• Title/Summary/Keyword: Chemical compositions

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Burnup Measurement of Spent $U_3$Si/Al Fuel by Chemical Method Using Neodymium Isotope Monitors

  • Kim, Jung-Suk;Jeon, Young-Shin;Park, Kwang-Soon;Song, Byung-Chul;Han, Sun-Ho;Kim, Won-Ho
    • Nuclear Engineering and Technology
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    • v.33 no.4
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    • pp.375-385
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    • 2001
  • The total burnup in the spent U$_3$Si/Al fuel samples from Hanaro reactor was determined by destructive methods using $^{148}$ Nd, the sum of $^{143}$ Nd and $^{144}$ Nd, the sum of $^{145}$ Nd and $^{146}$ Nd, and the sum of total Nd isotopes($^{143}$ Nd, $^{144}$ Nd, $^{145}$ Nd, $^{146}$ Nd, $^{148}$ Nd and $^{150}$ Nd) monitors. The fractional($^{235}$ U) turnup in the spent fuel samples was also determined by U and Pu mass spectrometric method. The samples were dissolved in a mixture of 4 M HCI and 10 M HNO$_3$ without any catalyst. The separation of U, Pu and Nd from the spiked and unspiked sample solutions was achieved by two sequential anion exchange separation methods. The isotope compositions of these elements, after their separation from the fuel samples were measured by mass spectrometry. The contents of the elements in the spent fuel samples were determined by isotope dilution mass spectrometric method(IDMS) using $^{233}$ U, $^{242}$ Pu and $^{150}$ Nd as spikes. The effective fission yield was calculated from the weighted fission yields averaged over the irradiation period. The difference between total turnup values determined by various Nd monitors were in the range of 1.8%.

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The Influence of Chemical Compositions of Weld Metal and Welding Conditions on Hot Cracking by Hot Cracking Test (Inconel 690 오버레이용접부의 고온균열 발생에 미치는 용접금속의 화학조성 및 용접조건의 영향)

  • 양병일;지병하;김정태;박광식;최해수;박화순
    • Journal of Welding and Joining
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    • v.20 no.3
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    • pp.74-83
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    • 2002
  • In order to investigate the hot cracking phenomena of the Inconel 690 overlay welds, the hot cracking test(modified Varestraint test) was performed by varying augmented strain and welding speed in GTAW. A total of five kinds of specimens was used in the hot cracking test. The specimens used were two kinds of one layer specimens that were composed of just Inconel 690 deposited metal and three kinds of double layer specimens that were composed with as upper part of Inconel 690 weld metal and lower part of SA508 cl.3 or STS 309L. The main results are as fo11ows: In the welds composed of just Inconel 690, as the augmented strain was more increased and the welding speed was more decreased, the extent of cracking was more increased. And these cracks were mainly solidification cracks, and liquation cracks were also observed partially in HAZ. And hot cracking susceptibily of Inconel 690 welds by using filler metals containing Nb were higher than that of the welds with Nb free. The hot cracking susceptibility of Inconel 690 weld metal was increased with dilution of SA 508 cl.3 and STS 309L, and the influence of SA 508 cl.3 was higher than that of 575 309L. The results of calculation of $TSC\Delta$ and $TLC\Delta$ in Inconel 690 weld metal changed by dilution with base metal or neighboring welds were agreed well with the results of hot cracking test in this study. Therefore, it was expected that the hot cracking was considerably decreased or prevented by using proper welding conditions such as lower heat input, filler metals, base metal and neighboring welds.

The Effect of Heat-treatment on Brazing Characteristics of WC-9%Co/SUJ2 Steel (WC-9%Co와 SUJ2강의 접합특성에 미치는 열처리의 영향)

  • 정하윤;김종철;박경채
    • Journal of Welding and Joining
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    • v.15 no.5
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    • pp.56-63
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    • 1997
  • In The study, the bonding of WC-9%Co to SUJ2 steel using Ag-Cu-Zn-Cd insert metal has performed to investigate the bonding properties by heat-treatment. Bonding was brazed for 5-30min at 95$0^{\circ}C$, performed solution treatment for 5 min at 85$0^{\circ}C$ and sustained subsequently oil quenching. To investigate the effect of heat-treatment, tempering was executed at $600^{\circ}C$ for 30 min after oil quenching. Mechnical properties and chemical compositions on the brazed bonding interface were investigated by means of microstructural observation, 4-point bending test and EDS and XRD measurements. The results obtained were as follows. 1) The bonding strength of WC-9%Co/SUJ2 joints by Ag-Cu-Zn-Cd insert metal obtained about 78, 117 and 72MPa after brazing for 5, 20 and 30 min at 95$0^{\circ}C$. And the highest bonding strength obtained about 131MPa after brazing for10 min at 95$0^{\circ}C$ 2) Higher bonding strength of 288MPa was obtained in the joint that brazed for 10 min at 95$0^{\circ}C$, and carried out tempering for 30 min at $600^{\circ}C$ subsequently. 3) Fracture of joint brazed by Ag-Cu-Zn-Cd insert metal for 5, 10, 20 and 30 min created WC-9%Co/SUJ2 interface. The joint that brazed for 10 min at 95$0^{\circ}C$ and then tempered for 30 min at $600^{\circ}C$ was fractured at the site of WC-9%Co.

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A study on performance evaluation of rod rubber bushing under static and fatigue loadings (토크 로드 부품의 정하중 및 피로하중하에서의 성능평가 연구)

  • 이순복;김완두
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.14 no.5
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    • pp.1320-1329
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    • 1990
  • A static performance tester for a torque rod assembly was developed to evaluate the three characteristics of the rod rubber bushing : radial spring characteristic, thrust spring characteristic, and rotational torque characteristic. Among the various schemes considered in the conceptual design stage, the final versatile type was determined to perform three different tests in one machine. The performance testing machine carried out radial spring test, thrust spring test, and torque test of the torque rod assembly. Static performance of the torque rod assembly was evaluated with the tester developed and fatigue strength of the assembly was also tested with the servo-hydraulic structural fatigue testing machine. The life of the component was found to be related with the rubber quality and adhesionability between the rubber and the steel rod. The optimum rubber hardness was experimentally found by changing the chemical compositions of rubber, and the adhesion was improved by optimizing the shape of the outer section of a the rubber, this study ensured the development of a reliable torque rod assembly.

Effects of Mungbean Flour Level in Combination with Microbial Transglutaminase on Physicochemical and Textural Properties of Low-salt Pork Model Sausages

  • Lee, Hong Chul;Chin, Koo Bok
    • Food Science of Animal Resources
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    • v.33 no.2
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    • pp.221-228
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    • 2013
  • This study was performed to evaluate the effects of various levels of mungbean flour (MF) (0-2.4%) on the quality characteristics of pork model sausages (PMS) in experiment 1 and also select the optimum level of MF to enhance the water retention and gelling properties of low-salt PMS (LSPMS) with or without microbial transglutaminase (MTGase) in experiment 2. In experiment 1, the addition of MF did not affect pH, chemical compositions (fat and moisture contents), color values, and functional properties (expressible moisture, EM (%) and cooking yield, CY (%)) of PMS. However, the addition of MF increased the chewiness of PMS and hardness if the mungbean flour at the level of more than 1.2% was incorporated. Since the interaction between the microbial transglutaminase (MTGase) treatment and MF level was not significant (p>0.05), data were pooled by different factors (MTGase treatment and MF level) in experiment 2. MF improved the water binding ability and textural springiness of LSPMS. On the other hand, MTGase treatment decreased the pH and cooking yield (%) of LSPMS, but increased most textural properties. In conclusion, the addition of MF could enhance the water retention and textural properties of PMS and LSPMS, regardless of MTGase, when it was added to over 1.2%. Based on these results, mungbean protein may interact with MTGase on the low-salt comminuted meat systems. Therefore, further study might be needed to understand the mechanisms of interaction between MTGase and functional components induced from MF.

Distribution of Clay Minerals in Soils on the Northern Drainage Basin of the Nakdong River (낙동강 북부 배수유역의 토양 점토광물 분포)

  • Lee, Bong-Ho;Jeong, Gi-Young
    • Journal of the Mineralogical Society of Korea
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    • v.21 no.4
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    • pp.349-354
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    • 2008
  • Semiquantitative mineralogical analysis of clays in soils was performed to understand the distribution of clay minerals in relation to bedrock lithology on the northern basin of the Nakdong River. The soils developed on the granitic bedrocks have high contents of kaolinite and smectite. mite was the major clay mineral in the soils from sedimentary bedrocks, with minor kaolinite, smectite, and intergrade (interstratified chlorite-smectite or hydroxy-interlayed vermiculite) clay minerals. Illite and kaolinite contents of the soils from metamorphic and volcanic bedrocks fall between those of the soils from the granitic bedrocks and those of the soils from the sedimentary bedrocks. The clay mineralogy of the soils depends on the compositions of bedrock minerals and their susceptibility to chemical weathering. The weathering of plagioclase resulted in the high kaolinite content of the soils derived from granitic bedrocks, while the soils derived from sedimentary bedrocks are abundant in residual illite.

Geochemical Characteristics of Mineral Phases in the Mantle Xenoliths from Sunheul-ri, Jeju Island (제주도 선흘리 일대에 분포하는 맨틀포획암 내의 광물의 지화학적 특성 연구)

  • Kil, Young-Woo;Shin, Hong-Ja;Yun, Sung-Hyo;Koh, Jeong-Seon;Ahn, Ung-San
    • Journal of the Mineralogical Society of Korea
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    • v.21 no.4
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    • pp.373-382
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    • 2008
  • First reported geochemical characteristics of mantle xneoliths (spinel peridotites) from Sunheul-ri, Jeju Island, provide important clues for understanding the lithosphere composition, equilibrium temperature, and the period of entrainment and transport of the xenoliths in the host magma. Core and rim of mineral phases in the xenoliths are constant chemical compositions as $Fo_{89-90}$ of olivines. The ranges of equilibrium temperature, obtained by two pyroxenes geothermometer, are about $951{\sim}1035^{\circ}C$ for Sunheul-ri spinel peridotite xenoliths and are similar to the range of equilibrium temperatures for the xenoliths from other sites in Jeju island. The period of entrainment and transport of the xenoliths in the host magma of Sunheul-ri mantle xenoliths is about 42 days.

Effect of Dry Grinding of Laterite on the Extraction of Nickel and Cobalt (라테라이트광의 건식분쇄가 니켈 및 코발트의 침출에 미치는 영향)

  • Kim, Wan-Tae;Choi, Do-Young;Kim, Sang-Bae
    • Journal of the Mineralogical Society of Korea
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    • v.23 no.3
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    • pp.227-234
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    • 2010
  • We investigated the effect of dry grinding of laterite on the extraction of nickel and cobalt. The major chemical compositions of the sample for this work were $SiO_2$, $Fe_2O_3$ and MgO. The sample contained 0.81% Ni and 0.02% Co. The major minerals of the sample were lizardite and quartz with minor amounts of forsterite and enstatite. The mean particle size, specific surface area and density of the ground sample decreased with increasing grinding time, while the amorphization of lizardite increased as identified by XRD analysis. The grinding enabled the extraction ratio of Ni and Co to increase by the breakdown of Mg-OH bonding in the lizardite structure. However, physical properties of quartz were not changed by grinding. The extraction ratio of Ni and Co increased with increasing grinding time. Approximately 80% of Ni and Co were extracted regardless of the kind of acid solutions when the sample was ground for 60 minutes.

Odorous Emissions from Household-related Sources: A Case Study on a Sewage Treatment Plant (생활악취 배출원의 악취 배출 특성 연구: 하수처리장을 중심으로)

  • Jeon, E.C.;Sa, J.H.;Kim, S.T.;Hong, J.H.;Kim, K.H.
    • Journal of Korean Society for Atmospheric Environment
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    • v.22 no.3
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    • pp.337-351
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    • 2006
  • In this study, to describe the basic characteristics of strong odorous sources, the emissions of odorous compounds from a large-scale sewage treatment plant in K city were investigated. According to this study, the emission patterns of major odorous compounds were distinguished clearly by several factors such as treatment processing types, chemical compositions of odors released, and temporal changes (e.g., seasonal variations). For the purpose of this study, emission rates of odorous compounds were quantified using a dynamic flux chamber (DFC) method from three major treatment (T) processes including T1 (Grit sedimentation basin), T2 (Aeration tank), and T3 (Final sedimentation). When the relative strengths of each emission source were compared, the strongest one was seen from T1 with the maximum of $NH_{3}\;(34.5\;{\mu}g/m^{2}/min)$ followed by $H_{2}S\;(20.4\;{\mu}g/m^{2}/min)($. While the strongest emissions of most odorous compounds were seen commonly from T1, those seen from T2 and T3 were significantly reduced relative to the ones found in T1. Considering the general patterns of odorous emission, it is concluded that control of odors from T1 unit is most important because of its considerably high emission strengths.

Microstructural Evaluation and High Temperature Mechanical Properties of Ni-22Cr-18Fe-9Mo ODS Alloy (Ni-22Cr-18Fe-9Mo계 ODS 합금의 미세조직 및 고온인장 특성 평가)

  • Jeong, Seok-Hoan;Kang, Suk-Hoon;Han, Chang-Hee;Kim, Tae-Kyu;Kim, Do-Hyang;Jang, Jin-Sung
    • Journal of Powder Materials
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    • v.18 no.5
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    • pp.456-462
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    • 2011
  • Yttrium oxide is one of the most thermo-dynamically stable materials, so that it is generally used as a dispersoid in many kinds of dispersion strengthed alloys. In this study, a nickel-base superalloy is strengthened by dispersion of yttrium oxide particles. Elemental powders with the composition of Ni-22Cr-18Fe-9Mo were mechanically alloyed(M.A.) with 0.6 wt% $Y_2O_3$. The MA powders were then HIP(hot isotactic press)ed and hot rolled. Most oxide particles in Ni-22Cr-18Fe-9Mo base ODS alloy were found to be Y-Ti-O type. The oxide particles were uniformly dispersed in the matrix and also on the grain boundaries. Tensile test results show that the yield strength and ultimate tensile strength of ODS alloy specimens were 1.2~1.7 times higher than those of the conventional $Hastelloy^{TM}$ X(R), which has the same chemical compositions with ODS alloy specimens except the oxide particles.