• 제어로봇시스템학회:학술대회논문집
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• 제어로봇시스템학회 2003년도 ICCAS
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• pp.2600-2605
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• 2003

The PBL (Poly-butadiene Latex) production process is a typical batch process. Changes of the reactor characteristics due to the accumulated scaling with the increase of batch cycles require adaptive tuning of the PID controller being used. In this work we propose a tuning method for PID controllers based on the closed-loop identification and the genetic algorithm (GA) and apply it to control the PBL process. An approximated process transfer function for the PBL reactor is obtained from the closed-loop data using a suitable closed-loop identification method. Tuning is performed by GA optimization in which the objective function is given by ITAE for the setpoint change. The proposed tuning method showed good control performance in actual operations.

• 한국대기환경학회지
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• 제15권2호
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• pp.183-190
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• 1999

Magnetite was synthesized with $FeSO_4$, and NaOH for the decomposition of carbon dioxide and for the study of the methane formation. The chemical equivalent ratio was changed from 0.5 to 1.50 for the magnetite synthesis. The chemical equivalent ratio was fixed in 1.00, and Nickel chloride and Rhodium chloride equally added and synthesized with the ratio was of 0.10~10.00 mole%. The crystal strucure of the synthesized magnetite was measured XRD. Putting synthesized magnetite in the reactor and using hydrogen gas oxygen-deficient magnetite was made. Injecting carbon dioxide in the reactor, the decomposition reaction was experimented. The formation of methane was confirmed injecting hydrogen gas in the reactor after carbon dioxide was decomposed.

• 제어로봇시스템학회:학술대회논문집
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• 제어로봇시스템학회 1989년도 한국자동제어학술회의논문집; Seoul, Korea; 27-28 Oct. 1989
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• pp.813-818
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• 1989

A two compartmented autoclave reactor for the polymerization of low density polyethylene is analyzed with respect to the effects of heat transfer and operation variables. Each compartment being considered as a completely mixed cell, two CSTRs model is proposed. The system shows various multiplicity features of steady state and periodic oscillatory motions. Heat removal efficiency and initiator supplement appear to have significant effect on the conversion of monomer with the temperature properly maintained, which should be taken into account in the reactor design.

• 제어로봇시스템학회:학술대회논문집
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• 제어로봇시스템학회 1992년도 한국자동제어학술회의논문집(국제학술편); KOEX, Seoul; 19-21 Oct. 1992
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• pp.100-105
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• 1992

A mathematical model is developed for a CSTR in which free radical solution polymerization of methyl methacrylate(MMA) takes place. It turns out that five ordinary differential equations are to be treated simultaneously in order to predict the reactor performance. Although the reaction proceeds under the conditions of relatively low temperature and pressure, the system shows very complex bifurcation features due to the diffusion limitation (gel effect) and the temperature dependence of the kinetic parameters and physical properties. The effects of various system parameters on the reactor performance as well as on the polymer properties are investigated by using the bifurcation analysis. The application of the singularity theory enables us to divide the parameter space into several different regions, in each of which the system takes a unique steady state structure. Under certain circumstances, complex dynamic features such as HB points and limit cycles are observed and these should be taken into consideration in the reactor design.

• Journal of the Korean Wood Science and Technology
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• 제18권4호
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• pp.79-85
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• 1990

Many kinds of acetosolv lignin including ricestraw and spruce lignin were pyrolyzed. and liquefied in the autoclave reactor using 50% tetralin and m-cresol solution respectively as soluble solvent and Co-Mo as catalyst. In order to promote deoxyhydrogenolysis reaction $H_2$ gas was supplied into the reactor. The ratio between lignin and the soluble solvent are lg and 10cc. The reaction conditions are $200^{\circ}-700^{\circ}C$ of reaction temperature, 10-50 atms of reaction pressure and 100-500rpm of the reactor stirrer. By the deoxyhydrogenolysis liquefaction reaction, the main chemical structures of lignin which are aryl-alkyl-${\beta}$-0-4 ether, phenylcoumaran and biphenyl etc. are easily destroyed into liqufied aromatic compounds and aliphatic compunds linked with aromatic compounds. The percent yield of monomeric phenols on the weight bvase of lignin reacted reached to 12-14% by the chemical analytic GC-MS etc.

• 산업기술연구
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• 제14권
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• pp.63-75
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• 1994

The objective of this research is to analyze the phenomena of negative ion behavior in silane plasma chemical vapor deposition. Based on the plasma chemistry, the model equations for the formation and transport of negative ions were proposed and solved. The evolutions of gaseous species along the reactor were presented for several conditions of process variables such as reactor pressure, total gas flow rate, and electric field. Based on the model results, it is found that : (1) The concentration profiles of positive ions show the sharp peaks at the center of plasma reactor. (2) Most of negative ions are located in bulk plasma region, because the negative ions are excluded from the sheath region by electrostatic repulsion.

• 한국광과학회:학술대회논문집
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• 한국광과학회 2005년도 제12회 학술대회 논문초록
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• pp.124-124
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• 2005

• Biotechnology and Bioprocess Engineering:BBE
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• 제5권1호
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• pp.65-70
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• 2000

An approximated analytical solution of mathematical model for the three phase fluidized bed bioreactor (TFBBR) was proposed using the linearization technique to describe oxygen utilization rate in wastewater treatment. The validation of the model was done in comparison with the experimental results. Satisfactory agreement was obtained in the comparison of approximated analytical solution and numerical solution in the oxygen concentration profile of a TFBBR. The approximated solutions for three modes of the liquid phase flow were compared. The proposed model was able to predict the biomass concentration, dissolved oxygen concentration the height of efficient column, and the removal efficiency.

• Biotechnology and Bioprocess Engineering:BBE
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• 제8권1호
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• pp.23-31
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• 2003

A mathematical model was formulated to simulate the long-term performance of an anaerobic bioreactor designed to digest Korean food wastes. The system variables of various decomposition steps were built into the model, which predicts the temporal characters of Solid waste, and volatile fatty acid (VFA) in the reactor, and gas production in response to various input loadings and temperatures. The predicted values of VFA and gas production were found to be in good agreement with experimental observations in batch and repeated-input systems. Finally, long-term reactor performance was simulated with respect to the seasonal temperature changes from 5C in winter to 25C in Summer at different food waste input loadings. The simulation results provided us with information concerning the success or failure of a process during long-term operation .

• Korean Chemical Engineering Research
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• 제45권6호
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• pp.677-679
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• 2007

$SiCl_4$ 증기를 수증기에 의해 처음으로 2단계 가수분해시키는 방식에 의해 200~300 nm 크기의 단분산에 가까운 구형 실리카 분말을 건식으로 제조하였다. 1단계로 회분식 반응기를 사용하여 $150^{\circ}C$ 정도의 저온에서 부분 가수분해에 의해 단분산에 가까운 silicon oxychloride 구형 입자를 형성시킨 후 2단계로 관형반응기를 사용하여 $1,000^{\circ}C$에서 가수분해 반응을 완료시킴으로써 1단계 이후의 입자 형상이 거의 그대로 보존된 실리카 분말을 제조하였다.