• 제목/요약/키워드: Chemical Reactor

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Auger 반응기에서 제조한 다시마 유래 열분해오일의 특성 (Characteristics of Pyrolysis Oils from Saccharina japonica in an Auger Reactor)

  • 최재욱;손덕원;서동진;김화용;이윤우
    • 청정기술
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    • 제24권1호
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    • pp.70-76
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    • 2018
  • 오거 반응기를 이용하여 해조류 바이오매스인 다시마로부터 열분해 오일 제조 실험을 수행하였으며, 열분해 오일의 물리화학적 특성을 살펴보았다. 주요 공정 변수인 열분해 온도 및 오거 컨베이어 속도의 최적 조건은 각각 $412^{\circ}C$, 20 rpm이었으며, 이 때 열분해 오일의 최대 수율은 32 wt%이었다. 낮은 탄소 함량 및 높은 산소 함량으로 인해, 다시마 유래 열분해 오일의 발열량($23.6MJ\;kg^{-1}$)은 기존 화석연료의 약 60% 이었다. 열분해 오일의 GC/MS 분석 결과, 1,4-Anhydro-d-galactitol, dianhydromannitol, 1-hydroxy 2-propanone, isosorbide 등이 주요 화합물로 확인되었다. 촤는 탄소 함량이 낮고 산소함량이 높아 발열량($13.0MJ\;kg^{-1}$)이 낮으며 다량의 무기 성분 및 황을 포함하고 있는 것으로 확인되었다.

석탄, 폐타이어, 폴리프로필렌의 공동액화 특성 및 상승효과 (Characteristics and Synergistic Effects of Coal/Waste Tire/Polypropylene Coliquefaction)

  • 정태진;정대희;김성철;임명훈;나병기;송형근;윤도영;김대흠;한춘
    • 에너지공학
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    • 제9권3호
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    • pp.228-236
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    • 2000
  • 본 연구에서는 순간 고온식 tubing-bomb reactor를 사용하여 41$0^{\circ}C$에서 Alaska산 아역청탄, 폐타이어, 폴리프로필렌 혼합물의 공동액화 시 액화특성 및 상승효과를 연구하였다. 석탄, 폐타이어와, 폴리프로필렌의 조성을 변화시키고 수소공여용매인 tetralin의 양을 변화시켜가며 공동액화를 진행했을 경우 공동액화율을 살펴보면, 무촉매 반응의 경우 폴리프로필렌의 양이 많아지면 tetralin이 첨가되지 않았을 경우 액화율이 증가하였으나 tetralin이 첨가되었을 경우 공동액화율이 감소하였다. 촉매 반응의 경우에는 모든 반응조건에서 상승효과가 나타났으며 폴리프로필렌의 양이 증가할수록 공동액화율이 증가하여 석탄 : 폐타이어 : 폴리프로필렌의 조성이 1:1:3에서 tetralin 4$m\ell$, Co-naphthenate 촉매 사용하였을 때가 최적의 반응조건으로 83%의 공동액화율을 나타내었다.

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소형 공정열교환기 시제품의 고온구조해석 (High-temperature Structural Analysis on the Small Scale PHE Prototype)

  • 송기남;이형연;홍성덕;박홍윤
    • 한국압력기기공학회 논문집
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    • 제6권1호
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    • pp.57-64
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    • 2010
  • PHE(Process Heat Exchanger) is a key component required to transfer heat energy of $950^{\circ}C$ generated in a VHTR(Very High Temperature Reactor) to the chemical reaction that yields a large quantity of hydrogen. Korea Atomic Energy Research Institute established the gas loop for the performance test of components, which are used in the VHTR, and they manufactured a PHE prototype to be tested in the loop. In this study, as part of the high-temperature structural-integrity evaluation of the PHE prototype, which is scheduled to be tested in the gas loop, we carried out high-temperature structural-analysis modeling, thermal analysis, and thermal expansion analysis of the PHE prototype. The results obtained in this study will be used to design the performance test setup for the PHE prototype.

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소형가스루프 시험조건에서 소형 공정열교환기 시제품의 고온구조해석 (High-Temperature Structural Analysis on the Small-Scale PHE Prototype under the Test Condition of Small-Scale Gas Loop)

  • 송기남;홍성덕;박홍윤
    • 한국압력기기공학회 논문집
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    • 제8권1호
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    • pp.1-7
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    • 2012
  • A PHE (Process Heat Exchanger) is a key component required to transfer heat energy of $950^{\circ}C$ generated in a VHTR (Very High Temperature Reactor) to the chemical reaction that yields a large quantity of hydrogen. A small-scale PHE prototype made of Hastelloy-X is being tested in a small-scale gas loop at Korea Atomic Energy Research Institute. In order to properly evaluate the high-temperature structural integrity of the small-scale PHE prototype, it is very important to impose a proper constraint condition on its structural analysis model. For this effort, we tried to impose several constraint conditions on the structural analysis model and consequently fixed a proper and effective displacement constraints.

Feasibility of Composting Combinations of Sewage Sludge, Cattle Manure, and Sawdust in a Rotary Drum Reactor

  • Nayak, Ashish Kumar;Kalamdhad, Ajay S.
    • Environmental Engineering Research
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    • 제19권1호
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    • pp.47-57
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    • 2014
  • The aim of this paper was to study the effect of five different waste combinations (C/N 15, C/N 20, C/N 25, C/N 30, and control) of sewage sludge coupled with sawdust and cattle manure in a pilot scale rotary drum reactor, during 20 days of the composting process. Our results showed that C/N 30 possesses a higher temperature regime with higher % reduction in moisture content, total organic carbon, soluble biochemical oxygen demand and chemical oxygen demand; and higher % gain in total nitrogen and phosphorus at the end of the composting period implying the total amount of biodegradable organic material is stabilized. In addition, $CO_2$ evolution and oxygen uptake rate decreased during the process, reflecting the stable behavior of the final compost. A Solvita maturity index of 8 indicated that the compost was stable and ready for usage as a soil conditioner. The results indicated that composting can be an alternate technology for the management of sewage sludge disposal.

기상합성법을 이용한 탄소나노튜브의 대량합성 (Mass production of carbon nanotubes using Vapor Phase Growth)

  • 류승철;이태재;이철진
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 하계학술대회 논문집
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    • pp.123-126
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    • 2001
  • Multiwalled carbon nanotubes were massively produced by the catalytic reaction of C$_2$H$_2$ - Fe(CO)$\sub$5/ mixture at 750 - 950$^{\circ}C$ in a quartz tube reactor and over quartz substrates. Well-aligned MWNT array grows perpendicular to the quartz tube reactor and the quartz substrates at an average of 60 nm in diameter and up to several thousands of micrometers in length. This method does not require any pretreatment of substrates and CNTs are grown at atmospheric pressure. It could be suitable for mass production of multiwalled nanotubes. Scanning electron microscope and transmission electron microscope images of the nanotubes deposited on the substrates allowed us to monitor the quality of MWNTs grown under different operating conditions.

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$SnO_2$ 박막증착을 위한 APCVD Reactor 내 유량 균일도 향상에 대한 수치 해석적 연구 (COMPUTATIONAL ANALYSIS FOR IMPROVING UNIFORMITY OF $SNO_2$ THIN FILM DEPOSITION IN AN APCVD SYSTEM)

  • 박준우;윤익로;정하승;신승원;박승호;김형준
    • 한국전산유체공학회:학술대회논문집
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    • 한국전산유체공학회 2010년 춘계학술대회논문집
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    • pp.567-570
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    • 2010
  • With continuously increasing flat panel display size, uniformity of thin film deposition has been drawing more attentions and associated fabrication methodologies are being actively investigated. Since the convective flow field of mixture gas plays a significant role for deposition characteristics of thin film in an APCVD system, it is greatly important to maintain uniform distribution and consistent concentration of mixture gas species. In this paper, computational study has been performed for the improvement of flow uniformity of mixture gas in an APCVD reactor during thin film deposition process. A diffuser slit has bee designed to spread the locally concentrated gas flow exiting from the flow distributor. A uniform flow distributor has been developed which has less dependency on operating conditions for global flow uniformity

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신형경수로의 증기발생기 전열관 재질 Inconel-690 적용 (The Use of Inconel 690 as Tube Material For Advanced Pressurized Water Reactor Steam Generator)

  • 임혁순;정대율;변성철;이광한
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2003년도 춘계학술대회
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    • pp.49-54
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    • 2003
  • Most of the operating pressurized water reactors (PWRs)has chosen Inconel 600 as steam generator tubing. The long-term operation of steam generators showed that the use of this material induced localized corrosion damages. The current trend is using Inconel 690 as a tube material for the replacement steam generators. Based on the current trend, we have chosen Inconel 690 for the advanced Power Reactor 1400 (APR1400) steam generator tube material. In this paper, we examined the technical consideration in this modification: the effect of chemical composition, thermal conductivity, corrosion resistance and wear characteristics

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Nuclear Design Methodology of Fission Moly Target for Research Reactor

  • Cho, Dong-Keun;Kim, Myung-Hyun;Sohn, Dong-Seong
    • Nuclear Engineering and Technology
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    • 제31권4호
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    • pp.365-374
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    • 1999
  • A nuclear design of fission moly production targets for a research reactor, HANARO was peformed. It was found that the use of MCNP-4A, ORIGEN-2 code was reliable for the analysis of production characteristics of $^{99}$ Mo in a target fuel at an irradiation holes. A parametric study was done for the optimization of target location, target dimension, target shape and fuel materials. It was shown that a fuel thickness was the most sensitive parameters and electro-deposited target gave the highest 99Mo yield ratio. A pellet target with vibro-compaction powder, however, showed the largest production capacity and better engineering feasibility even with less yield ratio. Ten kinds of optimized target design for both LEU and HEU satisfied all the given design constraints. The most favorable design was the HEU ring-shaped electro-deposited target, considered the safety limit, production yield, chemical process easiness, yield ratio, and amount of radioactive waste.

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Wire-Plate 반응기에서 펄스 코로나 방전을 이용한 탈황 탈질에 관한 연구 (A Study on the Removal of SOx/NOx by a Pulsed Corona Discharge in the Wire-Plate Reactor)

  • 신완호;송영훈;김한석;최연석;김석준
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1996년도 하계학술대회 논문집 C
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    • pp.1910-1912
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    • 1996
  • This paper presents the results of laboratory experimentals to remove $SO_2$ and $NO_x$ by a pulsed corona discharge in the wire-plate reactor. A rotating spark gap switch was used to generate the pulse by chewing the dc high voltage. Repetition frequency of the pulse was 60Hz and rising time of 50ns. The photo pictures of positive streamer corona taken by ICCD camera, pulse voltage and current were measured using a digital oscilloscope. Simultaneous effects of $C_{2}H_{4}$ injection and heterogeneous chemical reactions on nonthermal plasma process to remove $SO_2$ and $NO_x$ from flue gas were investigated in the present study

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