• Title/Summary/Keyword: Chemical Reactor

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Molecular and Ecological Analyses of Microbial Community Structures in Biofilms of a Full-Scale Aerated Up-Flow Biobead Process

  • Ju, Dong-Hun;Choi, Min-Kyung;Ahn, Jae-Hyung;Kim, Mi-Hwa;Cho, Jae-Chang;Kim, Tae-Sung;Kim, Tae-San;Seong, Chi-Nam;Ka, Jong-Ok
    • Journal of Microbiology and Biotechnology
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    • v.17 no.2
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    • pp.253-261
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    • 2007
  • Molecular and cultivation techniques were used to characterize the bacterial communities of biobead reactor biofilms in a sewage treatment plant to which an Aerated Up-Flow Biobead process was applied. With this biobead process, the monthly average values of various chemical parameters in the effluent were generally kept under the regulation limits of the effluent quality of the sewage treatment plant during the operation period. Most probable number (MPN) analysis revealed that the population of denitrifying bacteria was abundant in the biobead #1 reactor, denitrifying and nitrifying bacteria coexisted in the biobead #2 reactor, and nitrifying bacteria prevailed over denitrifying bacteria in the biobead #3 reactor. The results of the MPN test suggested that the biobead #2 reactor was a transition zone leading to acclimated nitrifying biofilms in the biobead #3 reactor. Phylogenetic analysis of 16S rDNA sequences cloned from biofilms showed that the biobead #1 reactor, which received a high organic loading rate, had much diverse microorganisms, whereas the biobead #2 and #3 reactors were dominated by the members of Proteobacteria. DGGE analysis with the ammonia monooxygenase (amoA) gene supported the observation from the MPN test that the biofilms of September were fully developed and specialized for nitrification in the biobead reactor #3. All of the DNA sequences of the amoA DGGE bands were very similar to the sequence of the amoA gene of Nitrosomonas species, the presence of which is typical in the biological aerated filters. The results of this study showed that organic and inorganic nutrients were efficiently removed by both denitrifying microbial populations in the anaerobic tank and heterotrophic and nitrifying bacterial biofilms well-formed in the three functional biobead reactors in the Aerated Up-Flow Biobead process.

Wastewater Treatment using Air-lift Biofilm Reactor (공기부상 생물막 반응기를 이용한 산업폐수 처리)

  • 최광수;한기백
    • Journal of Environmental Science International
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    • v.9 no.4
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    • pp.351-367
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    • 2000
  • Air-lift biofilm reactor should be an admirable process substituting conventional activated sludge process, because of its small area requirement as well as high volumetric loading capacity and stability against loading and chemical shocks. However most of the past research on the performance of ABR was focused on the sewage treatment. This research studied the applicability of ABR to treat high strength wastewater. A bench-scale ABR was operated to treat high strength synthetic wastewater, tannery wastewater and petrochemical wastewater, and its applicability was conclusive In case of synthetic wastewater, ABR showed good performance in which the substarate removal efficiency was higher that 80% even under short HRT(1.4 hr) and high volumetric loading rate(9.3 kgCODcr/$m^3$.day). When ABR was applied to treat tannery wastewater, it was suggested that the maximum volumetric loading rate and F/M ratio should be 7.7kgCODcr/$m^3$.day, 0.76 $day^{-1}$, respectively. And high substrate removal efficiency over than 90 % was observed with 4,000 mgCODcr/L of petrochemical wastewater. Even though effluent concentration was quite high, ABR should be applicable to treat the high strength wastewater, because of its high loading capacity.

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Removal Characteristics of $SO_2$ in the Coal Combustion Flue Gas Treatment Convergence System (석탄화력발전소 현장의 석탄연소 배가스 고도처리용 건식 분류층 반응 실증장치에서의 $SO_2$ 제거성능 특성)

  • Jeon, Seong-Min;Park, Hyung-Sang;Park, Young-Ok
    • Particle and aerosol research
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    • v.9 no.4
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    • pp.239-246
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    • 2013
  • The purpose of this study is to determine the feasibility of dry-type desulfurization process for actual application to coal-fired power plant. We used actual exhaust gas from Facility Y, Plant #2 to fabricate a demo-scale testing device to attempt to improve the efficiency of desulfurization. A spout-bed circulating dry scrubber convergence system connecting turbo reactor with bag filter was devised, then analyzed for performance characteristics of $SO_2$ removal for Ca/S mole ratio, superficial gas velocity, and ammonia injection, and for secondary reaction characteristics of the non-reactive sorbent at the bag filter. As a result, the installation of spout-bed circulating dry scrubber convergence system showed better economy and efficiency for removing sulfur than the existing wet/semidry-type desulfurization process. In addition, the best efficiency for desulfurization occurred when connected to the bag filter, with differential pressure maintained at 150 $mmH_2O$.

Bio-degradation of Phenol in Wastewater by Enzyme-loaded Membrane Reactor: Numerical Approach

  • Barbieri, Giuseppe;Choi, Seung-Hak;Scura, Francesco;Mazzei, Rosalinda;Giorno, Lidietta;Drioli, Enrico;Kim, Jeong-Hoon
    • Membrane Journal
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    • v.19 no.1
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    • pp.72-82
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    • 2009
  • A mathematical model was written for simulating the removal of phenol from wastewater in enzyme-loaded membrane reactor (EMR). The numerical simulation program was developed so as to predict the degradation of phenol through an EMR. Numerical model proves to be effective in searching for optimal operating conditions and creating an optimal microenvironment for the biocatalyst in order to optimize productivity. In this study, several dimensionless parameters such as Thiele Modulus (${\phi}^2$, dimensionless Michaelis-Menten constant ($\xi$), Peclet number (Pe) were introduced to simplify their effects on system efficiency. In particular, the study of phenol conversion at different feed compositions shows that low phenol concentrations and high Thiele Modulus values lead to higher reactant degradation.

Treatment of Food Waste Leachate using Pure-Oxygen Jet Loop Reactor(JLR) (순산소 Jet 폭기 시스템을 이용한 음폐수 처리 특성)

  • Yoon, Ae-Hwa;Park, Noh-Back;Bae, Jong-Hun;Jun, Hang-Bae;Kwon, Young-Bae
    • Journal of Korean Society of Water and Wastewater
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    • v.24 no.6
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    • pp.763-773
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    • 2010
  • The removal efficiencies and a total oxygen transfer coefficient for food waste leachate(FWL) were estimated by using Jet Loop Reactor(JLR). Pure oxygen was used instead of air to improve oxygen concentration in the JLR for high total chemical oxygen demamd(TCOD) in FWL. In JLB, in order to examining the oxygen transfer characteristic, the circulation flowrate and oxygen flowrate were controlled with 7~10 L/min(1.5 L/min interval) and 0.2~0.5 L/min (0.1 L/min interval) and we experimented according to the each condition. As a result, Oxygen uptake rate(OUR) and oxygen transfer rate could be maximized than the oxygen flowrate to increase the circulation flowrate. In addition, it determined that JLR using the pure oxygen which can obtain the greatest oxygen transfer rate as it was the high-concentration organic wastewater like the food waste leachate through the continuous experiment was appropriate.

Quantitative Estimation of Radiation Damage in Reactor Pressure Vessel Steels by Using Multiscale Modeling (멀티스케일 모델링을 이용한 압력용기강의 조사손상 정량예측)

  • Lee, Gyeong-Geun;Kwon, Junhyun
    • Transactions of the Korean Society of Pressure Vessels and Piping
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    • v.10 no.1
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    • pp.113-121
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    • 2014
  • In this work, an integrated model including molecular dynamics and chemical rate theory was implemented to calculate the growth of point defect clusters(PDC) and copper-rich precipitates(CRP) which could change the mechanical properties of reactor pressure vessel(RPV) steels in a nuclear power plant. A number of time-dependent differential equations were established and numerically integrated to estimate the evolution of irradiation defects. The calculation showed that the concentration of the vacancies was higher than that of the self-interstitial atoms. The higher concentration of vacancies induced a formation of the CRPs in the later stage. The size of the CRPs was used to estimate the mechanical property changes in RPV steels, as is the same case with the PDCs. The calculation results were compared with the measured values of yield strength change and Charpy V-notch transition temperature shift, which were obtained from the surveillance test data of Korean light water reactors(LWRs). The estimated values were in fair agreement with the experimental results in spite of the uncertainty of the modeling parameters.

Performance assessment of {tris (2-methyl-1-aziridinyl) phosphine oxide} photocatalytic mineralization in a falling film reactor, using response surface methodology

  • Saien, J.;Raeisi, A.;Soleymani, A.R.;Norouzi, M.
    • Advances in environmental research
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    • v.1 no.4
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    • pp.289-304
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    • 2012
  • Tris (2-methyl-1-aziridinyl) phosphine oxide (MAPO) is extremely poisonous and persistent in aqueous media. An efficient UV/nano$TiO_2$ process was employed for its mineralization in a high duty falling film photo-reactor based on an experimental design scheme that considers interactions between the main variables. The influencing variables and their range were determined with preliminary studies. The results show substrate mineralization to some extent under mild conditions of: T = $30^{\circ}C$, pH = 8.5, $[MAPO]_0=60\;mg\;L^{-1}$ and $[TiO_2]=110\;mg\;L^{-1}$. The relative importance of the influencing parameters were initial pH > temperature > $[MAPO]_0$ > [$TiO_2$]; while the interdependence of all the parameters was significant. Accordingly, a reduced quadratic expression was developed. Meanwhile, mineralization kinetic studies, based on chemical oxygen demand, revealed a power law model with order of 2.6 during process time until 150 min.

Treatment of High Concentration Organic Wastewater with a Sequencing Batch Reactor (SBR) Process Combined with Electro-flotation as a Solids-liquid Separation Method

  • Choi, Younggyun;Park, Minjeong;Park, Mincheol;Kim, Sunghong
    • Environmental Engineering Research
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    • v.19 no.4
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    • pp.395-399
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    • 2014
  • Operation characteristics of the sequencing batch reactor (SBR) process with electro-flotation (EF) as a solid liquid separation method (EF-SBR) were investigated. EF-SBR process showed excellent solid-liquid separation performance which enabled to separate biosolids from liquid phase within 30 min and to extend cyclic reaction time. Although influent organic loading rate was increased stepwise from 5 to 15 g COD/day, food to microorganisms (F/M) ratio could be maintained about 0.3 g COD/g VSS/day in EF-SBR because biomass concentration could be easily controlled at desired level by EF. However, it was impossible to increase biomass concentration at the same level in control SBR (C-SBR) process because solid-liquid separation by gravity settling showed a limitation at higher mixed liquor suspended solids (MLSS) concentration with 60 min of settling time. Total chemical oxygen demand (TCOD) removal efficiency of EF-SBR process was not decreased although influent organic loading rate became 3 times higher than initial value. However, it was seriously deteriorated in C-SBR process after increasing the rate over 10 g COD/day, which was accounted for insufficient organic removal by relatively higher food to microorganisms (F/M) ratio as well as biosolids wash-out by a limitation of gravity sedimentation.

Reactor design of PECVD system using a liquid aerosol feed method (미립액상법을 위한 PECVD 반응로설계)

  • 정용선;오근호
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.7 no.2
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    • pp.235-243
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    • 1997
  • The high-$T_c$ superconducting phase, $YBa_2Cu_3O_x$, was deposited on the single crystal MgO substrate, using a liquid aerosol feed method in a plasma enhanced chemical vapor deposition(PECVD) reactor. The effect of the plasma distribution depending on the design of a reactor was studied by the analysis of the microstructures of thin films. The particles landed were frequently observed on the films and the two causes that were responsible for the particle deposition were explained. The particles were deposited by the unstable and non-uniform plasma and the low evaporation rate of the precursors. Also, the thin film deposition rate decreased significantly as the distance between the evaporating location and the substrate increased.

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The Investigation of Reaction Parameters on the Reactivity in the Preparation of TiB2 by SHS (자전연소합성법에 의한 TiB2 분말의 제조에 있어 반응성에 대한 반응변수의 고찰)

  • Shin, Chang-Yun;Park, Young-Chul;Lee, Huk-Hee;Nersisyan, Hayk;Won, Chang-Whan
    • Journal of the Korean Ceramic Society
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    • v.43 no.1 s.284
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    • pp.16-21
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    • 2006
  • The preparation of $TiB_2$ by SHS in $B_2O_3-Mg-TiO_2$ system was investigated in this study. In the preparation of $TiB_2$, the effect on reactivity and reaction products of the initial pressure of inert gas in reactor, the content of Mg and $TiO_2$ in mixture was investigated. The minimum initial pressure of inert gas in reactor for SHS reaction in this system was 5atm, and as the pressure increased, the concentration of unreacted Mg decreased and combustion temperature increased. At the initial inert gas pressure in reactor of 50atm, the optimum composition for the preparation of pure $TiB_2$ was $B_2O_3+5Mg+TiO_2$. The $TiB_2$ synthesized in this condition had an irregular shape and the particle size of $1\~3{\mu}m$.