• Title/Summary/Keyword: Chemical Reduction

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Fly Ash Application Effects on CH4 and CO2 Emission in an Incubation Experiment with a Paddy Soil (항온 배양 논토양 조건에서 비산재 처리에 따른 CH4와 CO2 방출 특성)

  • Lim, Sang-Sun;Choi, Woo-Jung;Kim, Han-Yong;Jung, Jae-Woon;Yoon, Kwang-Sik
    • Korean Journal of Soil Science and Fertilizer
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    • v.45 no.5
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    • pp.853-860
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    • 2012
  • To estimate potential use of fly ash in reducing $CH_4$ and $CO_2$ emission from soil, $CH_4$ and $CO_2$ fluxes from a paddy soil mixed with fly ash at different rate (w/w; 0, 5, and 10%) in the presence and absence of fertilizer N ($(NH_4)_2SO_4$) addition were investigated in a laboratory incubation for 60 days under changing water regime from wetting to drying via transition. The mean $CH_4$ flux during the entire incubation period ranged from 0.59 to $1.68mg\;CH_4\;m^{-2}day^{-1}$ with a lower rate in the soil treated with N fertilizer due to suppression of $CH_4$ production by $SO_4^{2-}$ that acts as an electron acceptor, leading to decreases in electron availability for methanogen. Fly ash application reduced $CH_4$ flux by 37.5 and 33.0% in soils without and with N addition, respectively, probably due to retardation of $CH_4$ diffusion through soil pores by addition of fine-textured fly ash. In addition, as fly ash has a potential for $CO_2$ removal via carbonation (formation of carbonate precipitates) that decreases $CO_2$ availability that is a substrate for $CO_2$ reduction reaction (one of $CH_4$ generation pathways) is likely to be another mechanisms of $CH_4$ flux reduction by fly ash. Meanwhile, the mean $CO_2$ flux during the entire incubation period was between 0.64 and $0.90g\;CO_2\;m^{-2}day^{-1}$, and that of N treated soil was lower than that without N addition. Because N addition is likely to increase soil respiration, it is not straightforward to explain the results. However, it may be possible that our experiment did not account for the substantial amount of $CO_2$ produced by heterotrophs that were activated by N addition in earlier period than the measurement was initiated. Fly ash application also lowered $CO_2$ flux by up to 20% in the soil mixed with fly ash at 10% through $CO_2$ removal by the carbonation. At the whole picture, fly ash application at 10% decreased global warming potential of emitted $CH_4$ and $CO_2$ by about 20%. Therefore, our results suggest that fly ash application can be a soil management practice to reduce green house gas emission from paddy soils. Further studies under field conditions with rice cultivation are necessary to verify our findings.

Influence of Nutritional Supplementation to the Substrate on Vegetative and Reproductive Growth of Winter Mushroom, Flammulina velutipes (Curt. ex Fr.) Sing. and Chemical Changes of the substrates Produced during Growth of the Fungus (톱밥 배지(培地)에 대(對)한 영양첨가(營養添加)가 팽이버섯의 생장(生長)및 배지(培地)의 화학적(化學的) 성분(成分) 변화(變化)에 미치는 영향(影響))

  • Chang, Hak-Gil
    • The Korean Journal of Mycology
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    • v.4 no.1
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    • pp.31-44
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    • 1976
  • The studies were carried out to examine the effects of supplementation of nutritional substances and physical conditions in substrate on the mycelial growth and yield of fresh sporophores of winter mushroom, Flammulina velutipes(Curt. ex Fr.) Sing. and to obtain further informations on the nutritional requirements of the fungus with reference to improvement of substrate through [analysis of chemical composition of the substrates during the cultivation period. The results obtained are summarized as follows: 1. The best yield of fresh sporophores, 84.4 g per 280 g substrate in a bottle, was obtained from the mixture of poplar sawdust 10 and rice bran 3 by volume when Flammulina velutipes was cultivated on the poplar sawdust supplemented by rice bran, wheat bran, cattle manure and various combinations of these materials as nutrient sources. The substrates of poplar sawdust 10 plus rice bran 3 and 2 or wheat bran 3 with a higher yield of fresh sporophores showed a comparatively higher content of total nitrogen. total sugar, and potassium. 2. The mycelial growth of the fungus was compared on the substrates of poplar sawdust supplemented by the several nutrient sources and poplar sawdust alone. The fastest linear growth occurred on substrates of poplar sawdust alone and poplar sawdust plus cattle manure deficient in sugar and nitrogen sources, but mycelial density was more sparse on the substrates. Also, growth in a solution extracted from these substrates was very meager. 3. In the substrates which varied with bulk density and moisture content optimum bulk density and moisture content for mycelial growth was 0.2g/cc and 72% on a dry weight basis, respectively, but the highest yield of fresh sporophores was obtained at the bulk density of 0.3g/cc and moisture content of 67%. 4. By increasing the ratio of rice bran in poplar sawdust the loss of total weight and ash, content at each stage was increased, and during the cultivation period of 75 days, loss of total weight of the substrates at inoculation was 17.8 to 28.8% and ash content increased about 12%. 5. 11 to 14% of the cellulose and 3 to 4% of the lignin content per original substrate were decreased without a great difference depending of the mixing ratio of rice bran. The soluble glucose concentration in the substrates was increased during the same period. 6. In the process of vegetative and reproductive growth of the fungus upon the substrates, the total nitrogen was increased in quantity per dry weight of sample but was reduced in absolute quantity to a minute extent. There is no great changes in content of organic nitrogen including amino acid nitrogen, and hydrolysable ammonium nitrogen during the vegetative growth period, but occurrence of sporophores resulted in a decrease in the nitrogen content of these forms. On the one hand, by an increase of additive amounts of rice bran, nitrogen contents of these forms were higher and the reduction range during the reproductive growth period became wider. 7. Mycelial growth of the fungus was accelerated in various liquid media supplemented with organic nitrogen sources such as peptone and yeast extract in comparison with addition of inorganic nitrogen sources. Furthermore, mycelial growth was mere vigorous in the media with higher content of organic nitrogen sources.

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Fermentative Characteristics of Low-Sodium $Kimchi$ Prepared with Salt Replacement (대체염을 이용한 저 나트륨 김치의 발효 특성)

  • Yu, Kwang-Won;Hwang, Jong-Hyun
    • The Korean Journal of Food And Nutrition
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    • v.24 no.4
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    • pp.753-760
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    • 2011
  • This study was carried out to investigate the effects of various kinds of commercial salts, including Hanju salt, Deep sea water salt, $Salicornia$ $herbacea$ salt, Guwoon salt, Bamboo salt and salt replacement for the reduction of Na concentration in $kimchi$. The fermentative characteristics of these salts were determined during the fermentation at $10^{\circ}C$. $kimchi$ using a salt replacement and with $Salicornia$ $herbacea$ salt showed slow changes in their pH values. The use of salt replacement showed the lowest level(0.97%) of the retardation of $kimchi$ fermentation. For the preparation of $kimchi$ that used a low Na, chemical and microbial changes were investigated during the fermentation of process, examining preparations with both table salt and a salt replacement(CS-17). The salinity level of $kimchi$ prepared with table salt(control) and the salt replacement (CS-17) were 2.17~2.5% and 1.72~1.99% during fermentation, respectively. The Na contents of $kimchi$ with CS-17(562.5 mg%) showed a lower level than that with table salt(879.0 mg%). The growth of Leuconostoc sp. was highest ($1.5{\times}10^8$ cfu/g) in $kimchi$ with CS-17 at 6 day-fermentation, but the highest level($2.3{\times}10^7$ cfu/g) in $kimchi$ with table salt was at 7dayfermentation. The cells of $Lactobacillus$ sp. in the $kimchi$ prepared with CS-17 and table salt increased to $3.0{\times}10^8$ cfu/g and $6.0{\times}10^7$ cfu/g at 8day-fermentation, respectively. It was concluded that the use of CS-17 could reduce Na levels in $kimchi$ and mitigate over-maturation.

Effect of Growth and Yield of Wheat, Soil Properties on Leguminous Cover Crops-Wheat Mixtures (두과 피복작물과 밀 혼파 재배 시 밀의 생육과 수량 및 토양특성에 미치는 영향)

  • Jeon, Weon-Tai;Seong, Ki-Yeong;Oh, Gye-Jeong;Lee, Hyun-Bok;Kim, Min-Tae;Lee, Yong-Hwan;Kang, Ui-Gum;Kim, Sook-Jin;Kang, Hang-Won
    • Korean Journal of Soil Science and Fertilizer
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    • v.45 no.2
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    • pp.198-203
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    • 2012
  • Leguminous cover crops fix nitrogen from the atmosphere. The objective of this research was carried out to decrease fertilizer amount by cover crops-wheat mixtures cultivation. Field experiment was conducted at upland soil 2008 to 2009. Cover crops were used crimson clover and hairy vetch. Treatments consisted of three wheat-crimson clover (wheat 10 kg + crimson clover 1, 3, $5kg\;10a^{-1}$), wheat-hairy vetch mixture (wheat 10 kg + hairy vetch $2kg\;10a^{-1}$), and wheat - hairy vetch mixture - crimson clover (wheat 10 kg + hairy vetch 2 kg + crimson clover $3kg\;10a^{-1}$). These treatments were divided into no fertilizer and top dressing. The yield of wheat and crimson clover mixtures had no significantly differences compared to wheat only at top dressing plots. Also soil chemical and physical properties were a little bit improved such as OM, $NO_3$-N, and bulk density etc by wheat-crimson clover mixtures. Therefore, we suggested that crimson clover and wheat mixture could be used to reduction of fertilizers amount for environmental friendly wheat production.

Effect of Incorporation Times of Green Barley and Hairy Vetch on Rice Yield in Paddy Soil with Liquid Pig Manure (돈분액비를 시용한 녹비보리 및 헤어리베치의 혼입시기가 벼 수량에 미치는 영향)

  • Kang, Se-Won;Seo, Dong-Cheol;Lee, Sang-Gyu;Seo, Young-Jin;Park, Ju-Wang;Ryu, Jin-Hee;Kim, Min-Tae;Kang, Hang-Won;Heo, Jong-Soo;Cho, Ju-Sik
    • Korean Journal of Environmental Agriculture
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    • v.32 no.4
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    • pp.287-293
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    • 2013
  • BACKGROUND: Soil incorporation of green manure crop(GMC) and liquid pig manure(LPM) is one of the methods for reduction of chemical fertilizer and the increase of crop yield. The objective of this study was to select optimal incorporation time of GMCs on growth and nutrient property in paddy soil treated LPM. METHODS AND RESULTS: The kinds of GMCs were Hordeum vulgare L.(green barley, GB) and Vicia villosa roth(hairy vetch, HV). The effects of GMCs on rice yield were investigated under different incorporation times of GMCs(LPM1: at 25 days before rice transplantation, LPM2: at 18 days before rice transplantation, LPM3: at 11 days before rice transplantation). In GB treatments, the biomass was greater in the order of $$LPM3{\geq_-}LPM2{\geq_-}LPM1$$. Contents of N, P and K ranged 1.21~1.28, 0.36~0.38 and 1.41~1.45%, respectively, regardless of incorporation times. The amounts of nutrient supply in GB treatments were higher in LPM1 than those in other treatment conditions. In GB treatments, rice yields in LPM1, LPM2 and LPM3 were 523, 525 and 526(increasing yield 3% than control) kg/10a, respectively. In HV treatments, the amounts of nutrient supply were higher in the order of $$LPM3{\geq_-}LPM2{\geq_-}LPM1$$. Rice yields were 530 kg/10a for LPM1, 531 kg/10a for LPM2, 535 (increasing yield 5% than control) kg/10a for LPM3 in HV treatments, respectively. CONCLUSION(s): The optimum incorporation time of green barley and hairy vetch was at 11 days before rice transplantation(LPM3) in paddy soil with liquid pig manure.

A Review Study on Major Factors Influencing Chlorine Disappearances in Water Storage Tanks (저수조 내 잔류염소 감소에 미치는 주요 영향 인자에 관한 문헌연구)

  • Noh, Yoorae;Kim, Sang-Hyo;Choi, Sung-Uk;Park, Joonhong
    • Journal of Korean Society of Disaster and Security
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    • v.9 no.2
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    • pp.63-75
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    • 2016
  • For safe water supply, residual chlorine has to be maintained in tap-water above a certain level from drinking water treatment plants to the final tap-water end-point. However, according to the current literature, approximately 30-60% of residual chlorine is being lost during the whole water supply pathways. The losses of residual chlorine may have been attributed to the current tendency for water supply managers to reduce chlorine dosage in drinking water treatment plants, aqueous phase decomposition of residual chlorine in supply pipes, accelerated chlorine decomposition at a high temperature during summer, leakage or losses of residual chlorine from old water supply pipes, and disappearances of residual chlorine in water storage tanks. Because of these, it is difficult to rule out the possibility that residual chlorine concentrations become lower than a regulatory level. In addition, it is concerned that the regulatory satisfaction of residual chlorine in water storage tanks can not always be guaranteed by using the current design method in which only storage capacity and/or hydraulic retention time are simply used as design factors, without considering other physico-chemical processes involved in chlorine disappearances in water storage tank. To circumvent the limitations of the current design method, mathematical models for aqueous chlorine decomposition, sorption of chlorine into wall surface, and mass-transfer into air-phase via evaporation were selected from literature, and residual chlorine reduction behavior in water storage tanks was numerically simulated. The model simulation revealed that the major factors influencing residual chlorine disappearances in water storage tanks are the water quality (organic pollutant concentration) of tap-water entering into a storage tank, the hydraulic dispersion developed by inflow of tap-water into a water storage tank, and sorption capacity onto the wall of a water storage tank. The findings from his work provide useful information in developing novel design and technology for minimizing residual chlorine disappearances in water storage tanks.

Hydrochemistry and Nitrogen and Sulfur Isotopes of Emergency-use Groundwater in Daeieon City (대전지역 민방위 비상급수용 지하수에 대한 수리화학과 질소 및 황 동위원소 연구)

  • 정찬호
    • The Journal of Engineering Geology
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    • v.13 no.2
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    • pp.239-256
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    • 2003
  • The purpose of this study is to investigate the hydrochemical characteristics of emergency-use groundwater in the Daejeon area, and to elucidate the contamination source of $NO_3-N$ and the origin of sulfate in the groundwater. The groundwater shows weak acidic pH, the electrical conductivity ranging from 142 to $903{\;}\mu\textrm{S}/cm$, and the hydrochemical types of $Ca-HCo_3$ and $Ca-Cl(SO_4,{\;}NO_3)$. The Box-Whisker analysis and the Krigging analysis of chemical data of groundwater were made to demonstrate the concentration distribution of hydrochemical composition, and to compare the trend of hydrochemical data. The groundwater in the area of Dong-gu, Jung-gu and Daeduk-gu, where are old town, shows higher electrical conductivity, nitrate content, sulfate and $EpCO_2$ levels than groundwater in new town area of Seo-gu and Yusung-gu. ${\delta}^{15}N$ of groundwater in the area of Seo-gu and Yusung-gu ranges from +7.4 to $+9.6{\textperthousand}$, indicating that major contamination source of $NO_3-N$ is the leakage from municipal sewage pipe lines. ${\delta}^{15}N$ of groundwater in the old town area of Tong-gu, Jung-gu and Daeduk-gu shows the range between +10.2 and $+23.5{\textperthousand}$, meaning that major contamination source is leakage of septic tank. ${\delta}^{34}S$ of groundwater shows the range of $+3~13.4{\;}{\textperthousand}$. Sulfur isotope indicates the possibility of a sulfate reduction and the input of anthrophogenic source.

EFFECT OF 10% CARBAMIDE PEROXIDE ON DENTIN (상아질에 대한 10% Carbamide peroxide가 미치는 영향)

  • Seo, Sang-Woo;Kown, Yong-Hoon;Kim, Hyun-Jung;Nam, Soon-Hyeun;Kim, Kyo-Han;Kim, Young-Jin
    • Journal of the korean academy of Pediatric Dentistry
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    • v.30 no.3
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    • pp.423-430
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    • 2003
  • The teeth bleaching with bleaching agent is widely used at recent times. Until yet the exact mechanism of the bleaching agent isn't known but it is thought that is by the complex reduction-oxidation reaction of the decomposed free radical from bleaching agent through various ways. In other words, it is supposed that the teeth are whitened by agent's changing chemical structures of stain-causing materials. The purpose of this study is to exam the change of the dentinal character by bleaching agent and to evaluate the safety of this agent. For this study, after applying 10% carbamide peroxide to enamel of human premolar for 6 hours a day for 2 weeks we examined changes of surface morphology, microhardness, composition and contents of minirals in human dentin using SEM, microhardness tester, FT-Raman spectrometer and EPMA and got following results. There was no significant difference in surface morphologic change when we examined the effect of 10% carbamide peroxide which penetrated into dentin after applied on enamel surface comparing with result from specimen in distilled water No change was shown on the surface of peritubular and intertubular dentin within the nanometeric range. The microhardness between bleached teeth and teeth stored in distilled water showed no statistically significant difference FT-Raman spectra of dentin exhibited no change of the component in human dentin. Only the least change in peaks of organic and inorganic materials were detected in Raman intencity. The total content of mineral elements in dentin with no treatment, stored only in distilled water and stored in distilled water after bleaching were $98.73{\pm}1.89,\;98.56{\pm}2.11\;and\;97.47{\pm}2.51$ respectively. Also they showed no statistically significant difference. From above results, the effect of 10% carbamide peroxide bleaching on structure of dentin is very low and the results may confirm the safety of this bleaching agent.

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Effect of Complex Extracts of Mushroom and Sharp Toothed Eel on the Skin Conditions with Atopic Dermatitis and Acne Symptoms (갯장어 및 버섯 혼합추출물의 아토피 및 여드름 피부개선 효과)

  • Cha, Wol-Suk;Yoo, Ji-Hyun;Min, Myung-Ja;Nam, Hyung-Gun;Kim, Yun-Soo;Shin, Hyun-Jae;Kim, Jong-Soo;Choi, On-You;Kim, Ran;Choi, Du-Bok
    • KSBB Journal
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    • v.25 no.4
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    • pp.387-394
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    • 2010
  • This study was conducted to investigate effect of complex extract of various mushrooms and sharp toothed eel on the skin conditions with atopic dermatitis and acne symptoms. The total phenol concentration was increased in order of hot water> ethanol> ethyl acetate> petroleum ether> chloroform extract. Especially, when the hot water extract was used, it was about 2-3 fold higher than that of ethyl acetate, petroleumether, and chloroform extract. When the complex extract concentration was increased from 1.0 to 50 mg/L, the DPPH scavenging rate increased from 10.1 to 81.4%. The reduction power was sharply increased from 0.05 to 0.27 (700 nm) when the complex extract concentration was increased from 25 to 75 mg/L. However, above 100 mg/L, it was not decreased. In the case of SOD-like activity, it was 45.7% at 100 mg/L. Total numbers of patients with atopic dermatitis were 15 and 5 patients with severe acne symptoms. According to photos taken before and after the treatment and questionnaire results, considerable improvements in skin conditions are observed in the patients with atopic dermatitis and acne. For atopic patients, erythema and edema have been improved but the degree of effect was dependent on the individual's constitution. Concerning acne, the effect of coating of the extracts was prominent for first week and the degree decreased with time till 4 weeks. The complex extracts wereefficient in soothing rash and maturation. Side effects such as a scar were not detected during the application and treatment.

Quality characteristics of rice noodles treated with cold plasma (저온 플라즈마 처리한 쌀국수의 품질 특성)

  • Kim, Hyun-Joo;Lee, Byong Won;Baek, Ki Ho;Jo, Cheorun;Kim, Jae-Kyung;Lee, Jin Young;Lee, Yu-Young;Kim, Min Young;Kim, Mi Hyang;Lee, Byoungkyu
    • Korean Journal of Food Science and Technology
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    • v.52 no.5
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    • pp.560-563
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    • 2020
  • Cold plasma has been applied to improve quality of food product; however, studies on its effects on microbial and physicochemical qualities of rice noodles are rarely conducted. In this study, changes in the quality characteristics of rice noodles treated by cold plasma were determined. Cold plasma was generated in a square-shaped plastic container (250 W, 15 kHz, ambient air), and dielectric barrier discharge plasma treatments were applied to rice noodle samples for 0, 10, or 20 min. Rice noodles inoculated with either Bacillus cereus or Escherichia coli O157:H7 were subjected to plasma treatment for 20 min, and the approximate bacterial count reduction were 4.10 and 2.75 log CFU/g, respectively. The Hunter color values of the sample were increased after cold plasma treatment. Peroxide values and thiobarbituric acid reactive substance (TBARS) were increased with an increase in cold plasma treatment time. Futhermore, lipid oxidation was enhanced. Although further studies are warranted to evaluate changes in chemical qualities, such as lipid oxidation of rice noodles, induced by cold plasma, the results suggest that cold plasma can improve the microbial and physical qualities of rice noodles.