• Title/Summary/Keyword: Chemical Reactor

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Treatment of ballast water by complex process of advance filtration system

  • Park, Sang-Ho;Kim, In-Soo
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • v.1
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    • pp.387-392
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    • 2006
  • There have been several problems in treating shipboard sewage due to special environmental conditions of ship, such as limited space, rolling and pitching, change of temperature and so on. It was suggested that Sequence Batch Reactor (SBR) might be suitable process for overcome these problems in terms of small size, high capacity of treating wastewater and full automation. In this study a SBR process was employed for biological treatment of organic wastes in the shipboard sewage. This process was able to remove nitrogen and phosphorus as well as organic matter efficiently. More than 95% of chemical oxygen demand(COD) were removed. In addition, about 97% of total nitrogen (T-N) was reduced. The total phosphorus(T-P) reduction averaged 93%. A disturbance operation caused by the treatment of Methylene Blue Active Substances(MBAS) was not observed.

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Design on Main Mechanism of High Throughput Device for Enhancement of Oxidation and Recover Rate (산화속도 및 회수율 향상을 위한 고효율 장치 핵심 메커니즘 설계)

  • Kim, Y.H.;Park, B.S.;Jung, J.H.;Yoon, J.S.;Hwang, J.S.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2008.05a
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    • pp.473-476
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    • 2008
  • In this paper, we designed the main mechanism of high throughput device for rod-cuts of spent fuel. For this, we analyzed the mechanical methods(slitting, ball mill, roller straightening) and chemical methods(muffle furnace, rotary kiln). As the results, methods of ball drop and rotary drum for concepts design were selected in the analysis step. For enhancement of oxidation rate, we devised the blades on the reactor with mesh type. Also, for enhancement of decladding rate, we designed ball size and rotation reactor with mesh type and devised the vacuum system for fission products. Mechanisms of oxidation and recovery can simultaneously handle the rod-cuts of spent fuel and independently recover. The results of mechanism design can be used for scale-up of high throughput device.

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Photodegradation of VOCs by Using TiO$_2$-Coated POF (광촉매가 코팅된 플라스틱 광섬유를 이용한 VOC 광분해반응)

  • Ha, Jin-Wook;Joo, Hyun-Ku
    • Proceedings of the KAIS Fall Conference
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    • 2003.06a
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    • pp.350-352
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    • 2003
  • In this study plastic optical fibers(POFs) were considered as light-transmitting media and substrates for the potential use in photocatalytic environmental purification system. After the characteristics of POFs in terms of light transmittance and absorption were determined at the beginning, the detailed investigation was further performed through the photocatalytic degradation of trichloroethylene(TCE), iso-propanol and etc. with TiO$_2$-coated optical fiber reactor systems(POFR). It is concluded that the use of POfs is preferred to quartz optical fibers(QOFs) since the advantages such as ease of handling, lower cost, relatively reasonable light attenuation at the wavelength of near 400nm can be obtained. Various geometrical reactor shapes have been constructed and applied for the last one and half years. For the use of POF in water phase treatment, however, more detailed scientific and engineering aspects should be envisaged. This case requires a suitable mixture to obtain more stable and innocuous immobilization of photocatalyst on POF.

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Design of a Voting Mechanism considering Safety for Reliable System Using EPLD and Reliability Analysis

  • Ryoo, Dong-Wan;Lee, Hyung-Jik;Lee, Jeun-Woo
    • 제어로봇시스템학회:학술대회논문집
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    • 2001.10a
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    • pp.40.2-40
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    • 2001
  • The protection system of the system communication, nuclear reactor and chemical reactor are representative of reliable system. This reliable system must be designed based on reliability as well as concept of safety, which is a failed system go a way of safe. Reliable system is composed of part of data acquisition, calculator, communication with redundancy, and a voter is important factor of reliability. Because it is serially connected. This paper presents a Design and Analysis of a Voting Mechanism considering Safety for reliable system Using EPLD. In the case of digital implementation a coincidence logic (voter) of reliable system, it needs CPU and memory, so increase a number of units. Therefore the failure rate and cost are increased on contrary when it is designed EPLD or FPGA.

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Burnable poison optimized on a long-life, annular HTGR core

  • Sambuu, Odmaa;Terbish, Jamiyansuren
    • Nuclear Engineering and Technology
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    • v.54 no.8
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    • pp.3106-3116
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    • 2022
  • The present work presents analysis results of the core design optimizations for an annular, prismatic High Temperature Gas-cooled Reactor (HTGR) with passive decay-heat removal features. Its thermal power is 100 MWt and the operating temperature is 850 ℃ (1123 K). The neutronic calculations are done for the core with heterogeneous distribution of fuel and burnable poison particles (BPPs) to flatten the reactivity swing and power peaking factor (PPF) during the reactor operation as well as for control rod (CR) insertion into the core to restrain a small excess reactivity less than 1$. The next step of the study is done for evaluation of core reactivity coefficient of temperature.

Development Status of Iridium Catalyst for Hydrazine Decomposition

  • Kim, S.K.;Lee, K.H.;Yu, M.J.;Cho, S.J.;Lee, J.W.
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2008.03a
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    • pp.272-274
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    • 2008
  • A development of hydrazine decomposition catalyst for monopropellant thruster has been performed by Korea Aerospace Research Institute(KARI). The goal of this development is to product a catalyst showing the equivalent performance with space-proven catalysts. Catalyst production and physical/chemical analysis were conducted by Chonnam National University and the analysis result was compared with the result of other catalysts and our own specification. Using the developed prototype catalyst, short firing test was performed in a reactor to verify basic performance of catalyst. After the successful reactor test, hot firing tests were carried out in atmospheric and vacuum condition using 5N thruster to verify durability and safety of catalyst. In this paper, the catalyst development status will be presented.

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Depolymerization of Kraft Lignin at Water-Phenol Mixture Solvent in Near Critical Region (물-페놀 혼합 용매의 근임계 하에서의 크래프트 리그닌의 저분자화)

  • Eom, Hee-Jun;Hong, Yoon-Ki;Chung, Sang-Ho;Park, Young-Moo;Lee, Kwan-Young
    • Journal of Energy Engineering
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    • v.20 no.1
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    • pp.36-43
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    • 2011
  • Plant biomass has been proposed as an alternative source of petroleum-based chemical compounds. Especially, aromatic chemical compounds can be obtained from lignin by depolymerization processes because the lignin consist of complex aromatic materials. In this study, kraft lignin, the largest emitted substance among several kinds of lignin in Korea, was used as a starting material and was characterized by solid-state $^{13}C$-Muclear Magnetic Resonance($^{13}C$-NMR), Fourier Transform Infrared Spectroscopy(FT-IR), Elemental Analysis(EA). The depolymerization of kraft lignin was studied at water-phenol mixture solvent in near critical region and the experiments were conducted using a batch type reactor. The effects of water-to-phenol ratio and reaction temperature($300-400^{\circ}C$) were investigated to determine the optimum operating conditions. Additionally, the effects of formic acid as a hydrogen-donor solvent instead of $H_2$ gas were examined. The chemical species and quantities in the liquid products were analyzed using gas chromatography-mass spectroscopy(GC-MS), and solid residues(char) were analyzed using FT-IR. GC-MS analysis confirmed that the aromatic chemicals such as anisole, o-cresol(2-methylphenol), p-cresol(4-methylphenol), 2-ethylphenol, 4-ethylphenol, dibenzofuran, 3-methyl cabazole and xanthene were produced when phenol was added in the water as a co-solvent.

The Characteristics of Biopellet Produced Upon Reactor Configuration in UASB System (UASB 공법에 있어서 반응조의 형상변화에 따른 입상슬러지의 특성에 관한 연구)

  • Min, Kyung Sok;Ahn, Young Ho
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.14 no.3
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    • pp.679-688
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    • 1994
  • Physicochemical and morphological characteristics of biopellets produced in "control" and modified UASB reactor were investigated to compare the reactor performance with regard to the hydrogen partial pressure. The characteristics of biopellet produced in modified UASB reactor operated with high hydrogen partial pressure were better than those of "control" reactor operated with relatively lower hydrogen partial pressure, therefore the hydrogen partial pressure effected greatly on the formation and stability of the biopellet. Furthermore, pellets from the UASB system with modified settler showed a better settleability and biomass holding capacity. The chemical composition of biopellet was distinctively different from that of common bacterial formula, $C_5H_7O_2N$. Biopellets was composed the large fraction of nitrogen in comparison with common anaerobic microbes. These results implicated the existence possibility of polypeptide-type extracellular polymer. The morphological characterization with SEM showed that microorganisms observed at surface of biopellet produced in modified UASB reactor operated with high $P_{H_2}$ condition were very similar in shape and size to the Methanobrevibactor arboriphilus-$H_2$ utilizing methanogen. The microorganisms was distinguished from those of "control" reactor operated with low $P_{H_2}$ condition. From these results, it could be explained the hydrogen partial pressure effects on pelletization mechanism.

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Hydraulic Characteristics of Anaerobic Fluidized Bed Bioreactor (혐기성 유동상 반응기의 수리학적 특성)

  • Seok, Jong-Hyuk
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.2
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    • pp.90-96
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    • 2018
  • Tracer experiments were carried out on two laboratory modes, "without media mode" and "with media mode", to examine the hydraulic characteristics of the anaerobic fluidized bed bioreactor (AFBR). For both configurations, a formula was derived for the hydraulics and data interpretation to obtain the actual characteristics of the reactor. The dispersion model is based on the assumption that carriers are non-reacting and the dispersion coefficient is constant. The model represents the one-dimensional unsteady-state concentration distribution of the non-reacting tracer in the reactors. The experimental results showed that the media increased the mixing conditions in the reactor considerably. For the reactor without media, in the range tested, the dispersion coefficient was at least an order of magnitude smaller than that of the reactor with media. Advective transport dominates and the flow pattern approaches the plug flow reactor (PFR) regime. The dispersion coefficient increased significantly as us, the superficial liquid velocity, was increased proportionally to 0.82cm/s. On the other hand, for the reactor with media, the flow pattern was in between a PFR and a completely mixed flow reactor (CMFR) regime, and the dispersion coefficient was saturated at us=0.41cm/s, remaining relatively constant, even at us=0.82cm/s. The dispersion coefficient depends strongly on the liquid Reynolds number (Re) or the particle Reynolds number (Rep) over the range tested.

Effect of Sludge Pellets on $NO_x$ REmoval in $BaTiO_3$-sludge Packed-bed Reactor ($BaTiO_3$-슬러지 Packed-bed형 반응기에서 $NO_x$제거에 미치는 슬러지의 영향)

  • 박재윤;송원섭;고희석;박상현
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.14 no.10
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    • pp.861-867
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    • 2001
  • In this paper, in order to investigate the catalytic effect of the sludge exhausted from waterworks on NO$_{x}$ removal, we measure NO removal characteristics with and without sludge pellets in BaTiO$_3$-sludge packed-bed reactor of plate-plate geometry. NO initial concentration is 50 ppm balanced with air and a gas flow rate is 5ι/min. Gas temperature is changed from 25 to 10$0^{\circ}C$ to investigate the role of sludge pellet on removing active oxygen species and NO$_2$. BaTiO$_3$pellets is filled for coronal discharge at upstream of reactor and sludge pellets is filled for catalytic effect at downstream of reactor. The volume percent of sludge pellets to BaTiO$_3$pellets is changed from 0% to 100% and AC voltage is supplied to the reactor for discharging simulated gases. In the results, when sludge pellets is put at the downstream of plasma reactor, NO removal rate is slightly increased. However, NO$_2$and $O_3$ as by-products during NO removal is significantly decreased from 51ppm without sludge pellets to 5 ppm with sludge pellets and from 50 ppm without sludge pellets to 0.004ppm with sludge pellets, respectively. Therefore, NO$_{x}$(NO+NO$_2$) removal rate is increased up to 93%. It is thought that sludge pellet maybe react with active oxygen species and NO$_2$ generated by corona discharge in surface of BaTiO$_3$pellets, the then NO$_2$O$_3$as by-products are considerably decreased. When we increase gas temperature from room temperature to 10$0^{\circ}C$, NO removal rate is decreased, while NO$_2$ concentration is independent on gas temperature. These result suggest that the removal mechanism of active oxygen species and NO$_2$in sludge pellet is not absorption, but chemical reaction. Therefore we expect that sludge pellets exhausted for waterworks could be used as catalyst for NO$_{x}$ removal with high removal rate and low by-product.oduct.

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