• Title/Summary/Keyword: Chemical and physical characteristics

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A Study on the Properties and Fabrication of Bulk Forming GeSe Based Chalcogenide Glass for Infrared Optical Lens (적외선 광학렌즈 제작을 위한 GeSe의 벌크 제작 및 특성 연구)

  • Bae, Dong-Sik;Yeo, Jong-Bin;Park, Jung-Hoo;Lee, Hyun-Yong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.26 no.9
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    • pp.641-645
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    • 2013
  • Chalcogenide glass has superior property of optical transmittance in the infrared region. Glass made using Ge-Se how many important optical applications. We have determined the composite formular of $Ge_{0.25}Se_{0.75}$ to be the GeSe chalcogenide glass composition appropriate for IR lenses. Also, the optical, thermal and physical characteristics of chalcogenide glass depended on the composition ratio. GeSe bulk sample is produced using the traditional melt-quenching method. The optical, structural, thermal and physical properties of the compound were measured by using Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), Differential scanning calorimeter (DSC), and Scanning electron microscope (SEM) respectively.

Numerical Simulation of the Characteristics of Electrons in Bar-plate DC Negative Corona Discharge Based on a Plasma Chemical Model

  • Liu, Kang-Lin;Liao, Rui-Jin;Zhao, Xue-Tong
    • Journal of Electrical Engineering and Technology
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    • v.10 no.4
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    • pp.1804-1814
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    • 2015
  • In order to explore the characteristics of electrons in DC negative corona discharge, an improved plasma chemical model is presented for the simulation of bar-plate DC corona discharge in dry air. The model is based on plasma hydrodynamics and chemical models in which 12 species are considered. In addition, the photoionization and secondary electron emission effect are also incorporated within the model as well. Based on this model, electron mean energy distribution (EMED), electron density distribution (EDD), generation and dissipation rates of electron at 6 typical time points during a pulse are discussed emphatically. The obtained results show that, the maximum of electron mean energy (EME) appears in field ionization layer which moves towards the anode as time progresses, and its value decreases gradually. Within a pulse process, the electron density (ED) in cathode sheath almost keeps 0, and the maximum of ED appears in the outer layer of the cathode sheath. Among all reactions, R1 and R2 are regarded as the main process of electron proliferation, and R22 plays a dominant role in the dissipation process of electron. The obtained results will provide valuable insights to the physical mechanism of negative corona discharge in air.

Physicochemical Characteristics and Physiological Functions of ${\beta}-Glucans$ in Barley and Oats (보리, 귀리 ${\beta}-Glucan$의 이화학적 특성과 생리적 기능)

  • Lee, Young-Tack
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.41 no.spc1
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    • pp.10-24
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    • 1996
  • [ ($1{\to}3$) ], ($1{\to}4$)-${\beta}$-D-glucans(${\beta}-glucans$) are a major component of the cell walls of grasses as a component of the cereal endosperm and aleurone cell walls. Although ${\beta}-glucans$ exist in all cereals, their concentration is highest in oats and barley. Genetic and environmental differences are found in total ${\beta}-glucan$ content. Both oats and barley ${\beta}-glucans$ have cholesterol-lowering effects. This suggests possible use as food additives. Structural characterization of ${\beta}-glucan$ is important because structure can influence physical and physiological properties. In this review, ${\beta}-glucans$ of barley and oats are discussed in details including structure, chemical and physical properties, and nutritional implications. The use of barley and oat products as well as ${\beta}-glucan$ as a food additive continues to increase. This can provide an additional market for barley and oats, thus increasing the value of the crops.

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The Importance of Essential-Oils in the Green Synthesis of Silver Nanoparticles

  • Barzinjy, Azeez Abdullah
    • Journal of the Korean Chemical Society
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    • v.66 no.4
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    • pp.284-297
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    • 2022
  • The antibacterial activity of metallic nanoparticles (NPs), especially silver (Ag), has been investigated during the course of time in various chemical reactions for antibiotics free agents. Green synthesis of metallic NPs using either microorganisms or plant-extracts has appeared as a simple and replacement to chemical and physical methods. The synthesizing of these NPs through ecofriendly methods signifies an exceedingly applicable approach for offering economical, preferring scalability and possessing negligible ecological influences. Essential-oils are among the subordinate metabolites of plants and their antibacterial anti-inflammatory characteristics have been investigated widely and are commonly attained from the aromatic plants. The usage of essential-oils as reducing agents in biosynthesizing of Ag NPs bring together the interaction of a vital antibacterial agent that simplify the nucleation and growth process within the NPs formation. This review article is offering a progressive process of Ag NPs synthesis using essential oils along with proposing the most applicable formation mechanisms and their antibacterial activities.

Chemical Mechanical Polishing Characteristics of CdTe Thin Films for Application to Large-area Thin Film Solar Cell (대면적 박막 태양전지 적용을 위한 CdTe 박막의 화학적기계적연마 공정 특성)

  • Yang, Jung-Tae;Shin, Sang-Hun;Lee, Woo-Sun
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.58 no.6
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    • pp.1146-1150
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    • 2009
  • Cadmium telluride (CdTe) is one of the most attractive photovoltaic materials due to its low cost, high efficiency and stable performance in physical, optical and electronic properties. Few researches on the influences of uniform surface on the photovoltaic characteristics in large-area CdTe solar cell were not reported. As the preceding study of the effects of thickness-uniformity on the photovoltaic characteristics for the large-area CdTe thin film solar cell, chemical mechanical polishing (CMP) process was investigated for an enhancement of thickness-uniformity. Removal rate of CdTe thin film was 3160 nm/min of the maximum value at the 200 $gf/cm^2$ of down force (pressure) and 60 rpm of table speed (velocity). The removal rate of CdTe thin film was more affected by the down force than the table speed which is the two main factors directly influencing on the removal rate in CMP process. RMS roughness and peak-to-valley roughness of CdTe thin film after CMP process were improved to 96.68% and 85.55%, respectively. The optimum process condition was estimated by 100 $gf/cm^2$ of down force and 60 rpm of table speed with the consideration of good removal uniformity about 5.0% as well as excellent surface roughness for the large-area CdTe solar cell.

Adsorption Characteristics of Methylene Blue from Aqueous Solution According to Physical and Surface Properties of Activated Carbons (활성탄의 물리적 특성과 표면 특성에 따른 수중의 methylene blue의 흡착특성)

  • Kam, Sang-Kyu;You, Hae-Na;Lee, Min-Gyu
    • Journal of Environmental Science International
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    • v.23 no.11
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    • pp.1821-1826
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    • 2014
  • The adsorption characteristics of the methylene blue (MB) were studied using three activated carbons such as ACA and ACB with similar specific surface area (1,185 and $1,105m^2/g$), and ACC with relatively high specific surface area ($1,760m^2/g$). The surface chemical properties of these activated carbons were investigated by X-ray photoelectron spectroscopy (XPS). The results indicated that ACA had more functional groups (with phenol, carbonyl, and carboxyl etc.) than ACB (with carbonyl and carboxyl) and ACC (with carboxyl). The isotherm data were fitted well by Langmuir isotherm model. The adsorption capacities of ACA, ACB, and ACC for MB were 454.7 mg/g, 337.7 mg/g, and 414.0 mg/g, respectively. As phenol and carboxyl content of the surface on activated carbon increased, MB adsorption capacity was increased. Although ACA had a smaller specific surface area than ACC, the content of phenol and carboxyl group was abundant, so MB adsorption capacity was found to be higher than ACC.

High performance epoxy nanocomposites with amine-functionalized graphenes

  • Park, Sol-Mon;Kim, Dae-Su
    • Proceedings of the KAIS Fall Conference
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    • 2010.11a
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    • pp.470-473
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    • 2010
  • Graphene, consisting of a single layer of carbon in a two-dimensional lattice, has been emerging as a fascinating material with many unique physical, chemical and mechanical properties. In this study, graphenes were prepared by a chemical method. To develop high performance polymer nanocomposites reinforced by graphenes, adequate dispersion of the fillers and strong interfacial bonding between the fillers and the polymer matrix are essential. The purpose of this study was to examine the influence of introducing amine groups on the surfaces of graphenes. FT-IR spectroscopy, SEM were used to confirm the functionalization. Epoxy nanocomposites comprising the graphenes were prepared and their characteristics were investigated by DSC, DMA and TMA. Fracture surfaces of the nanocomposites were investigated by SEM. The functionalized graphenes induced strong interfacial bonding than the pristine graphenes and resulted in considerable improvements in the performance of the nanocomposites.

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Soil Physical and Chemical Characteristics of River-Bed Sediments in River Basins (하천 퇴적토양의 이화학적 특성)

  • Zhang, Yong-Seon;Sonn, Yeon-Gye;Park, Chan-Won;Hyun, Byung-Keun;Moon, Yong-Hee;Song, Kwan-Cheol
    • Korean Journal of Soil Science and Fertilizer
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    • v.44 no.6
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    • pp.963-969
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    • 2011
  • The river-bed sediments from the major river basins were analysed for the chemical and physical properties to evaluate environmental safety for the agricultural uses. The samples were taken from 16 sites of Han river, 36 of Geumgang river, 27 of Yeongsan river, and 140 of Nakdong river. The total of 219 samples from the 28 counties were taken from the surface of the sediments at the depth of 50 cm. The particle density of the sediments was greater than $2.63Mg\;m^{-3}$ and the whole range of the density was $2.60{\sim}2.69Mg\;m^{-3}$, the average particle size was 0.7 mm whereas the size range was 0.075~0.85 mm. The analyses of the particle sizes by basins showed that Han and Geumgang river had particle sizes of 0.075~0.85 mm, while Geumgang and Yeongsan river had particle sizes of 0.25~0.85 mm. Geumgang and Yeongsan river tended to have greater particle sizes. The average values of the chemical properties were 6.3 for pH, $0.16dS\;m^{-1}$ for EC, $8g\;kg^{-1}$ for organic matter, $101mg\;kg^{-1}$ for available phosphate, 0.39, 3.47, and $0.93cmol_c\;kg^{-1}$ for exchangeable potassium, calcium, and magnesium respectively. The greatest property at each basin was pH for Han river, Ec, available phosphate and exchangeable sodium for Geumgang river, organic matter, exchangeable calcium and magnesium for Yeongsan river, and exchangeable potassium for Nakdong river.

Effects of Substrate Temperature and Sputter Gas on the Physical Characteristics, Chemical Composition and Preferred Orientation of ZnO Thin Films (기판온도 및 스퍼터가스에 따른 ZnO 박막의 우선배향성, 화학조성, 물리적특성 변화)

  • 김병진;조남희
    • Journal of the Korean Ceramic Society
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    • v.34 no.12
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    • pp.1227-1234
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    • 1997
  • ZnO thin films were prepared by rf-magnetron sputter at various conditions. Crystallinity, microstructure, chemical composition, and optical composition, and optical properties of the films were investigated as functions of substrate temperature (R. T.-50$0^{\circ}C$) an sputter gas (O2/Ar=0-50%). ZnO thin films grown at 50$0^{\circ}C$ with sputter gas of pure argon as well as at R. T. with sputter gas of a mixture of argon & oxygen(O2/Ar=2%) exhibit a strong tendency of (002) preferred orientation, compared with a considerable random orientation at the other conditions. The thin films with (002) preferred orientation has a chemical stoichiometry of Zn/O-1.01, a band gap of 3.3eV, and a packing density of 98% respectively.

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Variational Characteristics of Water Quality and Chlorophyll a Concentration in the Northern Kamak Bay. Southern Korea (가막만 북부해역의 해양환경과 식물플랑크톤 군집의 변동특성 2. 수질환경과 엽록소 a량의 변동특성)

  • 윤양호
    • Journal of Environmental Science International
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    • v.9 no.5
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    • pp.429-436
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    • 2000
  • In order to study on the variational characteristics of water quality and chlorolphyll a concentration the water samples were collected daily or three times a week during the period from April 1990 to November 1991 at Kukdong port located in the northern Kamak bay of Southern Korea I made an analysis on biological factor as chlorophyll a concentration as well as physico-chemical factors such as water temperature salinity sigma-t dissolved oxygen, nutrients (ammonia, nitrite, nitrate, phosphate, and silicate) N/P ratio and chemical oxygen demand. In Northern Kamak bay seasonal variations in physical factors such as water temperature salinity and sigma-t were very marked. On the other hand chemical factors such as nutrients concentration and COD were not so. Chemical factors, in particular silicate were influenced by input of freshwater. And the roles of silicate on the seasonal succession of phytoplankton species composition was very low. Phytoplankton biomass as measured by chlorophyll a concentration was very high all the year round and it was controlled by the combination of several factors especially of N/P ratio determined by dissolved inorganic nitrogen.

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