• Title/Summary/Keyword: Chemical oxygen demand (COD)

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Treating Swine Wastewater by Anaerobic Bioreactors (혐기성 생물반응기에 의한 축산폐수의 처리)

  • Lee, Gook-Hee;Kim, Jong-Soo
    • Korean Journal of Environmental Agriculture
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    • v.18 no.1
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    • pp.54-60
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    • 1999
  • Three different types of lab-scale anaerobic bioreactors, AF and two-stage ASBF-PR and ASBF-SP, were evaluated in treating swine wastewater by operating at $1{\sim}2$ days of hydraulic retention time with increasing organic loading rate upto 6.3 $kg-COD/m^3{\cdot}d$ at $35^{\circ}C$. Seeding the anaerobic bioreactors with waste anaerobic digester sludge from a municipal wastewater treatment plant was effective and a 40-day acclimation period was required for steady-state operation. Three anaerobic bioreactors were effective in treating swine wastewater with COD removal efficiency of $66.4{\sim}84.9$% and biogas production rate of $0.333{\sim}0.796m^3/kg-COD_{removed}{\cdot}d$. Increases of organic loading rate by increasing influent COD concentration and/or decreasing hydraulic retention time caused decreases in COD removal efficiency and increases in biogas production rate. At relatively high organic loading rate employed in this study, the treatment efficiency of AF and ASBF-PR were similar but superior than that of ASBF-SP, indicating that porosity and pore size of the media packed in the bioreactors are more important factors contributing the performance of to bioreactors than specific surface area of the media. TKN in swine wastewater must be removed prior to the anaerobic processes when anaerobic process is considered as a major treatment process since influent TKN concentration of $1,540{\sim}1,870mg/L$ to the bioreactors adversely affect the activity of methanogenic bacteria, resulting in decreases of treatment efficiency and biogas production rate by 50%.

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Effect of the Addition of Granular Activated Carbon and Granular Sludge on the Performance of Upflow Anaerobic Sludge Blanket Reactors for Treating Leachate (상향류 혐기성 슬러지 블랭킷 반응조를 이용한 침출수 처리시 입상 활성탄 및 입상슬러지 첨가의 영향)

  • Lee, Chae-Young
    • Journal of the Korea Organic Resources Recycling Association
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    • v.16 no.4
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    • pp.91-97
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    • 2008
  • The objective of this research is to investigate the effect of the addition of granular activated carbon (GAC) and granular sludge on the performance of upflow anaerobic sludge blanket (UASB) reactors for treating leachate. For the control reactor, sludge obtained from an anaerobic digester was used as a seed material. On the other hand, GAC and granular sludge were incorporated with the seed sludge in the GAC reactor and the Granule reactor, respectively. The shortest acclimation period was observed in the Granule reactor. The GAC reactor also gave comparable performance to the Granule reactor at the beginning of operation. However, as the adsorptive capacity of GAC was exhausted, the effluent COD concentration increased gradually. Once the systems were stabilized, the GAC reactor showed slightly better results than the other two reactors in terms of chemical oxygen demand (COD) removal. COD removal in all reactors was more than 90% at hydraulic retention time of 1.0 day. Furthermore, GAC reactor showed little variation in COD removal rate and remained at 95% with organic loading rate (OLR) of 4.0 to $8.2kg\;COD/m^3.d$. Initial operating period was reduced by the addition of granular sludge, while the treatment efficiency was enhanced by the addition of GAC.

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Long-Term Variations of Water Quality in Jinhae Bay (진해만의 장기 수질변동 특성)

  • Kwon, Jung-No;Lee, Jangho;Kim, Youngsug;Lim, Jae-Hyun;Choi, Tae-Jun;Ye, Mi-Ju;Jun, Ji-Won;Kim, Seulmin
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.17 no.4
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    • pp.324-332
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    • 2014
  • In order to reveal the long-term variations of water quality in Jinhae Bay, water qualities had been monitored at 9 survey stations of Jinhae Bay during 2000~2012. The surface and bottom waters concentrations of chemical oxygen demand (COD), dissolved inorganic nitrogen (DIN), dissolved inorganic phosphorus (DIP), and chlorophyll-a (Chl.-a) were higher at the survey stations of Masan Bay than the stations of other Bays. Especially, station 1 which is located at the inner area of Masan Bay had the highest values in the concentrations of COD, DIN, and Chl.-a because there were terrestrial pollutant sources near the station 1 and sea current had not well circulated in the inner area of Masan Bay. In factor analysis, the station 1 also had the highest factor values related to factors which increase organic matters and nutrients in surface and bottom waters of Masan Bay. However, the stations (st.5, st.6, st.7, st.8, and st.9) of other Bays had lower values of the factors. In time series analysis, the COD concentrations of the bottom waters at 8 stations except for station 1 distinctly decreased. However, the COD concentrations of the surface waters showed no distinct decrease trends at all stations. In the concentrations of nutrients (DIN and DIP) of both surface and bottom waters, there were tremendous decrease trends at all stations. Therefore, these distinct decrease trends of the COD in bottom waters and the nutrients in surface and bottom waters of Jinhae Bay could have been associated with water improvement actions such as TPLMS (total pollution load management system).

Assessment of Seasonal Variation in Water Quality in Daedong Lake (대동호의 시기별 및 계절별 수질변화 평가)

  • Yun, Jin-Ju;Kang, Se-Won;Park, Jong-Hwan;Seo, Dong-Cheol;Kim, Hyun-Woo;Cho, Ju-Sik
    • Korean Journal of Environmental Agriculture
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    • v.39 no.3
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    • pp.197-203
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    • 2020
  • BACKGROUND: Most lakes have increased concerns about water pollution due to the inflow of non-point sources caused by human activities. Therefore, the lake water quality survey was conducted in order to propose effective plans for water quality management by analyzing the characteristics of lakes and the change of water quality. METHODS AND RESULTS: In order to investigate the physicochemical water quality in Daedong lake, water quality analysis was undertaken from July 2018 to June 2019. Water temperature was ranged from 7.8 to 34.3℃ and pH varied from 6.9 to 10.2. The concentration of Dissolved oxygen, Suspended solid, Biochemical Oxygen Demand (BOD), and Chemical Oxygen Demand (COD) were 5.6 ~ 17.2 mg/L, 2.4 ~ 35.3 mg/L, and 4.5 ~ 15.1 mg/L, and 0.9 ~ 2.8 mg/L, respectively. The Total Nitrogen (T-N) concentration ranged from 0.974 ~ 2.126 mg/L, and Total Phosphorus (T-P) concentration ranged from 0.014 ~ 0.057 mg/L. The Chlorophyll-a (Chl-a) ranged from 2.7 ~ 37.9 mg/㎥. Through Carlson TSIm assessment using T-P and Chl-a results, evaluating trophic state, Daedong lake was evaluated as mesotrophic. CONCLUSION: Water pollution management plan needs such as nutrient removal technology and nonpoint source management for prevention of eutrophication in Daedong lake.

Water Quality Assessment and Turbidity Prediction Using Multivariate Statistical Techniques: A Case Study of the Cheurfa Dam in Northwestern Algeria

  • ADDOUCHE, Amina;RIGHI, Ali;HAMRI, Mehdi Mohamed;BENGHAREZ, Zohra;ZIZI, Zahia
    • Applied Chemistry for Engineering
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    • v.33 no.6
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    • pp.563-573
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    • 2022
  • This work aimed to develop a new equation for turbidity (Turb) simulation and prediction using statistical methods based on principal component analysis (PCA) and multiple linear regression (MLR). For this purpose, water samples were collected monthly over a five year period from Cheurfa dam, an important reservoir in Northwestern Algeria, and analyzed for 12 parameters, including temperature (T°), pH, electrical conductivity (EC), turbidity (Turb), dissolved oxygen (DO), ammonium (NH4+), nitrate (NO3-), nitrite (NO2-), phosphate (PO43-), total suspended solids (TSS), biochemical oxygen demand (BOD5) and chemical oxygen demand (COD). The results revealed a strong mineralization of the water and low dissolved oxygen (DO) content during the summer period. High levels of TSS and Turb were recorded during rainy periods. In addition, water was charged with phosphate (PO43-) in the whole period of study. The PCA results revealed ten factors, three of which were significant (eigenvalues >1) and explained 75.5% of the total variance. The F1 and F2 factors explained 36.5% and 26.7% of the total variance, respectively and indicated anthropogenic pollution of domestic agricultural and industrial origin. The MLR turbidity simulation model exhibited a high coefficient of determination (R2 = 92.20%), indicating that 92.20% of the data variability can be explained by the model. TSS, DO, EC, NO3-, NO2-, and COD were the most significant contributing parameters (p values << 0.05) in turbidity prediction. The present study can help with decision-making on the management and monitoring of the water quality of the dam, which is the primary source of drinking water in this region.

TiO2 Photocatalytic Reaction on Glass Fiber for Total Organic Carbon Analysis (총유기탄소 분석을 위한 유리섬유를 이용한 이산화티타늄 광촉매 반응)

  • Park, Buem Keun;Lee, Young-Jin;Shin, Jeong Hee;Paik, Jong-Hoo
    • Journal of Sensor Science and Technology
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    • v.31 no.2
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    • pp.102-106
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    • 2022
  • Currently, the demand for real-time monitoring of water quality has increased dramatically. Total organic carbon (TOC) analysis is a suitable method for real-time analysis compared with conventional biochemical oxygen demand (BOD) and chemical oxygen demand (COD) methods in terms of analysis time. However, this method is expensive because of the complicated internal processes involved. The photocatalytic titanium dioxide (TiO2)-based TOC method is simpler as it omits more than three preprocessing steps. This is because it reacts only with organic carbon (OC) without extra processes. We optimized the rate between the TiO2 photocatalyst and binder solution and the TiO2 concentration. The efficiency was investigated under 365 nm UV exposure onto a TiO2 coated substrate. The optimized conditions were sufficient to apply a real-time monitoring system for water quality with a short reaction time (within 10 min). We expect that it can be applied in a wide range of water quality monitoring industries.

Using response surface methodology and Box-Behnken design in the study of affecting factors on the dairy wastewater treatment by MEUF

  • Khosroyar, Susan;Arastehnodeh, Ali
    • Membrane and Water Treatment
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    • v.9 no.5
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    • pp.335-342
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    • 2018
  • Micelle-Enhanced Ultrafiltration (MEUF) is a membrane separation processes that improving ultrafiltration process with the formation of micelles of the surface active agents. Surface active agents are widely used to improve membrane processes due to the ability to trap organic compounds and metals in the treatment of industrial waste water. In this study, surface active agents are used to improve micelle-enhanced ultrafiltration (MEUF) to reduce chemical oxygen demand (COD), total dissolved solid (TDS), turbidity and clogging the membrane in dairy wastewater treatment. Three important operational factors (anionic surface active agent concentration, pressure and pH) and these interactions were investigated by using response surface methodology (RSM) and Box-Behnken design. Results show that due to the concentration polarization layer and increase the number of Micelles; the anionic surface active agent concentration has a negative effect on the flux and has a positive effect on the elimination of contamination indices. pH, and the pressure have the greatest effect on flux. On the other hand, it could be stated that these percentages of separation are in the percentages range of Nano-filtration (NF). While MEUF process has higher flux than NF process. The results have been achieved at lower pressure while NF process needs high pressure, thus making MEUF is the replacement for the NF process.

Measurement of Waste Generation in Seawater Aquaria by Common Conger (Astroconger myriaster) arld Olive Flounder (Paralichyhus olivaceus) (해수활어수조에서 붕장어 (Astroconger myriaster)와 넙치 (Puralichyhus olivaceus)에 의한 오염물 발생량 산정)

  • SUH Kuen-Hack;SHIN Jeong-Sik;JO Jae-Yoon
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.37 no.6
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    • pp.492-497
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    • 2004
  • Waste concentration and waste generation rate in seawater aquaria by common conger (Astrocongey myriaster) and olive flounder (Paralichyhus olivaceus) were investigated. The initial fish density of common conger and olive flounder were $3{\%}\;and \;2.8{\%}$ of total weight of aquarium water, respectively Wastes in the seawater aquaria, such as protein, total suspended solid (TSS), ammonia, turbidity and chemical oxygen demand (COD) increased with days after stocking. Protein generation rate of common conger increased until 1 day after stocking while that of olive flounder increased until 3 days. The average protein generation rates of common conger and olive flounder were $0.28g/kg{\cdot}day\;and\;0.21g/kg{\cdot}day$, respectively. The trends of other waste generation rate were similar to protein generation rate.

Evaluation of Pollutant Removal Efficiency in Environmentally Friendly Full-scale Constructed Wetlands for Treating Domestic Sewage during Long-term Monitoring (장기 모니터링을 통한 환경친화형 인공습지 하수처리장의 수질정화효율 평가)

  • Seo, Dong-Cheol;Jo, In-Seong;Lim, Seok-Cheon;Lee, Byeong-Ju;Park, Seong-Kyu;Cheon, Yeong-Seok;Park, Jong-Hwan;Lee, Hong-Jae;Cho, Ju-Sik;Heo, Jong-Soo
    • Korean Journal of Environmental Agriculture
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    • v.28 no.2
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    • pp.97-105
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    • 2009
  • A constructed wetland which was composed of aerobic and anaerobic areas was evaluated for 3 years to effectively treat the sewage produced in farming and fishing communities. For 3 years in a constructed wetland, biochemical oxygen demand(BOD), chemical oxygen demand(COD), suspended solids(SS), total nitrogen(T-N), and total phosphorus(T-P) in effluent were 0.2${\sim}$11.8, 1.0${\sim}$41.9, 1.1${\sim}$6.5, 4${\sim}$60 and 0.02${\sim}$3.51 mg/L, respectively. Removal rate of BOD, COD and SS in effluent were 97, 92 and 99%, respectively, in the third year. As time goes by, removal rate of T-N and T-P in treated water in aerobic area and effluent were gradually increased in a constructed wetland. In the third year, removal rate in effluent were 62 and 73%, respectively. By the seasons, removal rate of BOD, COD, SS, T-N and T-P were 97${\sim}$98, 87${\sim}$91, 99, 43${\sim}$61 and 76${\sim}$86%, respectively. Removal rate of BOD, COD, SS and T-P were not affected by the seasons, but that of T-N in winter and spring were decreased than the other seasons.

Water Management Plan for the Nakdong River Using TOC and COD (총유기탄소와 화학적산소요구량을 이용한 낙동강 물관리 방안)

  • Bo Eun Kim;Meea Kang;Gyo-Cheol Jeong
    • The Journal of Engineering Geology
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    • v.33 no.1
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    • pp.51-59
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    • 2023
  • The Nakdong river is both a natural resource crucial to underwater ecosystems and a water source for its basin's residents. Industrial wastewater and domestic sewage must meet the relevant standards for discharged water before they can flow into the river. The correlation between old and new measures of organic matter was examined using water quality data from 50 monitoring locations in the main stream of the Nakdong river. The coefficient of determination (R2) for total organic carbon (TOC), the new measure of organic matter, and chemical oxygen demand (COD), the old measure of organic matter, in the main stream of the Nakdong river was 0.6134, indicating high correlation. Water quality at each location assessed using TOC and COD showed disparities that cannot be ignored: quality appeared higher when evaluating the main stream of the Nakdong river using TOC instead of COD. Therefore, there remains a need to review water quality ratings based on TOC; continuous monitoring of COD is also required. In addition, the cause of the difference should be clearly identified to help assess artificial sources of pollution and natural factors affecting organic matter. Water management of the Nakdong river will then be possible using the water quality rating.