• Title/Summary/Keyword: Chemical Transport

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Analysis on the Characteristics of Hazardous Chemical Transport Vehicle Accidents in Korea (국내 유해화학물질 운송차량사고 특성분석)

  • Jeong, Jae-uk;Lee, Sang-jae
    • Journal of the Society of Disaster Information
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    • v.16 no.2
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    • pp.310-317
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    • 2020
  • Purpose: In this study, the characteristics of hazardous chemical transport vehicle accidents during the last six years from 2014 to 2019 was analyzed. This study is to prevent chemical transport accidents. Method: Using statistics from the Ministry of Environment, chemical transport vehicle accidents were classified into accident type, accident cause and vehicle type. Result: Of the total 506 cases chemical accidents, 105 cases were caused by transport vehicle. More than 20 percent of total accidents were reported. Most of the accidents were caused by spill·leak. The main causes of the accident were traffic accidents(49 cases) and management negligence(29 cases). This was more than 74% of all transport vehicle accidents. By vehicle type, 57 cases(54%) were most common in tank lorries, followed by trucks (39 cases, 37%) and trailers (9 cases, 9%). Conclusion: In order to prevent accident of transport vehicle, thorough inspection of the transport vehicle is required and safe operation of the driver. In addition, the government needs to expand real-time monitoring of transport vehicles and comprehensively manage different systems by the relevant ministries.

A Study on the Effectiveness of the Hazardous Chemical Transport Vehicle Management System (유해화학물질 운반차량 관리제도 실효성 연구)

  • Kim, Sungbum;Lee, HyunSeung;Jeong, Seongkyeong
    • Journal of the Society of Disaster Information
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    • v.17 no.4
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    • pp.794-801
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    • 2021
  • Purpose: The effectiveness of the transport vehicle management system of the Chemical Substances Control Act will be studies and used as basic data for future system improvement plans. Method: After the enforcement of the Chemical Substances Control Act, the effectiveness for the transport vehicle management system was studies by comparing the transport plan, guidance and inspection status, safety training completion management, ect., and the reduction rate of chemical accidents. Results: The average number of chemical accidents in transport vehicles nationwide is 20 each year. And It is decreasing with the stabilization of the Chemical Substances Control Act('15.1.1). The first reason for the decrease in chemical accidents is the increase in submission of transport plans. Second, as the guidance and inspection rate increased every year, the shipper company's management of transport companies was naturally strengthened. Finally, it is judged that chemical accident caused by transport vehicles decrease through safety education. Conclusion: The current tranport vehicle management system of the Chemical Substances Control Act is effective. However, further research is needed to improve the practical and efficient transport vehicle management system.

Transport Coefficients across Charged Mosaic Membrane

  • Yang, Wong-Kang
    • Bulletin of the Korean Chemical Society
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    • v.25 no.5
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    • pp.665-667
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    • 2004
  • In previous studies, charged mosaic membranes having two different fixed charges in the membrane matrix indicated unique transport behavior such as preferential material transport. In this study, the composite charged mosaic membrane endurable to mechanical pressure in practical application was investigated from the same aspect of solute and solvent transport as before. Lp and ${\omega}$ estimated by taking account of active layer thickness were satisfactorily consistent with those in mosaic membrane without reinforcement. On the other hand, the reflection coefficient s indicated the negative value that suggests preferential material transport.

Single Crystalline NbO2 Nanowire Synthesis by Chemical Vapor Transport Method

  • Lee, Sung-Hun;Yoon, Ha-Na;Yoon, Il-Sun;Kim, Bong-Soo
    • Bulletin of the Korean Chemical Society
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    • v.33 no.3
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    • pp.839-842
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    • 2012
  • We report for the first time the synthesis of niobium dioxide nanowires on a sapphire substrate by chemical vapor transport method. We identified single crystalline nature of as-synthesized nanowires by scanning electron microscopy and transmission electron microscopy. Niobium dioxide nanowires with their large surface-to-volume ratio and high activities can be employed for electrochemical catalysts and immunosensors. The Raman spectrum of niobium dioxide nanowires also confirmed their identity.

Performance Comparison of CuPc, Tetracene, Pentacene-based Photovoltaic Cells with PIN Structures

  • Hwang, Jong-Won;Kang, Yong-Su;Park, Seong-Hui;Lee, Hye-Hyun;Jo, Young-Ran;Choe, Young-Son
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.311-312
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    • 2010
  • The fabricated photovoltaic cells based on PIN heterojunctions, in this study, have a structure of ITO/poly(3, 4-ethylenedioxythiophene)-poly(styrenesulfonate)(PEDOT:PSS)/donor/donor:C60(10nm)/C60(35nm)/2, 9-dimethyl-4, 7-diphenyl-1, 10-phenanthroline(8nm)/Al(100nm). The thicknesses of an active layer(donor:C60), an electron transport layer(C60), and hole/exciton blocking layer(BCP) were fixed in the organic photovoltaic cells. We investigated the performance characteristics of the PIN organic photovoltaic cells with copper phthalocyanine(CuPc), tetracene and pentacene as a hole transport layer. Discussion on the photovoltaic cells with CuPc, tetracene and pentacene as a hole transport layer is focussed on the dependency of the power conversion efficiency on the deposition rate and thickness of hole transport layer. The device performance characteristics are elucidated from open-circuit-voltage(Voc), short-circuit-current(Jsc), fill factor(FF), and power conversion efficiency($\eta$). As the deposition rate of donor is reduced, the power conversion efficiency is enhanced by increased short-circuit-current(Jsc). The CuPc-based PIN photovoltaic cell has the limited dependency of power conversion efficiency on the thickness of hole transport layer because of relatively short exciton diffusion length. The photovoltaic cell using tetracene as a hole transport layer, which has relatively long diffusion length, has low efficiency. The maximum power conversion efficiencies of CuPc, tetracene, and pentacene-based photovoltaic cells with optimized deposition rate and thickness of hole transport layer have been achieved to 1.63%, 1.33% and 2.15%, respectively. The photovoltaic cell using pentacene as a hole transport layer showed the highest efficiency because of dramatically enhanced Jsc due to long diffusion length and strong thickness dependence.

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Effect of Overlayer Thickness of Hole Transport Material on Photovoltaic Performance in Solid-Sate Dye-Sensitized Solar Cell

  • Kim, Hui-Seon;Lee, Chang-Ryul;Jang, In-Hyuk;Kang, Wee-Kyung;Park, Nam-Gyu
    • Bulletin of the Korean Chemical Society
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    • v.33 no.2
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    • pp.670-674
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    • 2012
  • The photovoltaic performance of solid-state dye-sensitized solar cells employing hole transport material (HTM), 2,2',7,7'-tetrakis-(N,N-di-p-methoxyphenyl-amine)-9,9'-spirobifluorene (spiro-MeOTAD), has been investigated in terms of HTM overlayer thickness. Two important parameters, soak time and spin-coating rate, are varied to control the HTM thickness. Decrease in the period of loading the spiro-MeOTAD solution on $TiO_2$ layer (soak time) leads to decrease in the HTM overlayer thickness, whereas decrease in spin-coating rate increases the HTM overlayer thickness. Photocurrent density and fill factor increase with decreasing the overlayer thickness, whereas open-circuit voltage remains almost unchanged. The improved photocurrent density is mainly ascribed to the enhanced charge transport rate, associated with the improved charge collection efficiency. Among the studied HTM overlayer thicknesses, ca. 230 nm-thick HTM overlayer demonstrates best efficiency of 4.5% at AM 1.5G one sun light intensity.