• Title/Summary/Keyword: Chemical compatibility

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Preparation and Characteristic of Sheet Molding Compound using Unsaturated Polyester Resin with Low Profile Agent of Polystyrene (저수축제 폴리스틸렌과 불포화 폴리에스터 수지를 사용한 Sheet Molding Compound 제조 및 특성)

  • Bae, Gi Boong;Lee, Sang Goo;Yoon, Hong Jin;Lee, Jong Dae
    • Korean Chemical Engineering Research
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    • v.50 no.3
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    • pp.588-593
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    • 2012
  • Compatibility of unsaturated polyester (UP) and low profile agent (LPA) of polystyrene (PS) have been investigated under various mixing conditions such as the ratio of UP and LPA, mixing time, mixing temperature, and input amount of 2nd UP. It was possible to obtain mixture with small particle size and low phase separation in condition of 35 g of LPA, 25 g of 1st UP input, 5 min of mixing time, 1700 rpm of mixing speed, and 45 g of 2nd UP input. It was found that compatibility of UP and LPA was very sensitive to mixing conditions. In addition, molded sample using sheet molding compound prepared by stable mixing condition appeared good properties such as low water adsorption, low shrinkage, and high gloss.

Compatibility of POSS Composites with Silicone Monomers and Application to Contact Lenses Material

  • Lee, Min-Jae;Lee, Kyungmun;Sung, A-Young
    • Journal of the Korean Chemical Society
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    • v.64 no.6
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    • pp.354-359
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    • 2020
  • This research was conducted to analyze the compatibility of used monomers and produce the high functional contact lens material containing silicone monomers. Silicone monomer (Sil-OH), Trimethylsilylmethacrylate (TSMA) were used as additives for the basic combination of Polyhedral Oligomeric Silsesquioxane (POSS), methyl methacrylate (MMA) and methyl acrylate (MA). And also, the materials were copolymerized with ethylene glycol dimethacrylate (EGDMA) as the cross-linking agent, AIBN (thermal polymerization initiator) as the initiator. It is judged that the fabricated lenses of all combinations are optically excellent and thus used monomers have good compatibility. Measurement of the optical and physical characteristics of the manufactured hydrophilic lens material were varied in each case. Especially TSMA with POSS increases the oxygen permeability and Sil-OH with POSS increases the wettability by the addition of Sil-OH. These materials were considered to have compatibility each other, so it can be used in functional contact lens material.

Chemical Compatibility of Solidified Liner Materials (매립장 고화차수재의 화학용액과의 반응특성)

  • 정하익;조진우;임재상;김상길
    • Proceedings of the Korean Geotechical Society Conference
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    • 2002.03a
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    • pp.343-346
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    • 2002
  • The chemical compatibility of leachate with the two natural materials was analyzed by performing the hydraulic conductivity test. The selected liner materials were natural marine clay and weathered soil sampled from Kimpo wastefill and Daehwa Dong, Kyonggi Do, respectively. PARAFIX, which is mainly composed of paraffin, cement, stearic acid, PVA etc., was used as solidifying agent. The chemical solutions used in the test were 10% acetic acid, 10% methanol, and real leachate from Kimpo wastefill and the results of tests were compared with that of distilled water. The results of tests show that hydraulic conductivity of solidified clay was increased slightly with permeation of acetic acid, methanol and the increase of hydraulic conductivity was not shown with permeation of leachate, distilled water and in case of weathered soil. Based on the tests, it is ascertained that the tested liner materials can be stable with the solution of low concentration.

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CHEMICAL COMPATIBILITY OF SOIL-BENTONITE CUT-OFF WALL FOR IN-SITU GEOENVIRONMENTAL CONTAINMENT

  • Inui, Toru;Takai, Atsushi;Katsumi, Takeshi;Kamon, Masashi;Araki, Susumu
    • Proceedings of the Korean Geotechical Society Conference
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    • 2010.09c
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    • pp.135-139
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    • 2010
  • A construction technique to install the soil-bentonite (SB) cut-off wall for in-situ geoenvironmental containment by employing the trench cutting and re-mixing deep wall method is first presented in this paper. The laboratory test results on the hydraulic barrier performance of SB in relation to the chemical compatibility are then discussed. Hydraulic conductivity tests using flexible-wall permeameters as well as swell tests were conducted for SB specimens exposed to various types and concentrations of chemicals (calcium chloride, heavy fuel oil, ethanol, and/or seawater) in the permeant and/or in the pore water of original soil. For the SB specimens in which the pore water of original soil did not contain such chemicals and thus the sufficient bentonite hydration occurred, k values were not significantly increased even when permeated with the relatively aggressive chemical solutions such as 1.0 mol/L $CaCl_2$ or 50%-concentration ethanol solution. In contrast, the SB specimens containing $CaCl_2$ in the pore water had the higher k values. The excellent linear correlation between log k and swelling pressure implies that the swelling pressure can be a good indicator for the hydraulic barrier performance of the SB.

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Study on compatibility of cellulose ester/poly(ethylene-co-isosorbide terephthalate) solution blends (셀룰로오스 에스터와 Poly(ethylene-co-isosorbide terephthalate) 용액 블렌드의 상용성에 관한 연구)

  • Kim, Yeon-Hee;Nam, Byeong-Uk
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.5
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    • pp.3351-3356
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    • 2014
  • Recently, Importance of studying based on biomass materials have increased due to the concern about plastic waste problems. Cellulose acetate butyrate (CAB) is a potential alternative to petroleum-based plastics because of its biodegradable property. Poly(ethylene-co-isosorbide terephthalate) (PEIT) is bio-based plastic, produced by isosorbide monomer. In this study, CAB/PEIT blends were prepared by solution blending to improve thermal stability of CAB. CAB and PEIT were dissolved in chloroform, and then precipitated in ethanol. To evaluate the compatibility of CAB/PEIT blends, the morphology and glass transition behaviors were analyzed by FE-SEM and DMA, respectively. TGA results revealed the improved thermal stabilities of the PEIT-rich and 50:50 compositions. No new or changed crystal structures were observed in the XRD result. Finally, CAB/PEIT solution blends showed good compatibility in overall compositions.

The Compatibility of Slurry Wall Materials with Leachate for Cut -off of Contaminated Sites (오염지역 차폐용 슬러리월 재료와 침출수의 반응 특성)

  • 이용수;정하익
    • Geotechnical Engineering
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    • v.13 no.2
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    • pp.9-16
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    • 1997
  • Cut-off methods of controlling leachate migration from waste landfills and contaminated sites are studied. Permeability and chemical compatibility tests are prrforlned on slurry wall materials including soil-bentonite, cement-bentonite, cement / fly ash-bentonite, plastic concrete. Hydraulic conductivity of soil-bentonite mixture is the lowest of these four bacuill materials. The leachate from municipal solid waste has little influence on the permeability of the backfill materials. The bentonite slurry becomes flocculated and aggregated when exposed to the leachate. The results of the permeability test showed that the hydraulic conductivities of the backfill materials are in the order soil-beiltonite, Plastic concrete, cement-bentonite. And the result c: the compatibility test showed increase in permeability due to the effects of leachate. Thus, in designing the slurry wall it is essential to check the behaviour of the bentonite slurry and backfill materials on the compatibility with the contaminants.

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Enhancement of Compatibility between Ultrahigh-Molecular-Weight Polyethylene Particles and Butadiene-Nitrile Rubber Matrix with Nanoscale Ceramic Particles and Characterization of Evolving Layer

  • Shadrinov, Nikolay V.;Sokolova, Marina D.;Okhlopkova, A.A.;Lee, Jungkeun;Jeong, Dae-Yong;Shim, Ee Le;Cho, Jin-Ho
    • Bulletin of the Korean Chemical Society
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    • v.34 no.12
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    • pp.3762-3766
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    • 2013
  • This article examines the modification of surface properties of ultrahigh-molecular-weight polyethylene (UHMWPE) with nanoscale ceramic particles to fabricate an improved composite with butadiene-nitrile rubber (BNR). Adhesion force data showed that ceramic zeolite particles on the surface of UHMWPE modulated the surface state of the polymer and increased its compatibility with BNR. Atomic force microscopy phase images showed that UHMWPE made up the microphase around the zeolite particles and formed the evolving layer with a complex interface. The complex interface resulted in improvements in the mechanical properties of the composite, especially its low-temperature resistance coefficients, thereby improving its performance in low-temperature applications.

Anomalous Permeation Observed in Fluoropolymer

  • Lee, Sang-Wha
    • Proceedings of the Membrane Society of Korea Conference
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    • 2004.05a
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    • pp.140-143
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    • 2004
  • Compatibility of polymeric materials governs their suitability for nearly all potential applications. An aspect of compatibility that is frequently important for fluoropolymers is their ability to isolate fluids by serving as a barrier to mass transport. This property is commonly expressed as permeability. In ideal cases, both solubility and diffusivity are constant at any given temperature and so the permeability is also a constant.(omitted)

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Cell-compatibility of physicochemically and biologically modified polymer surfaces (물리화학적 및 생물학적으로 표면개질된 고분자의 세포 적합성 연구)

  • Lee, J.H.;Park, K.H.;Khang, G.S.;Lee, H.B.;Andrade, J.D.
    • Proceedings of the KOSOMBE Conference
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    • v.1989 no.05
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    • pp.1-3
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    • 1989
  • We have treated polymer surfaces such as polyethylene, polystyrene and polyester by various physicochemical and biological surface modification methods to be suitable for cell adhesion. The physicochemical methods we used were $O_2$ plasma discharge, corona discharge, sulfuric acid and chloric acid treatments. For the biological treatments, blood proteins such as plasma protein, serum protein and fibronectin were adsorbed onto the polymer surfaces. Chinese Hamster Ovary (CHO) cells were cultured on the surface-modified polymers and the cell-compatibility of those surfaces were compared. The chloric acid and fibronectin treatments were found to be the best methods of rendering the polymer surfaces adhesive for CHO cells.

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Enhanced Compatibility of PC/PMMA Alloys by Adding Multiwall Carbon Nanotubes

  • Bae, Do-Young;Lee, Heon-Sang
    • Carbon letters
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    • v.11 no.2
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    • pp.83-89
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    • 2010
  • We prepared polycarbonate (PC)/poly(methyl methacrylate) (PMMA)/multiwall carbon nanotube (MWCNT) nanocomposites by co-rotating twin screw extruder at 533 K. Thermal analysis results indicate that the miscibility of PC and PMMA is enhanced by MWCNTs. Bead necklace-like morphology of PMMA-rich phase is observed in PC/PMMA/MWCNT nanocomposites with increasing PMMA weight fraction due to the bead necklace-like morphology. The tensile strength of PC/PMMA (75/25)/MWCNT (1 wt.%) nanocomposite is 3% higher than those of PC/PMMA (75/25) alloy. Suppression of die swell by MWCNT filler is observed in the melt flow of PC/PMMA/MWCNT nanocomposites during extrusion.