• Title/Summary/Keyword: Chemical cleaning agents

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A Study of On-line Cleaning Method for Increasing Efficiency in a Combustor (연소로 효율증진을 위한 on-line 세정 방법에 관한 연구)

  • Jang, Hyun-Tae;Han, Seung-Dong;Park, Tae-Sung;Cha, Wang-Seong
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.11 no.3
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    • pp.1016-1022
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    • 2010
  • An Experimental study of cleaning solution has been performed on a high capacity steam boiler burning heavy fuel oil to on-line cleaning of deposit. The deposit is mixture of soot, slag, ash, metal oxide and clinker. The traditional technology of deposit cleaning was carried hand-crafted. The conventional technology of boiler cleaning method is mechanical removal by the worker while the boiler shut down operation. In this experiment, the deposit of mixture of soot, slag, ash, metal oxide and clinker has been removed by the cleaning agents without shut down of boiler burning. This study found out the optimum cleaning solution composition. The best results have been obtained when the mixture of ammonium nitrate and $MgNO_3$ were used in cleaning solution. The various transition metal effect was investigated for optimum mixing condition. In this research, the metal compound additive of the clean solution compoition was obtained. The combustion efficiency was improved by on-line cleaning with derived clean solution compoition. On-line cleaning method prevents the fouling and corrosion in the boiler and heat exchanger.

Cleaning of the Waste Reverse Osmosis Membrane Filters for the Household Water Purifier and Their Performance Enhancement Study (정수기용 역삼투 폐분리막 필터의 세정 및 성능 향상 연구)

  • Cho, Young Ju;Rhim, Ji Won
    • Membrane Journal
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    • v.27 no.3
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    • pp.232-239
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    • 2017
  • In this study, the regeneration investigation for waste reverse osmosis membrane filters which were discarded after use for the household water purifiers has been carried out. Sodium hydroxide, sodium bisulfate, and ethylenediamine tetra acetic acid(EDTA). as the chemical cleaning agents were used. And they were in-situ cleaned with the micro-bubble generator as well. The best result was obtained when both 0.1% EDTA and micro-bubbles were used for 30 min cleaning. Thus, when the performance of the brand new RO membrane and restorated RO membrane were compared, the flux, 19.9%, the recovery ratio 45% were enhanced while the salt rejection was reduced for NaCl 100 mg/L solution, in other words, it has been recovered to the original brand new RO membrane filter. Also the removal of pollutants on membrane surface was confirmed in a naked eye through the scanning electron microscopy. Finally, this research has provided the possibility of the re-use of the waste RO membrane filters of household water purifier which were reclaimed or incinerated after use.

Preparation of Solvent-Free Low Foaming Scouring Agents and Their Scouring Characteristics (무용제형 저기포성 정련제의 제조 및 정련특성)

  • Park, Hong-Soo;Ahn, Sung-Hwan;Shim, Il-Woo;Jo, Hye-Jin;Hahm, Hyun-Sik;Kim, Yeoung-Chan;Kim, Seong-Kil
    • Journal of the Korean Applied Science and Technology
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    • v.23 no.1
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    • pp.37-44
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    • 2006
  • Solvent-free low foaming scouring agents (LFSC) were prepared by blending of 2-ethylhexylaminoethyl sulfate (2-EHAS), POE(10) octadecylbenzyl- ammonium chloride (POBAC) and Sedlan FF-200 (FF-200). As the results of several tests, 2-EHAS/POBAC/FF-200/water (8g/12g/20g/60g) mixture (LFSC-5) showed good cleaning power, penetrating ability and stability to alkali, and gave less problem in water pollution. The foaming power of LFSC-5 measured by Ross and Miles method was 8mm foam height immediately after foaming, and that measured by Ross and Clark method was less than 300mm foam height at $30^{\circ}C$, and 18mm at $80^{\circ}C$. As a result, LFSC-5 proved a good low foaming scouring agent for fiber.

Experiment on the Feasibility of Cleaning Building Pipelines using Ultrasonic Cavitation

  • Jo, Jae-Hyun;Lee, Ung-Kyun;Kim, Jae-Yeob;Lee, Sungchul;Kim, Kukhyun
    • International conference on construction engineering and project management
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    • 2022.06a
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    • pp.295-303
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    • 2022
  • Residential heating systems in South Korea are largely based on the use of ondol pipelines. Heat is transferred to the floor by passing hot water through a metal or plastic pipe buried within the concrete of the floor. Consequently, it is difficult to clean the inside of these pipes after installation. Over time, foreign substances such as scale accumulate in the pipe when the ondol heating method is used for an extended period. Therefore, in the past, pipes were cleaned by removing foreign substances attached to the inside surfaces of the pipes using high-pressure water or by disassembling the pipes and removing foreign substances with chemical agents. Recently, a method for removing foreign substances through the cavitation effect of ultrasound has been proposed. This idea might lead to the development of new technologies for cleaning pipe interiors. Consequently, this study investigated the use of ultrasound to clean pipes embedded in concrete. In this study, devices that generated ultrasonic waves with various frequencies and directions were prepared. After preparing arbitrarily contaminated pipes, the appropriate frequency, output strength, and output direction for each foreign substance were determined through repeated experiments. The results of this experiment could provide important information for future methods of cleaning the interior of ondol piping systems.

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A Study on Laboratory Treatment of Metalworking Wastewater Using Ultrafiltration Membrane System and Its Field Application (한외여과막시스템을 이용한 금속가공폐수의 실험실적 처리 및 현장 적용 연구)

  • Bae, Jae Heum;Hwang, In-Gook;Jeon, Sung Duk
    • Korean Chemical Engineering Research
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    • v.43 no.4
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    • pp.487-494
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    • 2005
  • Nowadays a large amount of wastewater containing metal working fluids and cleaning agents is generated during the cleaning process of parts working in various industries of automobile, machine and metal, and electronics etc. In this study, aqueous or semi-aqueous cleaning wastewater contaminated with soluble or nonsoluble oils was treated using ultrafiltration system. And the membrane permeability flux and performance of oil-water separation (or COD removal efficiency) of the ultrafiltration system employing PAN as its membrane material were measured at various operating conditions with change of membrane pore sizes and soil concentrations of wastewater and examined their suitability for wastewater treatment contaminated with soluble or insoluble oil. As a result, in case of wastewater contaminated with soluble oil and aqueous or semi-aqueous cleaning agent, the membrane permeability increased rapidly even though COD removal efficiency was almost constant as 90 or 95% as the membrane pore size increased from 10 kDa to 100 kDa. However, in case of the wastewater contaminated with nonsoluble oil and aqueous or semi-aqueous cleaning agent, as the membrane pore size increased from 10 kDa to 100 kDa and the soil concentration of wastewater increased, the membrane permeability was reduced rapidly while COD removal efficiency was almost constant. These phenomena explain that since the membrane material is hydrophilic PAN material, it blocks nonsoluble oil and reduces membrane permeability. Thus, it can be concluded that the aqueous or semi-aqueous cleaning solution contaminated with soluble oil can be treated by ultrafiltration system with the membrane of PAN material and its pore size of 100 kDa. Based on these basic experimental results, a pilot plant facility of ultrafiltration system with PAN material and 100 kDa pore size was designed, installed and operated in order to treat and recycle alkaline cleaning solution contaminated with deep drawing oil. As a result of its field application, the ultrafiltration system was able to separate aqueous cleaning solution and soluble oil effectively, and recycle them. Further more, it can increase life span of aqueous cleaning solution 12 times compared with the previous process.

Study on the Direct Bonding of Silicon Wafers by Cleaning in $HNO_3:H_2_O2:HF$ (HNO$_3:H_2O_2$ : HF 세척법을 이용한 실리콘 직접 접합 기술에 관한 연구)

  • Joo, C.M.;Choi, W.B.;Kim, Y.S.;Kim, D.N.;Lee, J.S.;Sung, M.Y.
    • Proceedings of the KIEE Conference
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    • 1999.07g
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    • pp.3310-3312
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    • 1999
  • We have studied the method of silicon direct bonding using the mixture of $HNO_$, $H_2O_2$, and HF chemicals called the controlled slight etch (CSE) solution for the effective wafer cleaning. CSE, two combinations of oxidizing and etching agents, have been used to clean the silicon surfaces prior to wafer bonding. Two wafers of silicon and silicon dioxide were contacted each other at room temperature and postannealed at $300{\sim}1100^{\circ}C$ in $N_2$ ambient for 2.5 h. We have cleaned silicon wafers with the various HF concentrations and characterized the parameters with regard to surface roughness, chemical nature, chemical oxide thickness, and bonding energy. It was observed that the chemical oxide thickness on silicon wafer decreased with increasing HF concentrations. The initial interfacial energy and final energy postannealed at $1100^{\circ}C$ for 2.5h measured by the crack propagation method was 122 $mJ/m^2$ and 2.96 $mJ/m^2$, respectively.

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Effect of Interfacial Properties on the Detergency in Dishwashing Agent Composition (식기용 세정제 조성에 있어서 계면물성이 세정력에 미치는 영향)

  • Oh, Hyun-Joo;Lim, Hyo-Seon;Kim, Young-Ho
    • Applied Chemistry for Engineering
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    • v.31 no.2
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    • pp.193-199
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    • 2020
  • The effects of the composition of the dishwashing detergent on interfaces of the oil (O) and the aqueous (W) solution in addition to the cleaning effects of interfacial properties were investigated. Also, the cleaning power of the oil contaminated on the surface of the dish according to each composition and the residuals of the contaminants and the cleaning agent after the washing rinses were evaluated. The removal of contaminated oil on the solid (S) surface in the composition of the cleaning agents used in this study was strongly related to the interfacial properties between the W/O/S, and was particularly dependent on the forward and backward dynamic contact angles. When both contact angles were low at the same time, the permeability of the cleaning solution was so high that the contaminated oil showed a high removal effect. The smaller the interfacial tension of O/W was, the better emulsification of the contaminated oil, the higher the interfacial tension, and the poorer emulsification were achieved. However, the emulsification effect did not significantly affect the cleaning power. In particular, in the case of the cleaner having low interfacial tension, the cleaning material remained on the surface of the solid after washing.

An experimental study on the durability evaluation of concrete applied functional nano composite inorganic activated carbon based coatings (기능성 나노복합 무기질 활성탄계 표면 처리제를 적용한 콘크리트의 내구성능 평가에 관한 실험적 연구)

  • Yang, Gi-Young;Jang, Seog-Jae;Baek, Jong-Myeong
    • Proceedings of the KSR Conference
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    • 2006.11b
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    • pp.1385-1390
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    • 2006
  • Concrete structure can be deteriorated by ingress of moisture and aggressive agents. To maintain the sound performance of concrete structure during the service life, it needs to protect concrete from ingress of moisture and aggressive agents before arising deterioration of concrete. Protection of concrete is possible by surface treatment. In this study, durability of the functional nano composite inorganic activated carbon based coatings which can provide a barrier against the ingress of moisture or aggressive ions to concrete is discussed. For the durability evaluation of the coatings, fine void structure evaluation test, chloride penetration acceleration test, accelerated carbonation test, freezing and thawing test, and the accelerated test of chemical erosion are conducted. As the result of this study, the functional nano composite inorganic activated carbon based coatings which became one formed complex compound with adsorption and porosity on concrete surface, had an effect on the function of far infrared radiation, antimicrobial action, air cleaning, airing assurance, and the interception of moisture of deterioration factor, chloride ion, carbon dioxide, sulfate, and so on.

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Effect on the Hydrogen Peroxide in the Ozonation of Ammonia (오존에 의한 암모니아 산화시 과산화수소가 미치는 영향)

  • 박문숙;안재동;노봉오
    • Journal of Environmental Health Sciences
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    • v.27 no.1
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    • pp.1-7
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    • 2001
  • Ammonia is used in the manufacture of fertilizers, refrigerants, stabilizers and many household cleaning agents. These wide applications resulted in ammonia contamination in water. Ammonia can be removed from water by physical, biological, and chemical methods. Ozonation is effictive in the treatment of water with low concentration of ammonia. This study is undertaken to provide kinetic data for the ozonation of ammonia with or without hydrogen peroxide. The results were as follows; The destruction rate of ammonia increased gradually with the influent hydrogen peroxide concentration up to 0.23 mM and inhibited in the range of 0.23~11.4mM, and the maximum removal rate of ammonia achieved at 0.23mM of hydrogen peroxide, and the overall kinetics was first order. The combination effect of hydrogen and ozone to oxide ammonia in aqueous solution was better than ozone alone. The reacted ammonia was converted completely to nitrate ion.

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Characteristics of ammonia ozonation with bromide (브롬촉매에 의한 암모니아의 오존산화시 특성)

  • 박문숙;양미경
    • Journal of environmental and Sanitary engineering
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    • v.17 no.2
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    • pp.1-10
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    • 2002
  • Ammonia is used in the manufacture of fertilizers, refrigerants, stabilizers and many household cleaning agents. The wide applications result in ammonia contamination in water. Ammonia can be removed from water by physical, biological, and chemical methods. Especially ozonation is effective in the treatment of water with low concentration of ammonia. Therefore, this study is undertaken to provide kinetic data for the ozonation of ammonia with bromide. The results were as follows; Ammonia oxidized by ozone with bromide catalysis. The denitrification rate of the ammonia increased proportionally to the concentration of bromide, and the overall reaction order was zero. It was also found that the effect of bromide ion concentration on the denitrification can be expressed by Monod type equation and there was no more effect above a proper bromide ion concentration. The reacted ammonia was converted completely to nitrate ion without bromide, but the denitrification of ammonia by ozone was conducted in the presence of bromide.