• Title/Summary/Keyword: Chemical heat pump

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Chemical and Physical Influence Factors on Performance of Bentonite Grouts for Backfilling Ground Heat Exchanger (지중 열교환기용 벤토나이트 그라우트의 시공성에 대한 화학적, 물리적 영향 요소에 관한 연구)

  • Lee, Chul-Ho;Gil, Hu-Jeong;Lee, Kang-Ja;Choi, Hang-Seok;Choi, Hyo-Pum
    • Proceedings of the Korean Geotechical Society Conference
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    • 2008.10a
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    • pp.1475-1486
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    • 2008
  • Bentonite-based grouting has been popularly used to seal a borehole installed for a closed-loop vertical ground heat exchanger in a geothermal heat pump system (GHP) because its high swelling potential. However, if the bentonite-based grouting is conducted in coastal areas, the salinity of groundwater changes in the mineral fabric of bentontie. In order words, an increase of cation concentration in groundwater leads to a reduction in the diffuse double-layer thickness in the bentonite mineral structure, and thus the volume of bentointe-based grouts will decrease proportional to the salinity of groundwater. In this paper, the effect of salinity (i.e., NaCl 0.5M, 0.25M, and 0.1M) on the change of swelling potential for bentonite-based grouts has been quantitatively evaluated for seven bentonite grouts from different product sources. In addition, in case of using addictives such as a silica sand to increase the thermal conductivity of bentonite-based grouts, the possibility of particle segregation has been studied considering the viscosity of grouts and salinity of groundwater.

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Consequence Analysis for Fire and Explosion Accidents in Propylene Recovery Process (프로필렌 회수공정에서 화재 및 폭발 사고의 피해영향 해석)

  • Han, Seong-Hwan;Lee, Hern-Chang;Park, Kyoshik;Kim, Tae-Ok
    • Journal of the Korean Institute of Gas
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    • v.18 no.1
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    • pp.52-60
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    • 2014
  • This study aims to suggest risk management plan including safety measures through hazard identification followed by consequence analysis in petrochemical plants. Consequence analysis was performed through practical release scenario by using PHAST RISK(ver. 6.7) software in the propylene recovery process(PRP). As results, consequences by fire or explosion accidents in the depropanizer zone, deethanizer zone and heat pump zone were relatively larger than other else zones among six process zones in the PRP. In the case of jet fire, it is recommendable not to install residence building within 200 m of the process zone. Additionally, process zones having large inventory or high pressure must be prevented from accidents and required to establish quick response against accidents.

Energy Efficiency Evaluation of Heating and Cooling Systems as Space Program in Renovated Library (도서관의 공간사용 특성에 따른 냉난방설비 리모델링의 경제성 평가)

  • Park, Kang-Hyun;Cha, Jung-Hoon;Kim, Su-Min;Park, Kyung-Won
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.24 no.3
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    • pp.205-211
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    • 2012
  • Unlike the previous approaches, we analyzed for economic efficiency of renewed heating and cooling systems as the characteristics of space. The purpose of this study is to analysis the energy consumption and economical efficiency of absorption chillers and EHP systems in renovated library. It is important that equipment selection should be considering energy cost as well as space program. In recently, many EHP systems were installed in the building for reducing the energy cost and for seeking the convenience of individual control. In contrast, though absorption chillers have the disadvantage of a central control, absorption chillers are appropriate for the conditions of the library that needs simultaneous operation. The results by payback period method, show that selection of heating and cooling systems should be consider for space program and the characteristics of space.

Flow Characteristics Evaluation in Reactor Coolant System for Full System Decontamination of Kori-1 Nuclear Power Plant (고리1호기 계통제염을 위한 원자로냉각재내 유동 특성 평가)

  • Kim, Hak Soo;Kim, Cho-Rong
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.16 no.3
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    • pp.389-396
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    • 2018
  • The Kori-1 Nuclear Power Plant (NPP), WH 2-Loop Pressurized Water Reactor (PWR) operated for approximately 40 years in Korea, was permanently ceased on June 18, 2017. To reduce worker exposure to radiation by reducing the dose rate in the system before starting main decommissioning activities, the permanently ceased Kori-1 NPP will be subjected to full system decontamination. Generally, the range of system decontamination includes Reactor Pressure Vessels (RPV), Pressurizer (PZR), Steam Generators (SG), Chemical & Volume Control System (CVCS), Residual Heat Removal System (RHRS), and Reactor Coolant System (RCS) piping. In order to decontaminate these systems and equipment in an effective manner, it is necessary to evaluate the influence of the flow characteristics in the RCS during the decontamination period. There are various methods of providing circulating flow rate to the system decontamination. In this paper, the flow characteristics in Kori-1 NPP reactor coolant according to RHR pump operation were evaluated. The evaluation results showed that system decontamination using an RHR pump was not effective at decontamination due first to impurities deposited in piping and equipment, and second to the extreme flow unbalance in the RCS caused deposition of impurities.

A Study on the Simulation of Chemical Heat Pump System Based on 2-Propanol /Acetone/Hydrogen System (2-Propanol/Acetone/Hydrogen 반응계로 구성된 화학적 열펌프 시스템의 모사 연구)

  • 김범재;여영구;정연수;송형근
    • Journal of the Korea Society for Simulation
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    • v.5 no.1
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    • pp.43-50
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    • 1996
  • 2-propanol/acetone/hydrogen 반응계로 구성된 화학적 열펌프 시스템은 낮은 온도(82.5~$90^{\circ}C$)에서의 2-propanol의 탈수소화 반응과 높은 온도(약 $200^{\circ}C$ 부근)에서의 acetone의 수소화반응을 이용하여 열을 고품위화 시키는 장치이다. 본 연구에서는 이 시스템의 해석 및 설계를 목적으로 이 시스템에 대한 수치적인 모델들을 세우고 Sequential modular approach를 이용하여 시스템의 모사를 수행하였다. 또한 에너지 효율을 최대화하기 위하여 열펌프 시스템에서의 환류비의 영향을 규명하였다. 모사결과 이 시스템의 scale up을 위한 정량적인 정상상태 운전조건들을 구할수 있었으며 두 반응의 반응 전화율이 다르더라도 반응물의 유량의 차이를 통하여 두 반응열이 거의 같아지는 것을 알수 있었다. 아울러 주어진 운전조건에서 증류의 환류비는 최소환류비 근처의 최적값이 존재함을 알수 있었다.

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Optimal Design of Urban MICROGRID using Economical Analysis Program (경제성분석 프로그램을 이용한 도심형 마이크로그리드 최적 설계)

  • Seung-Duck, Yu;SungWoo, Yim;Youseok, Lim;SungWook, Hwang;JuHak, Lee
    • KEPCO Journal on Electric Power and Energy
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    • v.8 no.2
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    • pp.69-72
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    • 2022
  • This paper actually investigates the load on major large-scale buildings in the downtown area, examines the economic feasibility of installing PV and ESS in a microgrid target building, and evaluates whether an electric vehicle capable of V2G through two buildings is effective as an economical analysis program (HOMER) was analyzed using. It is economical to install a mixture of ESS rather than using the whole PV, and it is shown that if there is an electric vehicle using the V2G function of EV, there is an economic effect to replace the PV. So that Incentives and policies are needed to replace a large area of PV and utilize the existing parking lot to lead EV as a resource of the microgrid. Currently, P2X technology that stores power as ESS or converts it to other energy to control when surplus renewable energy occurs in large-capacity solar power plants and wind farms, etc. This is being applied, and efforts are being made to maintain the stability of the system through the management of surplus power, such as replacing thermal energy through a heat pump. Due to the increase in electric vehicles, which were recognized only as a means of transportation, technologies for using electric vehicles are developing. Accordingly, existing gas stations do not only supply traditional chemical fuels, but electricity, and super stations that also produce electricity have appeared. Super Station is a new concept power plant that can produce and store electricity using solar power, ESS, V2G, and P2G. To take advantage of this, research on an urban microgrid that forms an independent system by tying a large building and several buildings together and supplies power through a super station around the microgrid is in full swing.

Chemical and Physical Influence Factors on Performance of Bentonite Grouts for Backfilling Ground Heat Exchanger (지중 열교환기용 멘토나이트 뒤채움재의 화학적, 물리적 영향 요소에 관한 연구)

  • Lee, Chul-Ho;Wi, Ji-Hae;Park, Moon-Seo;Choi, Hang-Seok;Shon, Byong-Hu
    • Journal of the Korean Geotechnical Society
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    • v.26 no.12
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    • pp.19-30
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    • 2010
  • Bentonite-based grout has been widely used to seal a borehole constructed for a closed-loop vertical ground heat exchanger in a geothermal heat pump system (GHP) because of its high swelling potential and low hydraulic conductivity. Three types of bentonites were compared one another in terms of viscosity and thermal conductivity in this paper. The viscosity and thermal conductivity of the grouts with bentonite contents of 5%, 10%, 15%, 20% and 25% by weight were examined to take into account a variable water content of bentonite grout depending on field conditions. To evaluate the effect of salinity (i.e., concentration of NaCl : 0.1M, 0.25M, and 0.5M) on swelling potential of the bentonite-based grouts, a series of volume reduction tests were performed. In addition, if the viscosity of bentonite-water mixture is relatively low, particle segregation can occur. To examine the segregation phenomenon, the degree of segregation has been evaluated for the bentonite grouts especially in case of relatively low viscosity. From the experimental results, it is found that (1) the viscosity of the bentonite mixture increased with time and/or with increasing the mixing ratio. However, the thermal conductivity of the bentonite mixture did not increase with time but increased with increasing the mixing ratio; (2) If bentonite grout has a relatively high swelling index, the volume reduction ratio in the saline condition will be low; (3) The additive, such as a silica sand, can settle down on the bottom of the borehole if the bentonite has a very low viscosity. Consequently, the thermal conductivity of the upper portion of the ground heat exchanger will be much smaller than that of the lower portion.

Comparison of Phytoncide (monoterpene) Concentration by Type of Recreational Forest (산림휴양지 유형에 따른 피톤치드(모노테르펜) 농도 비교)

  • Lee, Yong-Ki;Woo, Jung-Sik;Choi, Si-Rim;Shin, Eun-Sang
    • Journal of Environmental Health Sciences
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    • v.41 no.4
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    • pp.241-248
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    • 2015
  • Objectives: This study was conducted to provide scientific and effective information on phytoncides, which are associated with forest healing, and to activate recreational forests. Methods: The target sites were natural recreation forests, a forest park and an arboretum, and the control sites were three urban parks. The samples were collected at a volume of 6.0 L and a flow rate of 0.1 L/min for one hour using a low volume pump and the solid adsorbent sampling method. The phytoncide compounds adsorbed in the Tenax TA tube were analyzed by a automatic heat desorption unit and GC-MS. Results: By type of recreational forest, the annual concentrations of phytoncide (monoterpene) for the forest park showed the highest concentration with $1.450{\mu}g/m^3$, while those for the arboretum showed the lowest concentration at $0.892{\mu}g/m^3$, and thus the concentration of the forest park was approximately 1.6 times higher than the arboretum. The season showing the highest concentration of phytoncides was summer (June) and the forest park was the highest among the recreational forests. The concentrations of major components for phytoncide showed in descending order: ${\alpha}-pinene$, ${\beta}-pinene$, camphene, 3-carene and limonene. The seasonal concentration of ${\alpha}-pinene$, camphene and ${\beta}-pinene$ by type of recreational forest increased in April, which is characterized by low temperature and humidity, and the seasonal concentration of camphene decreased with higher humidity. The meteorological factors which had the high correlation with the concentration of total terpene were temperature and humidity. $CO_2$ and $O_2$ showed an inverse correlation. Conclusion: The major components of phytoncide were ${\alpha}-pinene$, ${\beta}-pinene$, camphene, 3-carene and limonene in descending order of concentration. Further and systematic study on the chemical nature of individual phytoncides, and on the effect of phytoncides on humans needs to be performed.