• Title/Summary/Keyword: Chemical compositions

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Chemical Composition and Biological Activities of Essential Oil from 'Setoka' Branches (세토카 가지 정유의 성분 분석 및 생리 활성)

  • Hyun, Ju Mi;Kim, Jung Eun;Yeum, Hyun Sook;Song, Jung-Min;Kim, Mi Ryang;Lee, Nam Ho
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.42 no.3
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    • pp.227-233
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    • 2016
  • This study was designed to analyze the chemical compositions of 'Setoka' branch essential oils (SEBO) and to test their biological activities. 'Setoka' is a Citrus species widely cultivated in Jeju Island. At the present, 'Setoka' branches produced by thinning process were mostly discarded as a waste. Therefore, utilization of this branch waste has received much attention. 'Setoka' branch essential oils (SBEO) were prepared by treatment of its ethanol extracts with jojoba oil. SBEO were chemically analyzed using gas chromatograph-mass spectrometry (GC-MS), and following components were identified; ethyl linoleate (64.14%), ethyl palmitate (16.50%), neophytadiene (11.06%) and beta-citronellol (5.09%). The anti-inflammatory activity in the SBEO was examined using RAW 264.7 murine macrophage cells stimulated with LPS. As a result, the SBEO inhibited nitric oxide (NO) productions with a dose-dependent manner. In addition, SBEO showed good anti-microbial activities against drug-susceptible and -resistant skin pathogens such as Staphylococcus aureus and Propionibacterium acnes, which are acne-causing bacteria. Based on these results, we suggest that SBEO has the possibility for use as an anti-inflammatory and anti-microbial agent in cosmetic applications.

Comparison of Physicochemical Composition of Kohlrabi Flesh and Peel (콜라비 가식부와 껍질의 이화학적 성분 비교)

  • Cha, Seon-Suk;Lee, Myung-Yul;Lee, Jae-Joon
    • Food Science and Preservation
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    • v.20 no.1
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    • pp.88-96
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    • 2013
  • This study was investigated to compare the major chemical components of kohlrabi (Brassica oleracea var. gongylodes) flesh and kohlrabi peel. Among the proximate compositions, the crude fat of kohlrabi peel contained lower than that of kohlrabi flesh, while the contents of carbohydrate and the crude protein were higher in the kohlrabi peel. Total free sugar content of the flesh kohlrabi was higher than that of the peeled kohlrabi, and the major free sugars of the flesh kohlrabi and peeled kohlrabi were identified as fructose and glucose. The value of glutamic acid was greater in amino acids of kohlrabi flesh and kohlrabi peel, and the contents of total amino acids and essential amino acids were higher in kohlrabi peel compared with kohlrabi flesh. Kohlrabi flesh also contained a higher level of unsaturated fatty acids than kohlrabi peel. The contents of organic acid were higher in kohlrabi peel, and the level of oxalic acid was the highest in both kohlrabi. The vitamin C contents of flesh kohlrabi and peeled kohlrabi were 231.36 mg/100 g and 402.75 mg/100 g, respectively. The mineral content of the peeled kohlrabi was higher than that of the flesh kohlrabi, and the mineral contents of the flesh and peeled kohlrabi were greater in the order of K>Ca>Mg>Na. As a result, the contents of total amino acid, essential amino acid, organic acid, vitamin C and mineral were higher in the peeled kohlrabi, and the free sugar and unsaturated fatty acid contents of the flesh kohlrabiwere higher.

Fabrication of Silane-crosslinked Proton Exchange Membranes by Radiation and Evaluation of Fuel Cell Performance (방사선을 이용한 실란 가교구조의 유/무기 복합 수소이온 교환막 제조 및 연료전지 성능 평가)

  • Lee, Ji-Hong;Sohn, Joon-Yong;Shin, Dong-Won;Song, Ju-Myung;Lee, Young-Moo;Nho, Young-Chang;Shin, Jun-Hwa
    • Polymer(Korea)
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    • v.36 no.4
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    • pp.525-530
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    • 2012
  • In this study, silane-crosslinked organic/inorganic composite membranes were prepared by simultaneous irradiation grafting of binary monomer mixtures (styrene and 3-(trimethoxysilyl)propyl methacrylate (TMSPM)) with various compositions onto a poly(ethylene-alt-tetraethylene) (ETFE) film and followed by sol-gel processing and sulfonation to provide a silane-crosslinked structure and a proton conducting ability, respectively. The Fourier transform infrared spectroscopy (FTIR) and thermo gravimetric analysis (TGA) were utilized to confirm the crosslinking of ETFE-g-PS/PTMSPM films. The prepared membranes with similar ion exchange capacity but a different TMSPM content were selected and their membrane properties were compared. The ETFE-g-PSSA/PTMSPM membranes were characterized by water uptake, dimensional stability, and proton conductivity after sulfonation. The membrane electrode assemblies (MEA) of the prepared membranes were fabricated and their single cell performances were measured.

Preparation and Adhesion of One Part Room Temperature Curable Alkoxy Type Silicone Sealant (일액형 알코올형 실리콘 실란트의 제조 및 접착 물성)

  • Kim, Dae-Jun;Park, Young-Jun;Kim, Hyun-Joong;Lee, Bong Woo;Han, Jae Chul
    • Journal of Adhesion and Interface
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    • v.2 no.4
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    • pp.1-9
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    • 2001
  • Silicone sealants are composed of polymer, plasticizer, crosslinker, catalyst and filler. Types and compositions of components are effected on sealant performances. In recent, use of alkoxy type silicone sealant increased due to environmental advantage. In this study, we investigated effects of component types and ratios on one-part room temperature curable alkoxy type silicone sealant preparation and adhesion properties. Alkoxy type silicone sealants were prepared with various PDMS (polydimethylsiloxane) viscosities. In addition, the effect of plasticizer, crosslinkers, and catalyst on sealant obtained from by mixture of PDMS viscosities of 20000 and 80000 was investigated. Reaction temperature on change of mixing time was observed, and then proper crosslinking systems were found. Adhesion (properties) of silicone sealants were measured. In the sealants preparation, stable reaction was achieved by adjusting composition variance ratio in the sealant mixture temperature below $40^{\circ}C$. The adhesion properties of sealant differ from substrate composition. The order of adhesion strength was glass/glass > glass/aluminum > aluminum/aluminum system. The elongation of sealant was increased as polymer viscosity and plasticizer content increased. The strength was increased as crosslinker and plasticizer decreased, while catalyst increased.

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Decontamination of Poultry Feeds by Gamma Irradiation (감마선 조사에 의한 가금용 사료의 살균)

  • Byun, Myung-Woo;Cho, Han-Ok;Lee, Jae-Won;Kwon, Joong-Ho;Kim, Young-Bae
    • Korean Journal of Food Science and Technology
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    • v.19 no.5
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    • pp.403-408
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    • 1987
  • The effects of gamma irradiation on microbiological and chemical qualities of four kinds of poultry feeds were investigated. The viable counts of total bacteria in the samples were $10^5\;to\;10^6/g$. They were reduced by 2 to 3 log cycles after 3 to 5 kGy irradiation, and were completely eliminated with irradiation of 7 kGy. Coliforms and enteric pathogens were contaminated in high levels in all samples, ranging from $1.2{\times}10^4\;to\;1.7{\times}10^5/g\;and\;4.0{\times}10\;to\;2.6{\times}10^3/g$, respectively, They were sterilized by 3 to 5 kGy irradiation. Fungi, ranging from $10^{2}\;to\;10^4/g$, mainly osmophiles were identified as Aspergillus and Penicillium. They were eliminated to a undetectable level by 5 to 10 kGy irradiation. Six kinds of species, including Aspergillus flavus, were potential mycotoxin producers. Chemical components, such as proximate compositions, and mineral contents were not affected by the gamma irradiation. However, TBA values and amino acid content seemed to be affected by gamma irradiation.

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Effect of Fermentation Time on the Chemical Composition of Mulberry (Morus alba L.) Leaf Teas (발효시간이 뽕잎차 구성성분에 미치는 효과)

  • Bae, Hui-Ae;Baek, Hyeon;Park, Hae-Il;Choung, Myoung-Gun;Sohn, Eun-Hwa;Kim, Sam-Hyun;Kim, Dae-Su;Chung, Ill-Min;Seong, Eun-Soo;Yu, Chang-Yeon;Lim, Jung-Dae
    • Korean Journal of Medicinal Crop Science
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    • v.19 no.4
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    • pp.276-286
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    • 2011
  • Morus alba (Mulberry) leaves were exposed to fermentation for varying amounts of time: no fermentation (0 min, MANF), medial fermentation (10 h, MAMF), and full fermentation (24 h, MAFF). The chemical compositions of the teas were determined and compared with those of commercial Camellia sinensis teas. The results showed that mulberry leaf teas contained significantly higher amounts of ash and fat than Camellia sinensis tea. Compared with Camellia sinensis teas, all mulberry leaf teas contained significantly more total free amino acids (24.26~54.25mg L-glutamic acid equivalent $g^{-1}$), but the concentration of caffeine was relatively low for mulberry leaf teas. High thiamine, riboflavin, and niacin contents were found in all mulberry leaf teas, but ascorbic acid and pyridoxine were found at higher levels in Camellia sinensis teas than in mulberry leaf teas. Color measurements demonstrated that mulberry leaf tea infusions generally had lower $a^*$ (greenness) and $b^*$ (yellowness) values than Camellia sinensis tea infusions. All infusions exhibited low turbidity levels (less than 10%). The contents of total phenols were measured as 71.8 and 74.9mg 100 $ml^{-1}$ infusion in MANF and MAFF, respectively, but the MAMF tea infusion showed significantly lower total phenols (64.6mg 100$ml^{-1}$ infusion). The total flavonoid contents of mulberry leaf tea infusions were lower (8.9~20.6mg 100 $ml^{-1}$ infusion) than those of Camellia sinensis teas and thus had lower antioxidant capacities (DPPH: 326.8~526.9 ${\mu}M$ trolox equivalent $g^{-1}$ and FRAP: 364.6~387.6 ${\mu}M$ trolox equivalent $g^{-1}$) than Camellia sinensis teas. The amounts of ${\gamma}$-aminobutyric acid (GABA) and rutin were higher in fermented mulberry leaf teas; the level of GABA increased with increasing fermentation time and the content was highest in MAFF, but rutin content was highest in MAMF.

Optimization of Post-Activation Systems to Improve the Embryonic Development in Porcine Parthenogenesis and Somatic Cell Nuclear Transfer

  • Roy, Pantu Kumar;Kim, Ghangyong;Fang, Xun;Hassan, Bahia MS;Soysa, Mahanama De;Shin, Sang Tae;Cho, Jong Ki
    • Journal of Embryo Transfer
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    • v.32 no.3
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    • pp.95-104
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    • 2017
  • This study was conducted to establish the optimal chemical post-activation conditions in porcine embryonic development after parthenogenesis (PA) and somatic cell nuclear transfer (SCNT) using 4 different chemical compositions (cytochalasin B (CB), cyclohexamide (CHX), demecolcine (DC), 6-dimethylaminopurine (DMAP). Porcine embryos were produced by PA and SCNT and then, cultured for post-activation with CB ($7.5{\mu}g/mL$), CB ($7.5{\mu}g/mL$) + CHX ($10{\mu}g/mL$), CB ($7.5{\mu}g/mL$) +DC ($0.4{\mu}g/mL$), and CB ($7.5{\mu}g/mL$) + DMAP (2 mM). In PA embryonic development, cleavage rates have been significantly higher in CB group (94.7%) and CB+DMAP group (94.1%) than that of CB+CHX and CB+DC group (88.1 and 84.3%, respectively). There have been no significant differences in blastocyst formation rates among the four groups. In cell number of blastocyst was shown in CB group (42.3%) significantly higher than CB+CHX and CB+DC group (40.6 and 40.6%, respectively). In SCNT embryonic development, CB+DMAP group (89.7%) significant differences were found on embryo cleavage rates when compared with other three groups. Blastocyst formation rates in CB+DMAP group (26.9%) were significantly higher when compared with CB, CB+CHX, and CB+DC groups (25.5, 20.2, and 22.1%, respectively). In blastocyst cell number, CB+DMAP group (41.4%) was found higher significant difference compared with other three groups. Additionally, we have investigated survivin expression in early development stages of porcine SCNT embryos for more confirmation. Our results establish that CB group and CB+DMAP group for 4 h during post-activation improves pre-implantation improvement of PA and SCNT embryos.

A Simulation Study on the Cascade Refrigeration Cycle for the Liquefaction of the Natural Gas [2]: An Application to the Multistage Cascade Refrigeration Cycle (천연가스 액화를 위한 캐스케이드 냉동사이클의 전산모사에 대한 연구 [2]: 다단 캐스케이드 냉동 사이클에 적용)

  • Cho, Jung-Ho;Kim, Yu-Mi
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.12 no.2
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    • pp.1013-1019
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    • 2011
  • In this paper, simulation works for a multi-stage cascade refrigeration cycle using propane, ethylene and methane as refrigerants have been performed for the liquefaction of natural gas using Peng-Robinson equation of state built-in PRO/II with PROVISION release 8.3. The natural gas feed compositions were supplied from Korea Gas Corporation and the flow rate was assumed to be 5.0 million tons per annual. Supply temperature for propane refrigerant was fixed as $-40^{\circ}C$, that for ethylene refrigerant as $-95^{\circ}C$, and that for methane refrigerant as $-155^{\circ}C$. For the multi-stage refrigeration cycle, three-stage refrigeration was assumed for propane refrigeration cycle, two-stage refrigeration for ethylene refrigeration cycle and three-stage refrigeration for methane refrigeration cycle. Natural gas was finally cooled and liquefied to $-162^{\circ}C$ by Joule-Thomson expansion. Conclusively, 91.71% by mole of the natural gas liquefaction ratio was obtained through a cascade refrigeration cycle and Joule-Thomson expansion and 0.433 kW of compression power was consumed for the liquefaction of 1.0 kg/hr of natural gas.

Characteristics of Manganese Nodule from the East Siberian Sea (동시베리아해 망간단괴의 특성)

  • Koo, Hyo Jin;Cho, Hyen Goo;Yoo, Chan Min;Jin, Young Keun
    • Journal of the Mineralogical Society of Korea
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    • v.30 no.4
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    • pp.219-227
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    • 2017
  • Manganese (Mn) nodules in the Arctic Sea have been founded in the Kara Sea and Barents Sea, but mineral and chemical compositions have been rarely investigated. In this study, mineralogical and geochemical characteristics of Mn nodules obtained during the Arctic Expedition ARA07C in northern East Siberian Sea were identified, and then genesis of Mn nodules were estimated by using these characteristics. Main manganese oxide minerals constituting the manganese nodule were buserite, birnessite, and vernadite. The Mn nodules generally represent radiated and massive texture, and the layered texture was developed restrictively. The radiated texture, main feature of the manganese nodule in the East Siberian Sea, is mainly composed of cuspate-globular microstructure. Compared with the Mn nodules in Pacific and Indian Oceans, Mn nodules of the East Siberian Sea are abundant in Mn, but Fe is too scarce. There was no difference in the chemical composition and microstructures between outer and inner part of nodule. Therefore, nodules are most likely to have only one genesis during their growth, and all of nodules indicate the diagenetic in $Mn-Fe-(Cu+Ni+Co){\times}10$ ternary diagram. It is considered that the manganese nodules in the East Siberian Sea are characterized by high Mn contents because manganese contents in the Arctic Ocean were mainly resulted from river or coastal erosion and most of them are trapped in the Arctic Ocean.

Chemical Components of White and Red Lotus (목련과 홍련의 화학성분)

  • Jeong, Chang-Ho;Son, Ki-Bong;Kang, Seon-Gyeong;Shim, Ki-Hwan
    • Journal of agriculture & life science
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    • v.43 no.1
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    • pp.43-50
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    • 2009
  • To get basic data for the utilization of white and red lotus as a raw material in functional food, chemical components of its leaf and root were investigated. Leaf had the highest level of nitrogen free extract and root had the highest level of moisture. The mineral analysis showed K(380.44~1,516.34 mg/100g), Ca(36.67~1,323.92 mg/100g), P(84.02~473.13 mg/100g) and Na(57.73~304.07 mg/100g). The rich free sugars in white and red lotus were glucose(161.12~765.15 mg/100g) and frutose (100.57~901.12 mg/100g). Total amino acid contents in leaf and root of white lotus and leaf and root of red lotus were 6,385.57, 1,162.93, 6,003.01 and 1,242.20 mg/100g, respectively. Although the free amino acid compositions of white and red lotus were different, their major free amino acids were glutamic acid, phenylalanine arginine and tyrosine. The ascorbic acid were 248.65 and 20.99 mg/100g in leaf and root of white lotus, 156.92 and 9.32 mg/100g in leaf and root of red lotus. The leaf of white lotus exhibited the highest total phenolic contents at 24.33 mg/g.