and characterization of isosorbide based PET/polycarbonate blends)

  • 박지수;남병욱;박준서
    • 한국산학기술학회논문지
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    • 제15권2호
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    • pp.1216-1221
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    • 2014
  • PEIT는 옥수수와 같은 재생 가능한 자원에서 유래한 isosorbide monomer를 이용하여 bio-contents를 함유하고 있는 PET이다. 하지만 isosorbide contents가 향상될수록 기계적물성이 감소하는 단점이 있다. 본 연구에서는 우수한 기계적 물성을 가지고 있는 polycarbonate를 이용하여 PEIT의 단점을 보완하고, 또한 PEIT를 이용하여 PC의 인장신율 향상을 통해 성형가공성을 개선하고자 하였다. 이축압출기를 통해 제조한 PEIT/PC 블렌드에서 polycarbonate가 모폴로지, 유리전이온도거동, 열적안정성 및 기계적 물성에 미치는 영향을 확인하기 위해 FE-SEM, DMA, TGA, UTM 및 Izod impact tester를 통하여 분석을 수행하였다. 이로써 우수한 기계적 물성을 가진 polycarbonate는 PEIT와 상용성이 있음을 확인하였으며, 특히 PEIT25PC75 조성에서 열적 안정성 및 기계적 특성의 향상이 뛰어난 것을 알 수 있었다.

한국 밭토양 화학성 변동 평가 (Status and Changes in Chemical Properties of Upland Soil from 2001 to 2017 in Korea)

  • 김이현;공명석;이은진;이태구;정구복
    • 한국환경농학회지
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    • 제38권3호
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    • pp.213-218
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    • 2019
  • BACKGROUND: Monitoring of the dynamic changes of chemical properties in agricultural land is very important for agricultural sustainability. Chemical properties of agricultural soils in Korea have been investigated at four-year interval in the order of paddy, plastic film house, upland, and orchard soils since 1999. METHODS AND RESULTS: Total 8,160 topsoil samples were taken from the upland in 2001, 2005, 2009, 2013, and 2017, respectively. Soil chemical properties such as pH, electrical conductivity (EC), organic matter (OM), available phosphate (Avail. $P_2O_5$), and exchangeable (Exch.) cations (K, Ca, and Mg) were analyzed. Soil pH and Exch. Ca contents have increased since 2001. Average concentration of Avail. $P_2O_5$ increased from $547mg\;kg^{-1}$ in 2001 to $657mg\;kg^{-1}$ in 2017. Average concentration of Exch. Ca in 2017 was higher than the upper limit of its optimal range for upland cultivation. Excess and deficiency of chemical properties of upland soils comply with soil analysis and fertilizer prescription. CONCLUSION: We concluded that excessive nutrient in upland needed to be properly managed with soil test.

1,4-Bisdiazo-2-butene의 合成과 그 化學的 性質의 硏究 (Synthesis and Study of the Chemical Properties of 1,4-Bisdiazo-2-butene)

  • 이학기
    • 대한화학회지
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    • 제13권4호
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    • pp.333-339
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    • 1969
  • Synthesis and chemical properties of 1,4-bisdiazo-2-butene have been studied. 1,4-Bisdiazo-2-butene which was very unstable produced in protic solvents 1,3-butadiene and one unidentified substance instead of ring compounds. The reaction in aprotic solvents remains for further investigations.

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Influences of solvent-exchange drying on the properties of cellulose hollow fiber membranes

  • Jie, Xingming;Cao, Yiming;Wu, Ming;Yuan, Quan
    • 한국막학회:학술대회논문집
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    • 한국막학회 2004년도 Proceedings of the second conference of aseanian membrane society
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    • pp.69-69
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    • 2004
  • Cellulose hollow fiber membranes (CHFM) were prepared from the cellulose/N-methylmorpholine-N-oxide/$H_2O$ system by immersion-precipitation and wet spinning. Different drying methods were carried out to investigate their influences on the properties of CHFM.(omitted)

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Effect of rheological properties on chemical absorption of carbon dioxide with MEA

  • Park, Sang-Wook;Kim, Tae-Young;Park, Byoung-Sik;Lee, Jae-Wook
    • Korea-Australia Rheology Journal
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    • 제16권1호
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    • pp.35-45
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    • 2004
  • Rates of chemical absorption of $CO_2$ in water-in-oil (w/o) emulsion were measured in a flat-stirred vessel at $25^{\circ}C$. The w/o emulsion was composed of aqueous monoethanolamine (MEA) droplets as a dispersed phase and non-Newtonian viscoelastic benzene solutions of polybutene (PB) and polyisobutylene (PIB) as a continuous phase. The liquid-side-mass transfer coefficient ($k_L$) was obtained from the dimensionless empirical equation containing Deborah number expressed as the properties of pseudoplasticity of the non-Newtonian liquid. $k_L$ was used to estimate the enhancement factor due to chemical reaction between $CO_2$ and MEA in the aqueous phase. PIB with elastic property of non-Newtonian liquid made the rate of chemical absorption of $CO_2$ accelerate compared with Newtonian liquid.