• 제목/요약/키워드: Chemical Recycling

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The Synthesis of Diamond/WC-Co Thin Film by HE-CVD (HE-CVD법에 의한 Diamond/WC-Co 박막합성)

  • Lee, Kee-Sun;Seo, Sung-Man;Shin, Dong-Uk;Kim, Dong-Sun
    • Proceedings of the Korean Institute of Resources Recycling Conference
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    • 2003.10a
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    • pp.185-189
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    • 2003
  • The effect of surface roughness of the substrate on HF-CVD diamond coating was researched. The surface roughness was changed variously by electro-chemical etching conditions. The etching process acted to remove the metallic cobalt from the WC-Co. Diamond nucleation density was higher in etched the substrate. Therefore, the etching process was effective in both Co-removal and higher surface roughness, leading to the improving the diamond nucleation and deposition.

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Adsorption of Ammonia on Municipal Solid Waste Incinerator Bottom Ash Under the Landfill Circumstance

  • Yao, Jun;Kong, Qingna;Zhu, Huayue;Zhang, Zhen;Long, Yuyang;Shen, Dongsheng
    • Korean Chemical Engineering Research
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    • v.53 no.4
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    • pp.503-508
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    • 2015
  • The adsorption characteristics of ammonia on MSWI bottom ash were investigated. The effect of the variation of the landfill environmental parameters including pH, anions and organic matter on the adsorption process was discussed. Results showed that the adsorption could be well described by pseudo-second-order kinetics and Langmuir model, with a maximum adsorption capacity of 156.2 mg/g. The optimum adsorption of ammonia was observed when the pH was 6.0. High level of ion and organic matter could restrict the adsorption to a low level. The above results suggested that MSWI bottom ash could affect the migration of ammonia in the landfill, which is related to the variation of the landfill circumstance.

Developing Advanced Total Recycling Method of FRP Boats (FRP선박의 일괄 재처리 방법의 개선)

  • Lee, Seung Hee;Yoon, Koo Young
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.16 no.1
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    • pp.53-59
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    • 2013
  • Since 1990s, the major recycling methods for mechanical recycling of FRP(Fiber Reinforced Plastics)boats has involved shredding and grinding of the scrap FRP in a new recycled product. But still it leads to secondary problem such as air pollution, unacceptable shredding noise level and few limited applications. This study is to propose a newly advanced method which is more efficient and environment friendly waste FRP regenerating system. As extracting FRP layer and making the recycled fiber for recycled-fiber reinforced concrete(RFRC) from waste FRP, the recycling process has some merits in a sense of the recycling energy and the environmental effects. In this study, for those tasks, spectro-chemical differentiation method and coloring water-soluble dye treatment makes the roving layer more distinguishable photophysically. Also that has remarkably reduced safety hazards and energy. Using the mechanical properties of polymers and composite, FRP with the orthotropic and laminated plastic structure has been easily separated in the new extracting system. Also the new method has introduced five kind of separating manuals for the some different compositions of FRP boats. The roving fiber of laminated glass-fiber layer is as good as the polyvinyl fiber which is cost-high commercial fiber to increasing strength of concrete products. The early study has shown the effectiveness of laminated glass-fiber layer which also is chemical-resistant due to the resin coating. These results imply that more efficient and environment friendly recycled glass fiber can be better applied to the fiber reinforced concrete(FRC) substitute and this study also has shown wide concrete applications with RFRC from the waste FRP boat.

Practical Use of Activated Recycling Water Sludge for Admixture of Concrete (활성도를 부여한 회수수 슬러지의 콘크리트 혼화재 활용)

  • Kim, Ho-Su;Baek, Chul-Woo;Park, Cho-Bum;Jeun, Jun-Young;Ryu, Deug-Hyun
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.777-780
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    • 2008
  • There were some attempt to reuse water with sludge combinative water for ready mixed concrete. But recycling water consist of cement, aggregate and chemical admixture. So it caused deterioration of concrete. The object of this study was to search for recycling method of the recycling water sludge as mineral admixture. This experiment dealed with the effect of $2.5{\sim}12.5$% range of the recycling sludge which can be used for admixture binder(BFS, FA, BFS+FA) on properties of activated recycling water sludge for admixture of concrete. As a result, Although the slump levels reduced and air contents increased as sludge replacement levels increased, it didn't change highly. The compression strength of concrete slightly increased with an increasing amount of recycling water sludge replacement.

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Applications and prospect of CDM project through recycling of inorganic waste (무기질(無機質) 폐기물(廢棄物)의 재활용(再活用)을 통한 CDM 사업(事業) 적용사례(適用事例) 및 전망(展望) - 시멘트 산업(産業)을 중심(中心)으로 -)

  • Cho, Jin-Sang;Cho, Kye-Hong;Ahn, Ji-Whan;Um, Seong-Il;Yeon, Kyu-Seok
    • Resources Recycling
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    • v.20 no.2
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    • pp.3-15
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    • 2011
  • Current, Registration fields of CDM projects are being conducted in a variety of parts such as mostly energy, chemical processing and manufacturing processes. However, there are not many CDM project registrations by recycling of inorganic waste. In this paper, analysis abroad CDM project and applications in order to review possibility of CDM project registration through the recycling of domestic inorganic waste were investigated. As a results, registered case of CDM project by inorganic waste recycling was researched to registrate in raw material alternative field of cement industry that inorganic waste can be used in large quantities. Application prospects of CDM project in Korea will be possible to analysis industrial scale, industry using inorganic raw materials, green house gas emissions and inorganic waste generated in large quantities.

일본 폐플라스틱 재활용 현황

  • 한국발포스티렌재활용협회
    • 환경사랑
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    • s.5
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    • pp.2-3
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    • 1996
  • 세계적으로 재활용 활동이 잘 이뤄지는 나라를 들라면 일본을 빼놓을 수 없다. 일본은 스티로폴을 포함한 플라스틱에 대한 사용 규제 제도는 시행하지 않고 있다. 그러나 자원 재순환정책의 일환으로 물질 재활용(Material Recycle), 에너지 재활용(Thermo Recycle), 화학적 재활용(Chemical Recycle) 등 다양한 재활용 방법을 적극 장려하고 있다.

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Physical Properties of Polymer Mortar Recycling Waste Concrete Powder as a Filler (폐콘크리트 미분말을 충전재로 재활용한 폴리머 모르타르의 물성)

  • Hwang, Eui-Hwan;Choi, Jae-Jin;Hwang, Taek-Sung
    • Applied Chemistry for Engineering
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    • v.16 no.3
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    • pp.317-322
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    • 2005
  • Nowadays, recycling of aggregates from the waste concrete is in big demand due to the protection of environment and the shortage of aggregates that are needed for ever expanding construction projects. This study was undertaken to examine the feasibility of recycling waste concrete powder produced in the crushing process of demolished concrete as a filler material for polymer mortar. In this study, polymer mortar specimens were prepared by varying the mix proportion of polymer binder (ranging 9~15 wt%), waste concrete powder (ranging 0~20 wt%) substituted for silica powder, 0.1~0.3 mm fine aggregate (ranging 21~24 wt%) and 0.7~1.2 mm fine aggregate (ranging 44~47 wt%). For the prepared polymer mortar specimens, various physical properties such as strength, water absorption, heat water resistance, acid resistance, pore distribution and SEM observation were investigated in this work. As a result, physical properties of polymer mortar were observed to have remarkably improved with an increase of polymer binder, but greatly deteriorated with an increase of substitution quantity of waste concrete powder.

The Composition and Physico-chemcal Characteristics of school waste in B area, Kyunggi-do (경기도 B 지역 학교폐기물의 성상 및 물리∙화학적 특성)

  • Lee, Keon Joo
    • Journal of the Korea Organic Resources Recycling Association
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    • v.16 no.1
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    • pp.70-78
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    • 2008
  • In this study, the composition and physico-chemical characteristics of school waste which is located in B area, kyunggi-do was investigated. It is necessary to measure the characteristics of school waste to build the data-base for resource and recycling of waste. This school waste was composed of 12.25% of food wastes, 56.26% of papers, 9.26% of plastics&vinyls, 1.52% of textiles, 3.70% of wood, 0.11% of rubbers&leathers and others, respectively. Most of school wastes are mainly composed of paper and plastic waste and composition of combustible waste was about as 90%. From 3-components analysis, contents of moisture, combustible component, and ash was 5.72%, 88.29% and 5.98%, respectively. Moisture content was higher in Agricultural Dwelling school area compare to the urban dwelling school area. The chemical element of the school waste has the high order of carbon, oxygen, hydrogen on the dry basis of wastes and the low heating value of the MSW which is measured by calorimeter is shown as 3720.44kcal/kg.

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Chemical properties of liquid swine manure for fermentation step in public livestock recycling center

  • Lee, Dong Sung;Lee, Jae-Bong;Lee, Myoung-Yun;Joo, Ri-Na;Lee, Kyo-Suk;Min, Se-Won;Hong, Byeong-deok;Chung, Doug-Young
    • Korean Journal of Agricultural Science
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    • v.43 no.3
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    • pp.424-431
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    • 2016
  • The nutrients in livestock manure produced during fermentation processes in public livestock recycling centers are used as fertilizers. However, the large amounts of swine manure produced in intensive livestock farms can be a nonpoint source of pollution. In this experiment, we investigated the chemical properties, inorganic components, and heavy metal contents in 101 samples of liquid swine manure collected from 28 public livestock recycling centers throughout the nation. Results showed that the average pH of the samples was alkaline (pH range 5.18 to 9.54), and their maximum EC was $53.2dS\;m^{-1}$. The amounts of total nitrogen and total phosphorus were in the range of 1000 - 2000 and $200-800mg\;L^{-1}$ while potassium, which constituted 47% of the total inorganic ions recovered from the liquid swine manure, amounted to $1500mg\;L^{-1}$. The most distinctive heavy metals recovered from the liquid swine manure were copper and zinc although the amounts of both heavy metals were much lesser than those of the standards as livestock liquid fertilizer set by the Rural Development Administration. On the other hand, the amount of nitrogen decreased rapidly with an increasing fermentation period from immature to mature, assumed to be lost as volatile compounds, such as ammonia, which are the major odor components during the fermentation process.

A Study of Organic Impurity Removal Efficiency for Waste LCD Touch Panel Glass by Solvents Types (폐 LCD 유리 재활용을 위한 용매 별 유기물 제거 효율에 대한 연구)

  • Kang, Yubin;Choi, Jin-Ju;Park, Jae Layng;Lee, Chan Gi
    • Resources Recycling
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    • v.29 no.6
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    • pp.57-64
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    • 2020
  • In this study, removal of OCA and organic impurities for recycling LCD touch panel glass was conducted by mechanical and chemical dissolution methode. Cut mill and oscillation mill were used for mechanical crushing of touch panel, and water, ethanol, dichloromethane were used to remove OCA and organic impurities. As a result of TGA, when applied only dicloromethane in the process, the efficiency of organic removal was to be best. In addition, removal effect of organic impurities increased as the cleaning temperature increased. As a result of zeta potential analysis to confirm the dispersion degree of touch panel glass in the solvent, the absolute value of the zeta potenial of water with the lowest cleaning effect was lower than other solvents, and it was confirmed that efficiency of organic removal is affected not only by the chemical dissolution properties but also the physical dispersion properties in the solvent.