• Title/Summary/Keyword: Chemical compositions

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Physicochemical Properties of Organic Sludge Discharged from an Industrial Complex in Ulsan (울산지역 산업단지에서 배출되는 유기성슬러지의 물리.화학적 특성)

  • Lee, Gang-Woo;Kim, Min-Choul;Lee, Jae-Jeong;Lee, Man-Sig;Kim, Ji-Won;Park, Hung-Suck;Shon, Byung-Hyun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.9 no.6
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    • pp.1760-1767
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    • 2008
  • In this study, we analyzed the physical and chemical properties such as proximate analysis, ultimate analysis, heating values, and thermogravimetric analysis for the organic sludges discharged from an industrial complex in Ulsan. The average water, combustible, and ash content of organic sludges were 72.9, 18.5, and 8.6%, respectively. And according to the ultimate analysis of organic sludges, the C, O, H, N, and S compositions were 33.9, 26.4, 4.4, 4.4, and 0.6%, respectively. According to the results of investigating the lower heating values, 6 sludges were on the range of $1,500{\sim}2,000\;kcal/kg$ and 4 sludges were on the range of over 2,000 kcal/kg. Therefore, these 10 sludges could be directly applied to industries which try to use the energy by direct incineration.

A Study on the Laminar Burning Velocity and Flame Structure with H2 Content in a Wide Range of Equivalence Ratio of Syngas(H2/CO)/Air Premixed Flames (넓은 당량비 구간에서 수소함유량에 따른 합성가스(H2/CO)/공기 예혼합화염의 연소속도 및 화염구조에 관한 연구)

  • Jeong, Byeong-Gyu;Lee, Kee-Man
    • Journal of the Korean Society of Combustion
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    • v.19 no.1
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    • pp.17-28
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    • 2014
  • In this study, the laminar burning velocity of syngas fuel($H_2/CO$) and flame structure with various hydrogen contents were studied using both experimental measurements and detailed kinetic analysis. The laminar burning velocities were measured by the angle method of Bunsen flame configuration and the numerical calculations including chemical kinetic analysis were made using CHEMKIN Package with USC-Mech II. A wide range of syngas mixture compositions such as $H_2$ : CO = 10 : 90, 25 : 75, 50 : 50, 75:25 and equivalence ratios from lean condition of 0.5 to rich condition of 5.0 have been considered. The experimental results of burning velocity were in good agreement with previous other research data and numerical simulation. Also, it was shown that the experimental measurements of laminar burning velocity linearly increased with the increment of $H_2$ content although the burning velocity of hydrogen is faster than the carbon monoxide above 10 times. This phenomenon is attributed to the rapid production of hydrogen related radicals such as H radical at the early stage of combustion, which is confirmed the linear increase of radical concentrations on kinetic analysis. Particular concerns in this study are the characteristics of burning velocity and flame structure different from lean condition for rich condition. The decrease of OH radicals and double peaks are observed with $H_2$ content in rich condition once $H_2$ fraction exceeds over threshold.

Effects of Alloying Elements and Heat Treatments on the Microstructures and Mechanical Properties of Ductile Cast Iron by Strip Casting (스트립캐스팅한 구상흑연주철박판의 합금원소 및 열처리에 따른 미세조직과 기계적 성질의 변화)

  • Lee, Gi-Rak;Ra, Hyung-Yong
    • Journal of Korea Foundry Society
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    • v.20 no.2
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    • pp.122-128
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    • 2000
  • Strip casting process is a new technology that makes a near net shape thin strip directly from molten metal. With this process, a large amount of energy and casting cost could be decreased from the abbreviation of reheating and/or hot rolling process. Ductile cast iron which has spheroidal graphite in the matrix is the most commercial and industrial material, because of its supreme strength, toughness, and wear resistance etc. But it cannot be produced to the thin strip owing to difficulty in rolling of ductile cast iron. In this study, ductile cast iron strips are produced by the twin roll strip caster, with different chemical compositions of C, Si, and Mn contents. And then heat-treated, microstructures and mechanical properties are examined. The microstructures of as-cast strip are that of white cast iron which consists of the mixture of cementite and pearlite, but the equiaxed crystal zone of the pearlite or segregation zone of cementite exists in the center region of the strip thickness, which cannot be observed in the rapidly solidified metallic mold cast specimens. This structure is supposed to be formed from the thermal distribution of strip and the rolling force. Comparing with the structures of each strips after heat treatment, increasing Si content makes smaller spheroidal graphite and more compact in the matrix, furthermore the less of Mn content makes the ferrite matrix be obtained clearer and easier. As a result of the tensile test of graphitization heat-treated strips, the yield strengths are about 250 MPa, the tensile strengths are about $430{\sim}500$ MPa, and the elongations are about $10{\sim}13%$. In the case of the strip which has the smaller and more compact spheroidal graphite in the ferrite matrix, the higher tensile strength and better drawability could be obtained.

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Survey on the Recycling of Waste Slag Generated by Smelting Reduction of Deep-Sea Manganese Nodules (망간단괴 용융환원 폐슬래그의 재활용 방안)

  • Park, Hyungkyu;Nam, Chulwoo;Kim, Sungdon
    • Resources Recycling
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    • v.23 no.4
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    • pp.69-74
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    • 2014
  • Slags generated in the smelting reduction of deep sea manganese nodule could be utilized as an additional materials for making Fe-Si-Mn alloys by mixing with cokes and re-smelting at an arc furnace. In this re-melting process slag is also generated, and the secondary slag is treated as waste. In this survey, recycling of the waste slag of Mn nodule was studied. It is tried to utilize the waste slag as ceramic materials or construction materials. However, it is difficult to use the waste slag directly as an additional material to ceramics such as portland cement or castable refractory material due to the much difference of chemical compositions. As an altercation road constructing material is considered, and toxicity on the soil of the waste slag was tested according to Korean Standard for testing permissible amount of toxic substances. The test result was satisfied with the requirements on the standard. So, it should be suggested that the waste slag of the Mn nodule could be utilized as constructing materials such as road filler or base materials.

A Study on Hydrochemistry Characteristics of Groundwater and Surface water near a Petroleum Contaminated area (유류오염지 주변 지하수와 지표수의 수화학적인 특성 연구)

  • Lim, Hong-Gyun;Lee, Jin-Yong;Park, Youngyun;Park, Yu-Chul
    • Journal of Soil and Groundwater Environment
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    • v.17 no.5
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    • pp.10-19
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    • 2012
  • The aim of this study was to examine chemical and isotopic compositions of groundwater and lake water near an area contaminated by petroleum and to evaluate influence of petroleum on them during the period from March to August 2011. In dry season, $Ca^{2+}$ and $SO{_4}^{2-}$ were dominant in the groundwater and lake water and $Ca^{2+}$ and $HCO{_3}^-$ were significant in wet season. ${\delta}^{18}O$ and ${\delta}D$ of the groundwater and lake water were plotted near LMWL (${\delta}D=8.06{\delta}^{18}O+12.5$). ${\delta}^{18}O$ and ${\delta}D$ of the lake water did not show seasonal variation. However, ${\delta}^{18}O$ and ${\delta}D$ of the groundwater were enriched in wet season compared with those in dry season because of influence of small ponds around wells where evaporation losses were slightly experienced. Redox condition of most lake water was oxidation environment in contact with the atmosphere during the study period. However, redox condition of groundwater was transitional environment in dry season and oxidation environment in wet season because of influence of contaminant such as petroleum. In some groundwater, the concentrations of $NO{_3}^-$ in some groundwater were less than 1 mg/L because of denitrification. Also, $NO{_3}^-$ showed positive correlation with $SO{_4}^{2-}$ and weak negative correlation with $HCO{_3}^-$, because of influence of denitrification.

Investigation of gamma radiation shielding capability of two clay materials

  • Olukotun, S.F.;Gbenu, S.T.;Ibitoye, F.I.;Oladejo, O.F.;Shittu, H.O.;Fasasi, M.K.;Balogun, F.A.
    • Nuclear Engineering and Technology
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    • v.50 no.6
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    • pp.957-962
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    • 2018
  • The gamma radiation shielding capability (GRSC) of two clay-materials (Ball clay and Kaolin)of Southwestern Nigeria ($7.49^{\circ}N$, $4.55^{\circ}E$) have been investigated by determine theoretically and experimentally the mass attenuation coefficient, ${\mu}/{\rho}(cm^2g^{-1})$ of the clay materials at photon energies of 609.31, 1120.29, 1173.20, 1238.11, 1332.50 and 1764.49 keV emitted from $^{214}Bi$ ore and $^{60}Co$ point source. The mass attenuation coefficients were theoretically evaluated using the elemental compositions of the clay-materials obtained by Particle-Induced X-ray Emission (PIXE) elemental analysis technique as input data for WinXCom software. While gamma ray transmission experiment using Hyper Pure Germanium (HPGe) spectrometer detector to experimentally determine the mass attenuation coefficients, ${\mu}/{\rho}(cm^2g^{-1})$ of the samples. The experimental results are in good agreement with the theoretical calculations of WinXCom software. Linear attenuation coefficient (${\mu}$), half value layer (HVL) and mean free path (MFP) were also evaluated using the obtained ${\mu}/{\rho}$ values for the investigated samples. The GRSC of the selected clay-materials have been compared with other studied shielding materials. The cognizance of various factors such as availability, thermo-chemical stability and water retaining ability by the clay-samples can be analyzed for efficacy of the material for their GRSC.

Comparative Analysis between Healthy and Powdery Mildew-infected Plants of Strawberry Cultivar Seolhyang (딸기 설향품종의 흰가루병 건전 및 감염식물 비교 분석)

  • Nam, Myeong-Hyeon;Jeon, Yi-Nae;Lee, Hee-Chul;Lee, He-Duck;Kang, Hee-Kyoung
    • Research in Plant Disease
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    • v.18 no.2
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    • pp.80-85
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    • 2012
  • We examined the incidence of powdery mildew in strawberry cv. Seolhyang plants, and performed a comparative analysis on the temperature, photosynthesis rate, and nutrient content of healthy and powdery mildew-infected plants. Powdery mildew first infected the fruit of the strawberries in mid-January, and the disease severity increased in both fruits and leaves during the late harvest season. The rate of photosynthesis and leaf temperatures of healthy plants were higher than those of powdery mildew-infected leaves and significantly decreased with an increase in the disease severity. The healthy and powdery mildew-infected plants in the soil analysis were not significantly different in chemical compositions. The leaves of the healthy plants contained lower potassium and higher manganese and chlorophyll concentrations than the powdery mildew-infected plants. In particular, manganese was significantly higher in healthy leaves than in infected leaves. Therefore, the concentrations of potassium, manganese and chlorophyll in strawberry leaves may be an important factor for disease suppression.

Potential of Using Ginger Essential Oils-Based Nanotechnology to Control Tropical Plant Diseases

  • Abdullahi, Adamu;Ahmad, Khairulmazmi;Ismail, Intan Safinar;Asib, Norhayu;Haruna, Osumanu;Abubakar, Abubakar Ismaila;Siddiqui, Yasmeen;Ismail, Mohd Razi
    • The Plant Pathology Journal
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    • v.36 no.6
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    • pp.515-535
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    • 2020
  • Essential oils (EOs) have gained a renewed interest in many disciplines such as plant disease control and medicine. This review discusses the components of ginger EOs, their mode of action, and their potential nanotechnology applications in controlling tropical plant diseases. Gas chromatography-mass spectroscopy (GC-MS), high-performance liquid chromatography, and headspace procedures are commonly used to detect and profile their chemical compositions EOs in ginger. The ginger EOs are composed of monoterpenes (transcaryophyllene, camphene, geranial, eucalyptol, and neral) and sesquiterpene hydrocarbons (α-zingiberene, ar-curcumene, β-bisabolene, and β-sesquiphellandrene). GC-MS analysis of the EOs revealed many compounds but few compounds were revealed using the headspace approach. The EOs have a wide range of activities against many phytopathogens. EOs mode of action affects both the pathogen cell's external envelope and internal structures. The problems associated with solubility and stability of EOs had prompted the use nanotechnology such as nanoemulsions. The use of nanoemulsion to increase efficiency and supply of EOs to control plant diseases control was discussed in this present paper. The findings of this review paper may accelerate the effective use of ginger EOs in controlling tropical plant diseases.

The Study of Instrumental Analysis of Deposits on Paper Machine and Holes/spots in Paper (제지공정 침착이물질 및 종이내 불순물성분의 기기분석적 고찰)

  • 마금자;이복진
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.29 no.3
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    • pp.7-16
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    • 1997
  • The constituents of deposits on paper machine and holes/spots in paper have been studied by consequently a combination of analytical techniques, such as FTIR, Py-GC-MS, and. EDS. FTIR spectroscopy was used prior to Py-GC-MS and EDS analysis, as preliminary analysis technique. The analysis of organic components were carried out with the use of a pyrolysis unit connected to a GC-MS, and inorganic components in ash were analysed by SEM equipped with an EDS analyzer after pyrolysis at 59$0^{\circ}C$. The deposits on the dryer section were complex pitch, which was the mixture of the organic contents of fatty acid ester and starch, and the inorganic contents of talc, clay, and calcium carbonate. The complex pitch was estimated to come from the coated broke. We knew the deposits on the metering rod of sym-sizer were associated with the interaction of unstable AKD and CaCO$_3$. The compositions of holes or spots varied considerably and were associated with chemical interaction within the system. The holes, spots, and blotches in the finished paper were PE and PP that were streamed out from pulp sources, complex pitch that were caused by the interaction of the different additives in the system, polymer such as flexible PVC that used for the prop of palette, and hot melt as adhesives that came from the inadequate handling of broke. In addition, we identified that poly(caprolactam) which is used for forming fabrics or press felts, could be mixed with the raw materials by accident and results in streak on coating.

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Characterization of Water Hyacinth (Eichhornia crassipes) Biomass and Evaluation of Applicability as an Organic Filler to Papermaking (부레옥잠 바이오매스의 특성분석과 제지적용성 평가)

  • Kim, Dong Sung;Heo, Yoon Sung;Sung, Yong Joo;Han, Seung-Won;Seo, Cheol Mo
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.46 no.5
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    • pp.79-87
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    • 2014
  • The enrichment with nutrients in rivers and lakes becomes serious problems in Korea. As the environmental friendly solution, the phytoremediation are getting more attention and the water hyacinth could be a strong candidate plant for this. Water hyacinth is a free floating freshwater plant proven to be a effective plant used for a purification of a polluted lakes, sewage wastewater, and livestock wastewater. The biggest obstacles for application of water hyacinth in Korea could be the disposal of the water hyacinth before winter, because there is no feasible use for the water hyacinth until now. In this study, the characteristics of water hyacinth were deeply investigated for providing background data to develop appropriate application of the water hyacinth. The water hyacinth was fractioned three parts, leaf, air blader, root of which morphological properties were evaluated with microscope and field emission scanning electron microscope (FE-SEM). The water contents of each parts of the water hyacinth were 87% for leaf, 96.5% for air bladder, 94.6% for root. The chemical compositions of each parts were also measured and showed around 29% of hot water extract in leaf and air bladder, 42% holocellulose for leaf, 47% holocellulose for air bladder. The application of water hyacinth biomass without root parts to papermaking provided bulkier structure, but the tensile strength was decreased.