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http://dx.doi.org/10.5012/bkcs.2014.35.4.1144

Synthesis and Catalytic Applications of Ruthenium(0) Nanoparticles in Click Chemistry  

Kumar, Avvaru Praveen (Department of Chemistry, Changwon National University)
Baek, Min-Wook (Department of Chemistry, Changwon National University)
Sridhar, Chirumarry (Department of Chemistry, Changwon National University)
Kumar, Begari Prem (Department of Chemistry, Changwon National University)
Lee, Yong-Ill (Department of Chemistry, Changwon National University)
Publication Information
Bulletin of the Korean Chemical Society / v.35, no.4, 2014 , pp. 1144-1148 More about this Journal
Abstract
Here we report a facile synthesis of ruthenium (Ru) Nanoparticles (NPs) by chemical co-precipitation method. The calcination of ruthenium hydroxide samples at $500^{\circ}C$ under hydrogen atmosphere lead to the formation of $Ru^0$ NPs. The size and aggregation of Ru NPs depends on the pH of the medium, and type of surfactant and its concentration. The X-ray diffraction (XRD), scanning electron microscope (SEM) and transmission electron microscope image (TEM) analyses of particles indicated the formation of $Ru^0$ NPs, and have 10 to 20 nm sizes. As-synthesized $Ru^0$ NPs are characterized and investigated their catalytic ability in click chemistry (azidealkyne cycloaddition reactions), showing good results in terms of reactivity. Interestingly, small structural differences in triazines influence the catalytic activity of $Ru^0$ nanocatalysts. Click chemistry has recently emerged to become one of the most powerful tools in drug discovery, chemical biology, proteomics, medical sciences and nanotechnology/nanomedicine. In addition, preliminary tests of recycling showed good results with neither loss of activity or significant precipitation.
Keywords
$Ru^0$ Nanoparticles; Chemical co-precipitation; Catalytic activity; Click chemistry;
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1 Cao, N.; Luo, W.; Cheng, G. Z. Int. J. Hydrogen Energ. 2013, 38, 11964.   DOI   ScienceOn
2 Mishra, D. K.; Dabbawala, A. A.; Hwang, J. S. Catal. Commun. 2013, 41, 52.   DOI   ScienceOn
3 Moses, J. E.; Moorhouse, A. D. Chem. Soc. Rev. 2007, 36, 1249.   DOI   ScienceOn
4 Paria, S.; Khilar, K. C. Adv. Colloid Interface Sci. 2004, 110, 75.   DOI   ScienceOn
5 Patakfalvi, R.; Papp, S.; Dekany, I. J. Nanopart. Res. 2007, 9, 353.   DOI
6 Thirumurugan, P.; Matosiuk, D.; Jozwiak, K. Chem. Rev. 2013, 113, 4905.   DOI   ScienceOn
7 Hein, C.; Liu, X. M.; Wang, D. Pharm. Res. 2008, 25, 2216.   DOI
8 Tornoe, C. W.; Christensen, C.; Meldal, M. J. Org. Chem. 2002, 67, 3057.   DOI   ScienceOn
9 Breinbauer, R.; Kohn, M. ChemBioChem 2003, 4, 1147.   DOI   ScienceOn
10 Lutz, J. F. Angew. Chem. Int. Ed. 2007, 46, 1018.   DOI   ScienceOn
11 Zhang, L.; Chen, X.; Xue, P.; Sun, H. H. Y.; Williams, I. D.; Sharpless, K. B.; Fokin, V. V.; Jia, G. J. Am. Chem. Soc. 2005, 127, 15998.   DOI   ScienceOn
12 Rasmussen, L. K.; Boren, B. C.; Fokin, V. V. Org. Lett. 2007, 9, 5337.   DOI   ScienceOn
13 Boren, B. C.; Narayan, S.; Rasmussen, L. K.; Zhang, L.; Zhao, H.; Lin, Z.; Jia, G.; Fokin, V. V. J. Am. Chem. Soc. 2008, 130, 8923.   DOI   ScienceOn
14 Tang, Z.; Kotov, N. A. Adv. Mater. 2005, 17, 951.   DOI   ScienceOn
15 Kirchhoff, M. M. Resour. Conserv. Recy. 2005, 44, 237.   DOI   ScienceOn
16 Zhang, L.; Chen, X. G.; Xue, P.; Sun, H. H. Y.; Williams, I. D.; Sharpless, K. B. J. Am. Chem. Soc. 2005, 127, 15998.   DOI   ScienceOn
17 Kumar, A. P.; Kumar, B. P.; Kumar, A. B. V. K.; Huy, B. T.; Lee, Y. I. Appl. Surf. Sci. 2013, 265, 500.   DOI   ScienceOn
18 Daniel, M. C.; Astruc, D. Chem. Rev. 2003, 104, 293.
19 Astruc, D.; Lu, F.; Aranzaes, J. R. Angew. Chem. Int. Ed. 2005, 44, 7852.   DOI   ScienceOn
20 Yan, N.; Xiao, C.; Kou, Y. Coord. Chem. Rev. 2010, 254, 1179.   DOI   ScienceOn
21 Naota, T.; Takaya, H.; Murahashi, S. I. Chem. Rev. 1998, 98, 2599.   DOI   ScienceOn
22 Mallat, T.; Baiker, A. Chem. Rev. 2004, 104, 3037.   DOI   ScienceOn
23 Chang, K. H.; Hu, C. C. Electrochem. Solid St. 2004, 7, A466.   DOI   ScienceOn
24 Neupane, S.; Kaganas, G.; Valenzuela, R.; Kumari, L.; Wang, X. W.; Li, W. Z. J. Mater. Sci. 2011, 46, 4803.   DOI
25 Antonetti, C.; Oubenali, M.; Raspolli Galletti, A. M.; Serp, P.; Vannucci, G. Appl. Catal. A 2012, 421-422, 99.   DOI   ScienceOn
26 Guerrero, M.; Roucoux, A.; Denicourt-Nowicki, A.; Bricout, H.; Monflier, E.; Colliere, V.; Fajerwerg, K.; Philippot, K. Catal. Today 2012, 183, 34.   DOI   ScienceOn
27 Gao, S.; Zhang, J.; Zhu, Y. F.; Che, C. M. New J. Chem. 2000, 24, 739.   DOI
28 Dikhtiarenko, A.; Khainakov, S. A.; Garcia, J. R.; Gimeno, J.; de Pedro, I.; Fernandez, J. R.; Blanco, J. A. J. Alloys Compd. 2012, 536, S437.   DOI   ScienceOn
29 Das, P.; Aggarwal, N.; Guha, N. R. Tetrahedron Lett. 2013, 54, 2924.   DOI   ScienceOn
30 Kolb, H. C.; Sharpless, K. B. Drug Discov. Today 2003, 8, 1128.   DOI   ScienceOn
31 Rostovtsev, V. V.; Green, L. G.; Fokin, V. V.; Sharpless, K. B. Angew. Chem. Int. Ed. 2002, 41, 2596.   DOI
32 Olivier, C.; Costuas, K.; Choua, S.; Maurel, V.; Turek, P.; Saillard, J. Y.; Touchard, D.; Rigaut, S. J. Am. Chem. Soc. 2010, 132, 5638.   DOI   ScienceOn
33 Tron, G. C.; Pirali, T.; Billington, R. A.; Canonico, P. L.; Sorba, G.; Genazzani, A. A. Med. Res. Rev. 2008, 28, 278.   DOI   ScienceOn