• Title/Summary/Keyword: Chemical Tools

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Design of Heat Exchanger for Section 3 of SI Hydrogen Production Process (SI 수소생산 공정 Section 3 열교환기 설계)

  • Kim, Ki-Sub;Park, Byung Heung
    • Journal of Institute of Convergence Technology
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    • v.7 no.1
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    • pp.19-22
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    • 2017
  • SI process is one of the most advanced thermochemical water splitting cycles enabling mass production of hydrogen without emitting carbon dioxide when coupled to nuclear heat energy. The highest temperature (close to $1000^{\circ}C$) required in SI process is well matched with the outlet temperature of a coolant circulating a high-temperature gas-cooled reactor at around $950^{\circ}C$. In Section 3, some heat exchangers are included to recover heats from process flows at high temperature. In this work, we designed a heat exchanger based on the $1Nm^3/hr$ $H_2$ production capacity using commercial tools for chemical process design.

Chemical Abundances of 93 Planet Host stars

  • Kang, Won-Seok;Lee, Sang-Gak;Kim, Kang-Min
    • The Bulletin of The Korean Astronomical Society
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    • v.35 no.2
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    • pp.78.1-78.1
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    • 2010
  • We obtained the spectra of 93 Planet host stars and 73 normal field stars in F, G, K type using BOES at BOAO. We measured the equivalent width of Fe and 13 elements lines using the automatic EW measurement program, TAME(Tools for Automatic Measurement of Equivalent-widths) and estimated the abundances by synth and abfind driver of MOOG code. Since the absence of planets in the normal field stars cannot be "completely" proved, this work focused on the chemical abundances and planet properties of planet host stars, which have the massive planets close to the parent star relatively. We carried out an investigation for the difference of abundances between stars with "Hot Jupiter" and normal field stars with no known planets. We examined the chemical composition of 12 elements, such as Na, Mg, Al, Si, Ca, Sc, Ti, V, Cr, Mn, Co, and Ni by EW measurements, and the S abundances were estimated using synthetic spectrum.

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Control of Slurry Flow Rate in Copper CMP (구리 CMP시 슬러리 Flow Rate의 조절)

  • Kim, Tae-Gun;Kim, Nam-Hoon;Kim, Sang-Yong;Seo, Yong-Jin;Chang, Eui-Goo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.04b
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    • pp.34-37
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    • 2004
  • Recently advancing mobile communication tools and I.T industry, semiconductor device is requested more integrated, faster operation time and more scaled-down. Because of these reasons semiconductor device is requested multilayer interconnection. For the multilayer interconnection chemical mechanical polishing (CMP) becomes one of the most useful process in semiconductor manufacturing process. In this experiment, we focus on understand the characterize and improve the CMP technology by control of slurry flow rate. Consequently, we obtain that optimal flow rate of slurry is 170ml/min, since optimal conditions are less chemical flow and performance high with good selectivity to Ta. If we apply this results to copper CMP process. it is thought that we will be able to obtain better yield.

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The Synthesis of Sensitizing Dye for Photographic Emulsion (사진유제용 증감색소의 합성)

  • Kim, Yeoung-Chan;Kang, Tai-Sung;Sohn, Byoung-Chung
    • Journal of the Korean Applied Science and Technology
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    • v.12 no.2
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    • pp.5-11
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    • 1995
  • In the study, sensitizing dye was prepared by the reaction of 2-methyl-3-sulfopropyl-5-phenyl-benzoxazolium(inner salt) with ortho-ester in the presence of triethylamine. The product was identified by using various analytical tools such as Elemental analyzer, IR spectrophotometer, UV-Vis spectrophotometer, $^{1}H$-NMR spectrometer, TGA and DSC. Therefore, it was concluded that benzoxazolo carbocyanine dye can be used as green-sensitizing dye for the spectral sensitization of photographic emulsion.

The Chemical Vapor Deposition of TiN on Cemented Tungsten Carbide Cutting Tools (초연합금절단공구상에 TiN의 화학증착피막에 관한 연구)

  • 이상래
    • Journal of the Korean institute of surface engineering
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    • v.15 no.3
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    • pp.138-145
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    • 1982
  • The effects of the simultaneous variations of the ratio of feed gases(H2/N2 Flow ratio), feed gas flow rate (H2/N2, total-flow rate) and partial pressures of TiCl4 (PTiCl41) as well as deposition time and cobalt content of the substrate on the deposition rate of the TiN Coated Cemented Tungsten Carbide Tools were investigated. Deposition was carried out in the temperature range of 930$^{\circ}C$-1080$^{\circ}C$ and an activation energy of 46.5 Kcal/mole can be calculated. Transverse rupture strength was noticeably reduced by the TiN coating on the virgin surfa-ce of Cemented Tungsten Carbide, the extent of which was decreased according to the coa-ting thickness. Microhardness value observed on the work was in the range of 1700∼2000kg/mm, which were in well agreement with the value of bult TiN. The wear resistance of TiN layers was performed by turning test and it was observed that crater and flank resistance remarkably enhanced by TiN coating.

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Diamond micro-cutting of the difficult -to -cut materials using Electrolysis (전기분해를 이용한 난삭재의 다이아몬드 미세가공)

  • 손성민;손민기;임한석;안중환
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2000.11a
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    • pp.951-954
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    • 2000
  • This paper presents a new cutting method, i.e. diamond cutting, aided by electrolysis, in order to cut ferrous materials with diamond tools. Diamond cutting is widely applied in manufacturing ultraprecision parts such as magnetic disk, polygon mirror, spherical/non-spherical mirror and copier drum, etc. because of the diamond tool edge sharpness. In general, however, diamond cutting cannot be applied to cutting steels, because diamond tools wear excessively in cutting iron based materials like steel due to their high chemical interaction with iron in high temperature. In order to suppress the diffusion of carbon from the diamond tool and to reduce increase of cutting force due to size effect, we attempt to change chemically the compositions of iron based materials using electrolysis in a limited part which will be soon cut. Through experiments under several micro-machining and electrolysis conditions, cutting using electrolysis, compared to conventional cutting, was found to result in a great decrease of the cutting force, a better surface and much less wear tool.

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The Metallization of Diamond Grits

  • Sung, James-C.;Hu, Shao-Chung;Chang, Yen-Shuo
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1134-1135
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    • 2006
  • A revolutionary "Active Braze Coated Diamond" (ABCD) has been developed for bonding diamond grits firmly in the metal matrix. The molten braze is wetted and reacted with diamond to form strong chemical bond at the interface so that the diamond does not become knocked out of tools. The ABC is a nickel alloy that can form metallurgical diffusion bondswith the metal matrix. In essence, ABCD turns diamond into a metal grain so that the diamond tools can be made by conventional powder metallurgical process without being concerned about the poor bonding between matrix metal powder and the diamond as before.

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Recent Trends in Cyclic Peptides as Therapeutic Agents and Biochemical Tools

  • Choi, Joon-Seok;Joo, Sang Hoon
    • Biomolecules & Therapeutics
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    • v.28 no.1
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    • pp.18-24
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    • 2020
  • Notable progress has been made in the therapeutic and research applications of cyclic peptides since our previous review. New drugs based on cyclic peptides are entering the market, such as plecanatide, a cyclic peptide approved by the United States Food and Drug Administration in 2017 for the treatment of chronic idiopathic constipation. In this review, we discuss recent developments in stapled peptides, prepared with the use of chemical linkers, and bicyclic/tricyclic peptides with more than two rings. These have widespread applications for clinical and research purposes: imaging, diagnostics, improvement of oral absorption, enzyme inhibition, development of receptor agonist/antagonist, and the modulation of protein-protein interaction or protein-RNA interaction. Many cyclic peptides are expected to emerge as therapeutics and biochemical tools.

Synthesis and Catalytic Applications of Ruthenium(0) Nanoparticles in Click Chemistry

  • Kumar, Avvaru Praveen;Baek, Min-Wook;Sridhar, Chirumarry;Kumar, Begari Prem;Lee, Yong-Ill
    • Bulletin of the Korean Chemical Society
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    • v.35 no.4
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    • pp.1144-1148
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    • 2014
  • Here we report a facile synthesis of ruthenium (Ru) Nanoparticles (NPs) by chemical co-precipitation method. The calcination of ruthenium hydroxide samples at $500^{\circ}C$ under hydrogen atmosphere lead to the formation of $Ru^0$ NPs. The size and aggregation of Ru NPs depends on the pH of the medium, and type of surfactant and its concentration. The X-ray diffraction (XRD), scanning electron microscope (SEM) and transmission electron microscope image (TEM) analyses of particles indicated the formation of $Ru^0$ NPs, and have 10 to 20 nm sizes. As-synthesized $Ru^0$ NPs are characterized and investigated their catalytic ability in click chemistry (azidealkyne cycloaddition reactions), showing good results in terms of reactivity. Interestingly, small structural differences in triazines influence the catalytic activity of $Ru^0$ nanocatalysts. Click chemistry has recently emerged to become one of the most powerful tools in drug discovery, chemical biology, proteomics, medical sciences and nanotechnology/nanomedicine. In addition, preliminary tests of recycling showed good results with neither loss of activity or significant precipitation.

Study on the Safe use of the Chemical Extinguishing Agent (화학물질 소화약제 안전한 사용에 관한 연구)

  • Cho, Jung-Rae
    • Fire Science and Engineering
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    • v.32 no.2
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    • pp.118-129
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    • 2018
  • This study analyzed the recent serious disaster cases of chemical extinguishing agent poisoning and suffocation investigated by KOSHA and proposed the safe use of chemical substances, including the chemical extinguishing agent. An analysis of the statistical figures an increase in the number and variations of chemical poisoning and suffocation cases in industry between 2011~2016 increased. Unlike other physical accidents, chemical accidents are very high in severity and it is difficult to identify the chemical hazard and risk. To prevent chemical disasters, it is essential to develop and use an easy chemical risk assessment tool. For the safe use of chemical substances, in which it is difficult to carry out hazard identification and risk assessments, this thesis presents the useful chemical recognition and risk assessment tools, CHEM-i and CHARM developed by KOSHA.