• 제목/요약/키워드: Chemical Substances

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감자 유래 극성화합물의 생리활성 분석 (Biological Activity Analysis of Potato-derived Polar Compounds)

  • 김대윤;남정환;이재권
    • 한국자원식물학회:학술대회논문집
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    • 한국자원식물학회 2019년도 추계학술대회
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    • pp.62-62
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    • 2019
  • Natural substances have various physiological activities. Substances isolated from natural substances are known to be safer and more potent than pharmaceuticals. Potatoes not only act as energy sources but also contain active ingredients such as vitamins and minerals. In particular, the potato contains a large amount of polar compounds, including the saponin in the polar compounds, and the physiological activity of the saponins, such as immunity enhancement, antioxidant and anti-inflammatory is known. In this study, the antioxidative activity of polar compounds from five potatoes was examined by chemical base anti-oxidation assay and cell based anti-oxidation assay. In the chemical base anti-oxidation assay, DPPH experiment showed activity in the order of Hongyoung, Haryung, Seohong, Sumi, and Jayoung. In the LPA experiment, IC50 was lower in the order of Jayoung, Seohong, Sumi, Hongyoung, and Haryung. In the cell based anti-oxidation assay, the smallest amount of ROS was generated when the compound was derived from Haryung and hongyoung, and strong SOD activity was observed in Sumi and Jayoung. The results of this study reveal the antioxidative effect of polar compounds extracted from various kind of potatoes, which will enable the acquisition of new bioactive candidates and the establishment of new profit generation models for farmers.

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다양한 수생태계에 적용 가능한 유해물질의 영양확대계수 (trophic magnification factor, TMF) 연구 - 생활화학제품에서 기인한 성분과 어류조사를 중심으로 (A Direction of the Monitoring of Household Chemical Products in Aquatic Environments: The Necessities for a Trophic Magnification Factor (TMF) Research on Fish)

  • 원은지;조하은;김도균;홍성진;신경훈
    • 생태와환경
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    • 제55권3호
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    • pp.185-200
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    • 2022
  • 수환경 내 다양한 유해물질의 위해성에 대한 관심은 환경 매체 내 물질의 농도뿐만 아니라 복잡한 먹이단계를 통한 어류 체내의 축적과 어류를 통한 인체 위해성으로 이어진다. 국내의 경우 2016년 이후 생활에서 사용되고 있는 화학제품(생활화학제품) 기인 위해 우려물질의 관리를 위한 등록과 평가 등에 관한 법률 개정과 함께 이들 물질의 환경 배출이 주목받게 됨에 따라 수생태계 내 잔류여부에 대한 조사도 수행되기 시작했다. 최근에는 이러한 물질의 관리를 위한 생태계 내 분포 조사 및 배출 계수 산정을 위한 연구사업이 수행되고 있는데 해당 연구 사업에서는 세정제, 접착제, 염색제, 방향제 등을 비롯한 화장품이나 세제 등에 포함되는 성분과 살균·소독제를 대상으로 영양단계 내 축적과 전달을 이해하기 위한 물질의 축적과 확대를 포함한다. 본 논문은 최근 발표된 생활화학제품기인 유해물질의 수환경 유입 및 분포에 대한 연구 결과를 정리하고 그 과학적 의미를 제시하며 또한 국내외 수행되고 있는 수환경 모니터링 기법에 대한 연구의 예를 바탕으로 현재 유해화학물질의 수환경 내 잔류 농도 및 분포, 생태계 모니터링을 위한 연구의 방향을 제안하고자 한다. 특히 어류를 대상으로 하는 조사에서 국내 수역에 서식하는 주요 어류조사 및 이를 바탕으로 한 대상 어류 선정의 필요성과 인체 위해성 연구의 필요성 등 시기적으로 요구되는 연구를 위한 영양단계 해석과 생물확대계수 연구의 방향을 소개하며 향후 국내에서 수행되고 있는 생물상 모니터링과 화학물질 연구에 대한 제언을 포함한다.

다단오존접촉조에서 유해화학물질의 제거특성 (Removal Characteristics of Hazard Organic Substances in the Multi-stage Ozone Contactor)

  • 박영규
    • 환경위생공학
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    • 제14권4호
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    • pp.41-49
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    • 1999
  • The water treatment by was performed to remove VOC and organic substances in the multi-stage ozone contactor. Ozone is mainly utilized to change the chemical structures of organic substance, of which finally has the purpose to degrad them. The removal efficiency of VOC has 20~60% at the ozone concentration of 3 ppm, in case of trichloroethylene, its efficiency is reduced by 85% at the ozone contact time of 8 min. Design factors such as the number of stage, ozone concentration, zone contact time are determined for optimal treatment in the multi-stage contactor.

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도입종 애기수영의 생태 특성 (Ecological Characteristics of Introduced Species, Rumex acetosella)

  • 길봉섭;유현경;신성은;김영식;백순옥
    • The Korean Journal of Ecology
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    • 제20권6호
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    • pp.413-421
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    • 1997
  • Ecological characteristics of Rumex acetosella have been studied both in the laboratory and in the field. R. acetosella grows well straight up after germination, elongating and thickening their rhizomes with sprouts erupting along their bodies of the rhizome. The number and development of leaves and ramets reach their peak by April. The size of leaves and the cover degree of the plant increase from April to May. R. acetosella is an ephemeral, a short life mode plant, finishing its life cycle in July or August. The germination and seedling growth of selected species exposed to aqueous extracts of R. acetosella were in inverse proportion to concentration. The growth of Rumex japonicus and Digitaria sanguinalis cultivated in soil with R. acetosella was more inhibited than that of the control. Twelve chemical compounds were identified from R. acetosella by GC and HPLC and verified by bioassay with the same chemical reagents. It would be assdumed that these chemical substances are responsible for the allelopathic effect of R. acetosella. In short, R. acetosella plants grow vigorously from April and maintain their superior competitive ability to other plants in forming their communities by emitting chemical substances into their environment.

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Nanosecond Gated Raman Spectroscopy for Standoff Detection of Hazardous Materials

  • Chung, Jin Hyuk;Cho, Soo Gyeong
    • Bulletin of the Korean Chemical Society
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    • 제35권12호
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    • pp.3547-3552
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    • 2014
  • Laser Raman spectroscopy is one of the most powerful technologies for standoff detection of hazardous materials including explosives. Supported by recent development of laser and sensitive ICCD camera, the technology can identify trace amount of unknown substances in a distance. Using this concept, we built a standoff detection system, in which nanosecond pulse laser and nanosecond gating ICCD technique were delicately devised to avoid the large background noise which suppressed weak Raman signals from the target sample. In standoff detection of explosives which have large kill radius, one of the most important technical issues is the detection distance from the target. Hence, we focused to increase the detection distance up to 54 m by careful optimization of optics and laser settings. The Raman spectra of hazardous materials observed at the distance of 54 m were fully identifiable. We succeeded to detect and identify eleven hazardous materials of liquid or solid particles, which were either explosives or chemical substances used frequently in chemical plants. We also performed experiments to establish the limit of detection (LOD) of HMX at 10 m, which was estimated to be 6 mg.

과불화합물의 규제 및 산업적 용도에 대한 화학구조적 고찰 (Chemical Structural Approach to Understand Global Prohibition on Perfluorinated Compounds and their Uses)

  • 최은경;나진성;조영달;송기봉;이수영;석광설
    • 한국염색가공학회지
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    • 제28권3호
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    • pp.134-155
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    • 2016
  • Perfluorinated chemicals are highly diverse and widely used. More than 160 substances are pre-registered under REACH and approximately 140 substances are in the existing chemicals list of Korea from this chemical group. Chemical structures of PFCs that are globally prohibited and still in uses are identified with OECD's classification of PFCs with an overall review on their uses in consumer products including textile products. Case examples for current domestic situation on use of PFCs as a major component of water-repelling agents in textile products as well as a brief summary of eight major PFC manufacturers' situation are presented from our survey study along the supply chains and the most recent report of EPA stewardship programme, respectively.

사료제조 공장의 발생악취 특성 및 약액세정탑을 이용한 악취저감효율 평가 (Characteristic of odor from feed manufactory and evaluation of odor reduction efficiency using chemical scrubber)

  • 임지영;전용빈;송승준;조영근;김진한
    • 실내환경 및 냄새 학회지
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    • 제17권4호
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    • pp.389-395
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    • 2018
  • The odor substances generated in a feed manufactory operating for the commercialization of animal-vegetable materials were analyzed and the odor reduction efficiency by a chemical scrubber was evaluated. The major causative substances in the feed manufactory comprised about 45.4% of ketone compounds and about 13.3% of aldehyde compounds. On the other hand, the removal efficiencies of diacetyl and acetoin as ketone compounds were 77.3% and 78.1%, respectively, by a chemical scrubber. Additionally, the removal efficiencies of acetaldehyde, butyraldehyde, valeraldehyde, 2-furancarboxaldehyde, and nonanal were 86.0%, 78.9%, 67.4%, 52.8%, and 71.9%, respectively. These rates were higher than the odor generation substance contribution rate as a result of treating the exhaust gas generated from the feed manufactory by the chemical scrubber using 5% of C3. It was also found that xylene, methylcyclopentane, benzene, ethylbenzene, 1,3,5-trimethylbenzene, and decane were almost not removed.

Chemical Constituents of the Fruiting Bodies of Clitocybe nebularis and Their Antifungal Activity

  • Kim, Young-Sook;Lee, In-Kyoung;Seok, Soon-Ja;Yun, Bong-Sik
    • Mycobiology
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    • 제36권2호
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    • pp.110-113
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    • 2008
  • During a continuing search for antimicrobial substances from Korean native wild mushroom extracts, we found that the methanolic extract of the fruiting body of Clitocybe nebularis exhibited mild antifungal activity against pathogenic fungi. Therefore we evaluated the antifungal substances and other chemical components of the fruiting body of Clitocybe nebularis, which led to the isolation of nebularine, phenylacetic acid, purine, uridine, adenine, uracil, benzoic acid, and mannitol. Nebularine showed mild antifungal activity against Magnaphorthe grisea and Trichophyton mentagrophytes, and phenylacetic acid potently inhibited the growth of Pythium ultium and displayed moderate antifungal activity against Magnaphorthe grisea, Botrytis cinerea, and Trichophyton mentagrophytes. The other isolated compounds showed no antimicrobial activity.

국내 토양 휴믹물질의 특성 규명 및 DB 구축에 대한 연구 (Characterization of Humic and Fulvic Acids Extracted at the Soils of Korea and Its DB Establishment)

  • 이창훈;유지호;신현상;정근호;이창우
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2003년도 총회 및 춘계학술발표회
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    • pp.397-400
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    • 2003
  • In this study, humic and fulvic acids in soils at the vicinity of domestic atomic power plants(NPPs), located in Yungkwang(YK), Uljin(UJ), Kori(KR), Koseong(KS), Wolseong(WS) area, and in volcanic ash soils of the Cheju island(Mt. Hanla(HL), Manjanggul(MJ)) were isolated, and characterized using chemical(elemental analysis, proton exchange capacity, molecular size distribution) and spectroscopic(UV/Vis., IR, FL, $^{13}$ C NMR spectra) methods. The results were compared with one another and compiled for their DB establishments. The humic substances distribution (humic acid, fulvic acid, Humin) in the soils were also determined by IHSS standard method. Main purpose of this study was to provide a basic data needed to evaluate the effect of humic substances on the migrational behaviour of radioactive elements in contaminated surface soil.

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Manufacture and Properties of Inorganic Chemical Treated Wood by Introducing of Fluorides

  • Kim, Soung-Joon;Lee, Jong-Shin
    • Journal of the Korean Wood Science and Technology
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    • 제36권2호
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    • pp.73-78
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    • 2008
  • Inorganic chemical treated wood was prepared by impregnation of calcium or magnesium chloride ($CaCl_2$ or $MgCl_2$) solution and immersion in saturated solution of ammonium fluoride ($NH_4F$) as a reactant in order to make an introduction of a refractory fluorides with fungicidal and insecticidal effects in wood. The weight percent gains (WPGs) were increased with increase in concentration of calcium chloride or magnesium chloride solution, and were higher in treatment with calcium chloride than with magnesium chloride. Inorganic substances were produced mainly in the lumina of tracheides. These substances were proved to be the calcium fluoride or magnesium fluoride by the energy dispersive X-ray analyzer in conjunction with a scanning electron microscope (SEM-EDX). The treated wood showed good decay resistance because the weight losses were hardly occurred by the test fungi such as Tyromyces palustris and Trametes versicolor. The fire resistance effect was superior to the treated wood compared with that of the untreated wood.