• 제목/요약/키워드: Chemical Reactor

검색결과 1,549건 처리시간 0.042초

Treatment of ballast water by complex process of advance filtration system

  • Park, Sang-Ho;Kim, In-Soo
    • 한국항해항만학회:학술대회논문집
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    • 한국항해항만학회 2006년도 International Symposium on GPS/GNSS Vol.1
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    • pp.387-392
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    • 2006
  • There have been several problems in treating shipboard sewage due to special environmental conditions of ship, such as limited space, rolling and pitching, change of temperature and so on. It was suggested that Sequence Batch Reactor (SBR) might be suitable process for overcome these problems in terms of small size, high capacity of treating wastewater and full automation. In this study a SBR process was employed for biological treatment of organic wastes in the shipboard sewage. This process was able to remove nitrogen and phosphorus as well as organic matter efficiently. More than 95% of chemical oxygen demand(COD) were removed. In addition, about 97% of total nitrogen (T-N) was reduced. The total phosphorus(T-P) reduction averaged 93%. A disturbance operation caused by the treatment of Methylene Blue Active Substances(MBAS) was not observed.

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산화속도 및 회수율 향상을 위한 고효율 장치 핵심 메커니즘 설계 (Design on Main Mechanism of High Throughput Device for Enhancement of Oxidation and Recover Rate)

  • 김영환;박병석;정재후;윤지섭;황정식
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 2008년도 춘계학술대회 논문집
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    • pp.473-476
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    • 2008
  • In this paper, we designed the main mechanism of high throughput device for rod-cuts of spent fuel. For this, we analyzed the mechanical methods(slitting, ball mill, roller straightening) and chemical methods(muffle furnace, rotary kiln). As the results, methods of ball drop and rotary drum for concepts design were selected in the analysis step. For enhancement of oxidation rate, we devised the blades on the reactor with mesh type. Also, for enhancement of decladding rate, we designed ball size and rotation reactor with mesh type and devised the vacuum system for fission products. Mechanisms of oxidation and recovery can simultaneously handle the rod-cuts of spent fuel and independently recover. The results of mechanism design can be used for scale-up of high throughput device.

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광촉매가 코팅된 플라스틱 광섬유를 이용한 VOC 광분해반응 (Photodegradation of VOCs by Using TiO$_2$-Coated POF)

  • Ha, Jin-Wook;Joo, Hyun-Ku
    • 한국산학기술학회:학술대회논문집
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    • 한국산학기술학회 2003년도 춘계학술발표논문집
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    • pp.350-352
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    • 2003
  • In this study plastic optical fibers(POFs) were considered as light-transmitting media and substrates for the potential use in photocatalytic environmental purification system. After the characteristics of POFs in terms of light transmittance and absorption were determined at the beginning, the detailed investigation was further performed through the photocatalytic degradation of trichloroethylene(TCE), iso-propanol and etc. with TiO$_2$-coated optical fiber reactor systems(POFR). It is concluded that the use of POfs is preferred to quartz optical fibers(QOFs) since the advantages such as ease of handling, lower cost, relatively reasonable light attenuation at the wavelength of near 400nm can be obtained. Various geometrical reactor shapes have been constructed and applied for the last one and half years. For the use of POF in water phase treatment, however, more detailed scientific and engineering aspects should be envisaged. This case requires a suitable mixture to obtain more stable and innocuous immobilization of photocatalyst on POF.

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Design of a Voting Mechanism considering Safety for Reliable System Using EPLD and Reliability Analysis

  • Ryoo, Dong-Wan;Lee, Hyung-Jik;Lee, Jeun-Woo
    • 제어로봇시스템학회:학술대회논문집
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    • 제어로봇시스템학회 2001년도 ICCAS
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    • pp.40.2-40
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    • 2001
  • The protection system of the system communication, nuclear reactor and chemical reactor are representative of reliable system. This reliable system must be designed based on reliability as well as concept of safety, which is a failed system go a way of safe. Reliable system is composed of part of data acquisition, calculator, communication with redundancy, and a voter is important factor of reliability. Because it is serially connected. This paper presents a Design and Analysis of a Voting Mechanism considering Safety for reliable system Using EPLD. In the case of digital implementation a coincidence logic (voter) of reliable system, it needs CPU and memory, so increase a number of units. Therefore the failure rate and cost are increased on contrary when it is designed EPLD or FPGA.

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Burnable poison optimized on a long-life, annular HTGR core

  • Sambuu, Odmaa;Terbish, Jamiyansuren
    • Nuclear Engineering and Technology
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    • 제54권8호
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    • pp.3106-3116
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    • 2022
  • The present work presents analysis results of the core design optimizations for an annular, prismatic High Temperature Gas-cooled Reactor (HTGR) with passive decay-heat removal features. Its thermal power is 100 MWt and the operating temperature is 850 ℃ (1123 K). The neutronic calculations are done for the core with heterogeneous distribution of fuel and burnable poison particles (BPPs) to flatten the reactivity swing and power peaking factor (PPF) during the reactor operation as well as for control rod (CR) insertion into the core to restrain a small excess reactivity less than 1$. The next step of the study is done for evaluation of core reactivity coefficient of temperature.

Development Status of Iridium Catalyst for Hydrazine Decomposition

  • Kim, S.K.;Lee, K.H.;Yu, M.J.;Cho, S.J.;Lee, J.W.
    • 한국추진공학회:학술대회논문집
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    • 한국추진공학회 2008년 영문 학술대회
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    • pp.272-274
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    • 2008
  • A development of hydrazine decomposition catalyst for monopropellant thruster has been performed by Korea Aerospace Research Institute(KARI). The goal of this development is to product a catalyst showing the equivalent performance with space-proven catalysts. Catalyst production and physical/chemical analysis were conducted by Chonnam National University and the analysis result was compared with the result of other catalysts and our own specification. Using the developed prototype catalyst, short firing test was performed in a reactor to verify basic performance of catalyst. After the successful reactor test, hot firing tests were carried out in atmospheric and vacuum condition using 5N thruster to verify durability and safety of catalyst. In this paper, the catalyst development status will be presented.

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물-페놀 혼합 용매의 근임계 하에서의 크래프트 리그닌의 저분자화 (Depolymerization of Kraft Lignin at Water-Phenol Mixture Solvent in Near Critical Region)

  • 엄희준;홍윤기;정상호;박영무;이관영
    • 에너지공학
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    • 제20권1호
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    • pp.36-43
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    • 2011
  • 식물계 바이오매스는 석유로부터 얻어지는 화학물질들을 대체할 수 있는 물질로 제안되고 있다. 특히 식물계 바이오매스의 15-30%를 이루고 있는 리그닌은 복잡한 방향족 중합체로 이루어져 있어, 리그닌의 저분자화 공정에 의해 다양한 방향족 화합물을 얻을 수 있다. 본 연구에서는 국내에서 가장 많이 배출되는 크래프트 리그닌을 출발 물질로 선정하고, $^{13}C$-Muclear Magnetic Resonance($^{13}C$-NMR), Fourier Transform Infrared Spectroscopy (FT-IR), Elemental Analysis(EA)을 통해 원료물질의 화학적 구조를 분석하였다. 크래프트 리그닌의 저분자화 는 물-페놀 혼합 용매의 근임계 영역에서 수행되었으며, tube bomb reactor를 사용하였다. 최적의 반응조건을 찾기 위해 물-페놀의 비율, 반응온도($300-400^{\circ}C$)를 변화시키며 실험을 수행하였다. 또한 기체상 수소를 대신하여 수소발생 용매인 formic acid 사용에 따른 영향을 조사하였다. 액상 생성물의 화학 종류 및 양은 GC-MS를 통해 분석하였고, 고체 잔류물(char)은 FT-IR을 통해 분석하였다. GC-MS 분석 결과 페놀이 첨가된 경우 anisole, o-cresol(2-methylphenol), p-cresol(4-methylphenol), 2-ethylphenol, 4-ethylphenol, dibenzofuran, 3-methyl cabazole, xanthene이 생성되는 것을 확인하였다.

UASB 공법에 있어서 반응조의 형상변화에 따른 입상슬러지의 특성에 관한 연구 (The Characteristics of Biopellet Produced Upon Reactor Configuration in UASB System)

  • 민경석;안영호
    • 대한토목학회논문집
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    • 제14권3호
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    • pp.679-688
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    • 1994
  • 본 연구에서는 UASB 반응조의 형상변화에 따른 입상슬러지의 물리 화학적 및 형태학적인 특성이 조사되었다. 또한 반응조내의 수소분압의 크기에 따른 반응조운전의 안정성이 조사되었다. 수소분압이 높게 유지된 수정개발된 UASB 반응조의 경우가 상대적으로 수소분압이 낮게 유지된 일반적인 UASB 반응조의 경우에 비해 입상슬러지의 침전성 및 미생물보유능이 더 우수하게 나타났다. 입상슬러지의 형성과 그 안정성에 수소분압이 큰 영향을 미치는 것으로 나타났다. 입상슬러지의 화학적 조성식은 일반적인 UASB 반응조와 수정개발된 UASB 반응조가 각각 $C_7H_{12}O_{4.6}N$$C_5H_9O_3N$으로, 일반적인 미생물의 경험식인 $C_5H_7O_2N$과는 상이하게 나타났다. 특히 수정개발된 UASB 반응조의 경우 입상슬러지내에 질소성분이 일반적인 혐기성 미생물보다 높게 나타나, 입상슬러지의 발생기작으로서 polypeptide계 체외폴리머의 존재가능성을 보여주고 있다. 전자현미경을 이용한 형태화적 특성조사결과, 일반적인 반응조의 경우와는 달리 수소분압이 높게 유지된 수정개발된 UASB 반응조의 경우 입상슬러지의 표면에서는 Methanobrevibactor arboriphilus와 같은 크기와 형태를 한 수소이용메탄균의 성장이 다발을 이루며 관찰되었는데, 이러한 현상은 입상슬러지의 형성 메커니즘을 뒷받침해주고 있다. 우수한 입상슬러지의 형성을 위해서는 상대적인 수소분압의 크기에 따른 효과적인 상분리가 이루어져, acetogens과 수소이용메탄균들간의 공생관계가 잘 유지되도록 해주어야 할 것으로 사료된다. 수정개발된 UASB 반응조가 일반적인 UASB 반응조에 비하여 수소이용메탄균의 성장에 더욱 효과적인 환경을 제공하는 것으로 판단되며, 입상슬러지의 경영성과 반응조 전체의 유기물질 제거효율 뿐만 아니라, 운전의 안정성 측면에서도 더 우수한 것으로 사료된다.

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혐기성 유동상 반응기의 수리학적 특성 (Hydraulic Characteristics of Anaerobic Fluidized Bed Bioreactor)

  • 석종혁
    • 한국산학기술학회논문지
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    • 제19권2호
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    • pp.90-96
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    • 2018
  • 기성 유동상 반응기(AFBR)의 수리학적 특성을 고찰하기 위해 "무담체 모드"와 "담체 충진 모드"의 두 가지 모드에서 추적자 실험을 수행하였다. 각 모드에서 동일한 실험조건으로 실험을 수행하여 수리학적 수치들이 유도되었고 실제 반응기의 수리학적 특성파악에 필요한 데이터를 얻어 해석하였다. 두 가지모드에서의 수리학적 해석을 위해 담체는 비 반응성이고 분산계수가 상수라는 가정으로 비 반응성 추적자의 일차원-비 정상상태 농도분포의 분산모델을 사용하였다. 실험결과 담체는 반응기 내부에서의 혼합효과를 크게 증가시켰다. 담체를 충진하지 않은 경우 충진한 경우에 비해 분산계수는 최소 1자리 수 이상 작게 나타났다. 담체가 없는 경우 실험영역(Pe⦤0.83cm/s)에서 이류흐름이 지배적 흐름이었고 반응기의 흐름형태는 마개흐름형 반응기(PFR)에 근접하였다. 이 때 분산계수는 0.83cm/s까지 겉보기유속에 비례적으로 증가하였다. 그러나 담체가 충진된 경우, 흐름형태는 마개흐름형 반응기 (PFR)과 완전혼합형 반응기(CMFR)사이에 있음을 나타내었으며 분산계수는 겉보기유속이 0.41cm/s에서 거의 최대치에 도달한 후 0.82cm/s까지 유사한 수치를 나타내었다. 본 실험조건에서 분산계수는 액체 레이놀즈수(Re) 또는 입자 레이놀즈수(Rep)에 비례하였다.

$BaTiO_3$-슬러지 Packed-bed형 반응기에서 $NO_x$제거에 미치는 슬러지의 영향 (Effect of Sludge Pellets on $NO_x$ REmoval in $BaTiO_3$-sludge Packed-bed Reactor)

  • 박재윤;송원섭;고희석;박상현
    • 한국전기전자재료학회논문지
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    • 제14권10호
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    • pp.861-867
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    • 2001
  • In this paper, in order to investigate the catalytic effect of the sludge exhausted from waterworks on NO$_{x}$ removal, we measure NO removal characteristics with and without sludge pellets in BaTiO$_3$-sludge packed-bed reactor of plate-plate geometry. NO initial concentration is 50 ppm balanced with air and a gas flow rate is 5ι/min. Gas temperature is changed from 25 to 10$0^{\circ}C$ to investigate the role of sludge pellet on removing active oxygen species and NO$_2$. BaTiO$_3$pellets is filled for coronal discharge at upstream of reactor and sludge pellets is filled for catalytic effect at downstream of reactor. The volume percent of sludge pellets to BaTiO$_3$pellets is changed from 0% to 100% and AC voltage is supplied to the reactor for discharging simulated gases. In the results, when sludge pellets is put at the downstream of plasma reactor, NO removal rate is slightly increased. However, NO$_2$and $O_3$ as by-products during NO removal is significantly decreased from 51ppm without sludge pellets to 5 ppm with sludge pellets and from 50 ppm without sludge pellets to 0.004ppm with sludge pellets, respectively. Therefore, NO$_{x}$(NO+NO$_2$) removal rate is increased up to 93%. It is thought that sludge pellet maybe react with active oxygen species and NO$_2$ generated by corona discharge in surface of BaTiO$_3$pellets, the then NO$_2$O$_3$as by-products are considerably decreased. When we increase gas temperature from room temperature to 10$0^{\circ}C$, NO removal rate is decreased, while NO$_2$ concentration is independent on gas temperature. These result suggest that the removal mechanism of active oxygen species and NO$_2$in sludge pellet is not absorption, but chemical reaction. Therefore we expect that sludge pellets exhausted for waterworks could be used as catalyst for NO$_{x}$ removal with high removal rate and low by-product.oduct.

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