• Title/Summary/Keyword: Chemical energy

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Effect of post-treatment routes on the performance of PVDF-TEOS hollow fiber membranes

  • Shadia R. Tewfik;Mohamed H. Sorour;Hayam F. Shaalan;Heba A. Hani;Abdelghani G. Abulnour;Marwa M. El Sayed;Yomna O. Mostafa;Mahmoud A. Eltoukhy
    • Membrane and Water Treatment
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    • v.14 no.2
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    • pp.85-93
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    • 2023
  • Membrane separation is widely used for several applications such as water treatment, membrane reactors and climate change. Cross-linked organic-inorganic hybrid polyvinylidene fluoride (PVDF) / Tetraethyl orthosilicate (TEOS) was adopted for the preparation of optimized hollow membrane (HFM) for membrane distillation or other low pressure separators for mechanical properties and permeability under varying pretreatment schemes. HFMs were prepared on semi-pilot membrane fabrication system. Novel adopted post-treatment schemes involved soaking in glycerol, magnesium sulphate (MgSO4), sodium hypochlorite (NaOCl), and isopropanol for different durations. All fibers were characterized for morphology using a scanning electron microscope (SEM), surface roughness using atomic force microscope (AFM), elemental composition by examining Energy Dispersive Spectroscopy (EDS), water contact angle (CA°) and porosity. The performance of the fibers was evaluated for pure water permeation flux (PWF). Post-treatment with MgSO4 gave the highest both tensile modulus and flux. Assessment of properties and performance revealed comparable results with other organic-inorganic separators, HF or flat. In spite of few reported data on post treatment using MgSO4 in presence of TEOS, this proves the potential of low cost treatment without negative impact on other membrane properties. The flux is also comparable with hypochlorite which manifests substantial precaution requirements in actual industrial use.The relatively high values of flux/bar for sample treated with TEOS, post treated with MgSO4 and hypochlorite are 88 and 82 LMH/bar respectively.

Using Chemical and Biological Approaches to Predict Energy Values of Selected Forages Affected by Variety and Maturity Stage: Comparison of Three Approaches

  • Yu, P.;Christensen, D.A.;McKinnon, J.J.;Soita, H.W.
    • Asian-Australasian Journal of Animal Sciences
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    • v.17 no.2
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    • pp.228-236
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    • 2004
  • Two varieties of alfalfa (Medicago sativa L cv. Pioneer and Beaver) and timothy (Phleum pratense L cv. Climax and Joliette), grown at different locations in Saskatchewan (Canada), were cut at three stages [1=one week before commercial cut (early bud for alfalfa; joint for timothy); 2=at commercial cut (late bud for alfalfa; pre-bloom head for timothy); 3=one week after commercial cut (early bloom for alfalfa; full head for timothy)]. The energy values of forages were determined using three approaches, including chemical (NRC 2001 formula) and biological approaches (standard in vitro and in situ assay). The objectives of this study were to determine the effects of forage variety and stage of maturity on energy values under the climate conditions of western Canada, and to investigate relationship between chemical (NRC 2001 formula) approach and biological approaches (in vitro and in situ assay) on prediction of energy values. The results showed that, in general, forage species (alfalfa vs. timothy) and cutting stage had profound impacts, but the varieties within each species (Pioneer vs. Beaver in alfalfa; Climax vs. Joliette in timothy) had minimal effects on energy values. As forage maturity increased, the energy contents behaved in a quadratic fashion, increasing at stage 2 and then significantly decreasing at stage 3. However, the prediction methods-chemical approach (NRC 2001 formula) and biological approaches (in vitro and in situ assay) had great influences on energy values. The highest predicted energy values were found by using the in situ approach, the lowest prediction value by using the NRC 2001 formula, and the intermediate values by the in vitro approach. The in situ results may be most accurate because it is closest to simulate animal condition. The energy values measured by biological approaches are not predictable by the chemical approach in this study, indicating that a refinement is needed in accurately predicting energy values.

A Study on Performance and Reactor Behavior of Chemical Refrigerator (화학식 냉동기의 성능 및 반응기 거동에 관한 연구)

  • Park, Seung-Hoon;Lee, Jong-Ho
    • Journal of Energy Engineering
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    • v.6 no.1
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    • pp.87-95
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    • 1997
  • A chemical heat pump based on the reversible reactions between metal chlorides and ammonia gas is attractive alternative to compression system and liquid absorption systems in cooling and refrigerating fields. The advantages of chemical heat pump are no regulatory constants due to CFC refrigerants, utilization of gas, industrial waste heat, electricity, fuel oil etc. as heat sources and wide applications to energy storage system, large-scale energy managements for industrial process. The scale-up of chemical heat pump from laboratory prototype to pilot plants necessitates the interpretation of system performance and evaluation of dynamic behavior in the chemical reactor. This study contains the prediction of performance of chemical refrigerator according to operating condition, the dynamic simulations through reactor modelling, which is used for the calculation of reactive medium temperature and the conversion variation with reactor cooling temperature, and the effect survey of block parameters on the power of refrigerator.

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Continuous Cell-Free Protein Synthesis Using Glycolytic Intermediates as Energy Sources

  • Kim, Ho-Cheol;Kim, Tae-Wan;Park, Chang-Gil;Oh, In-Seok;Park, Kyung-Moon;Kim, Dong-Myung
    • Journal of Microbiology and Biotechnology
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    • v.18 no.5
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    • pp.885-888
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    • 2008
  • In this work, we demonstrate that glycolytic intermediates can serve as efficient energy sources to regenerate ATP during continuous-exchange cell-free (CECF) protein synthesis reactions. Through the use of an optimal energy source, approximately 10 mg/ml of protein was generated from a CECF protein synthesis reaction at greatly reduced reagent costs. Compared with the conventional reactions utilizing phosphoenol pyruvate as an energy source, the described method yields 10-fold higher productivity per unit reagent cost, making the techniques of CECF protein synthesis a more realistic alternative for rapid protein production.

Lower Hole-injection barrier between pentacene and HDT-modified Gold with lowered workfunction

  • Hong, Ki-Pyo;Lee, Jong-Won;Yang, Sang-Yoon;Shin, Kwon-Woo;Jeon, Ha-Young;Kim, Se-Hyun;Park, Chan-Eon
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.238-238
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    • 2006
  • Through ultra-violet photoemission spectroscopy in-situ experiment, 0.67 eV energy barrier between 1-hexadecanethiol (HDT)-modified gold and pentacene was observed, which was 0.03 eV smaller than the energy barrier between bare gold and pentacene despite HDT modified gold had 0.8 eV lower work function than that of bare gold. This result is opposed to the idea that increasing the work function a metal decreases the energy barrier. This can be explained by two factors. One is the absence of interface dipole, which is observed in pentacene deposited on gold. The other is reduced ionization energy which can be explained through polarization energy or electronic splitting of molecular orbital with more crystalline structure observed through X-ray diffraction patterns.

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High-Performance and Fabrication of Graphene-based Flexible Supercapacitor

  • Ra, Eun Ju;Han, Jae Hee;Kim, Kiwoong;Lee, Sun Suk;Kim, Tae-Ho;An, Ki-Seok;Lim, Jongsun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.442-442
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    • 2014
  • Although electrochemical capacitors (ECs), also known as supercapacitors or ultracapacitors, is one of the most promising energy-storage devices because of its high power density, super-high cycle life, and safe operation. We herein report a synthesis of graphene-based flexible films by kneading method. Thus, a device can be readily made by sandwiching a polymer membrane included ionic liquid electrolytes between two identical graphene-based flexible films. Devices made with these electrodes exhibit ultrahigh energy density values while maintaining the high power density and excellent cycle stability of ECs. Moreover, these ECs maintain excellent electrochemical attributes under high mechanical stress and thus hold promise for high-energy, flexible electronics.

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Modularization and Application of Hybrid Renewable Energy Process in Seosan Area (서산 지역에서의 혼합 신재생에너지 공정의 모듈화 및 적용 연구)

  • JEONG SOO AHN;MIN HYEONG KANG;CHEON KIM;KYEONG SIK SEO;SEUNG HYEON KWAK;YU JIN CHOI;TAE JIN PARK;JAE CHEOL LEE
    • Transactions of the Korean hydrogen and new energy society
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    • v.34 no.2
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    • pp.212-225
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    • 2023
  • This study presents a modularized process of a hybrid renewable energy system that combines photovoltaic power and wind power to supply stable power in a unit area (1 km2). The water electrolysis process and fuel cells process also contributes to the supply of the stable power. The entire system can constantly supply power of 4.39 MW/km2. Actual meteorological data is used for simulation.

Energy Balance in Various Management of Paddy Ecosystem (논 생태계 관리방법에 따른 에너지 수지)

  • Lim, Kyoung-Soo;An, Sun-Hee;Kim, Jung-Wk
    • Korean Journal of Environmental Agriculture
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    • v.18 no.4
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    • pp.299-303
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    • 1999
  • A set of surveys was performed at Chungchongbuk-Do in 1997 in order to analyze energy related in rice production. Four cases in rice farming were surveyed : traditional farming, no chemical farming, duck farming, mud snail farming. The farmer in traditional fanning has used chemical fertilizers and chemicals such as general farmers. The farmer in no chemical farming has used chemical fertilizers and manure but has not use chemicals. The farmer in duck farming has not used chemical fertilizers and chemicals but brought up duck in paddy. The farmer in mud snail has not used chemical fertilizers and chemicals but brought up mud snail in paddy. The animals n paddy as like duck and mud snail not only eat weeds and insect but also input fertile material by excretion. The results of energy analysis are as follows 1. In view of energy, the duck farming was the most efficient of four cases. The mud snail farming was less efficient than the duck farming, the traditional farming was less efficient than the mud snail farming, the na chemical farming was less efiicierrt than the traditional farming. 2. Relatively to amount of product, non renewable energy was used more in traditional farming than other cases and renewable energy was used more in no chemical farming than other cases. 3. The reason of low energy efficiency in the no chemical farming was to input fertilizers and manure so much. So to input nutrients excessively in order not to use chemicals can make rice farming to be inefficient in a view of energy. 4. The farming to bring up animals in paddy was more sustainable than other cases because input of non renewable energy could be decreased. But in order to make it to be more sustainable, should be developed cultivation method to decrease input of non renewable direct energy such as fossil fuel and electricity .

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Heat Transfer Model and Energy Dissipation Rate in Bubble Columns with Continuous Operation (연속조작 기포탑에서 열전달 모델 및 에너지 소멸 속도)

  • Jang, Ji Hwa;Seo, Myung Jae;Lim, Dae Ho;Kang, Yong;Jung, Heon;Lee, Ho Tae
    • Korean Chemical Engineering Research
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    • v.47 no.5
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    • pp.587-592
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    • 2009
  • Heat transfer model and energy dissipation rate were investigated to examine the heat transfer mechanism in bubble columns with continuous operation. The energy dissipation rate($E_D$) obtained from the unsteady state heat transfer model based on the surface renewal theory was significantly small, comparing with the hydrodynamic energy dissipation rate($P_v$) calculated from the overall hydrodynamic energy balance based on the behaviors and holdups of gas and liquid phases in the column. It was found from these results that the energy dissipation rate based on the surface renewal theory is independent of the hydrodynamic energy dissipation rate obtained from the overall hydrodynamic energy balance in the bubble column, in considering their mechanism. The different two energy dissipation rates were correlated in terms of operating variables within this experimental conditions, respectively.