• Title/Summary/Keyword: Chemical Reactor

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Properties of Precursor Pitch Derived from Petroleum Residue

  • Yu, Hae-Il;Lee, Gyu-Dong;Gwon, Yeong-Bae
    • 한국기계연구소 소보
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    • s.15
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    • pp.37-46
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    • 1985
  • Properties of Precursor pitch derived from petroleum residue were studied physical and chemical analysis method for investigation of production of pitch fiber. For preparing of those precursor pitches it was carried out a temperature and time variation experiment i reactor. It was demonstrated the precursor pitch prepared in this study to have a similar properties to Ashland precursor pitch capable of bulk mesophase formation from the results of the basic analysis, that is, molecular weight distribution, coking yield, carbon content, chemical composition, etc.

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The Effect of CVD Reaction Variable on SnO2 Powder Characteristics

  • Kim, Kyoo-Ho
    • The Korean Journal of Ceramics
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    • v.4 no.3
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    • pp.235-239
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    • 1998
  • Ultrafine $SnO_2$ powder was prepared by the diffusion mixing gas-phase reaction of $SnCl_4$(g) and water vapor. The effects of reaction variables, such as the chloride partial pressure, the reaction temperature, and the residence time is the reactor, on the powder size were examined systematically. Calculated concentration and distribution of chemical species, using the Burke-Schumann diffusion mixing model, were compared with the experimetal results. The effects of the reaction variables on the powder size were also discussed qualitatively.

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Novel Polypyrrole composite membrane with high gas selectivity and permeability

  • Son, Won-Il;Kim, Byoung-Sik;Hong, Jae-Min
    • Proceedings of the Membrane Society of Korea Conference
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    • 2004.05b
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    • pp.147-152
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    • 2004
  • Gas separation membrane technology is useful for a variety of applications [1, 2]. such as hydrogen recovery from reactor purge gas, nitrogen and oxygen enrichment, water vapor removal from air, stripping of carbon dioxide from natural gas. etc. Although membrane separations are attractive because of low energy costs and simple operation, low permeabilities and/or selectivity often limit membrane applications [3, 4].(omitted)

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Toward the Construction of High-tech Infrastructure for Clean Manufacturing in Japanese Chemical Industry -Challenge of Simple Chemistry Program-

  • Shimizu, Yoshiaki
    • Clean Technology
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    • v.2 no.2
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    • pp.90-99
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    • 1996
  • Being confronted with the 21th century at hand, a paradigm shift has been a common topic for development in many fields. Among these, a concept of sustainable development is the most important one to resolve conflict and nurture mutualism between science/technology(SCI/TEC) and society/environment(SOC/ENV). Looking briefly over the resent stats of the chemical industry in Japan, in this paper, we will introduce a research program named simple chemistry as an example for such a challenge.

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Neural Model Predictive Control for Nonlinear Chemical Processes

  • Song, Jeong-Jun;Park, Sunwon
    • Proceedings of the Korean Institute of Intelligent Systems Conference
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    • 1993.06a
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    • pp.899-902
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    • 1993
  • A neural model predictive control strategy combining a neural network for plant identification and a nonlinear programming algorithm for solving nonlinear control problems is proposed. A constrained nonlinear optimization approach using successive quadratic programming combined with neural identification network is used to generate the optimum control law for complex continuous chemical reactor systems that have inherent nonlinear dynamics. The neural model predictive controller (MNPC) shows good performances and robustness. To whom all correspondence should be addressed.

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Direct Synthesis of Trisilaalkanes

  • Il Nam Jung;Gyu-Hwan Lee;Seung-Ho Yeon;Mi-Yeon Suk
    • Bulletin of the Korean Chemical Society
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    • v.12 no.4
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    • pp.445-449
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    • 1991
  • A series of trisilaalkanes has been prepared in high yields by the direct reaction of ${\alpha}$ -chloromethylsilanes with metallic silicon in the presence of copper catalyst using the stirred reactor equipped with a spiral band agitator at the carefully controlled temperature between $280^{\circ}C$ and $340^{\circ}C.$ Disilaalkane compounds were obtained as the minor products. Cadmium was found to be a good promotor for the reactions, while zinc was an inhibitor.

Performance Estimation and Process Selection for Chemical-Looping Hydrogen Generation System (금속매체 순환식 수소생산 시스템의 성능예측 및 공정선정)

  • Ryu, Ho-Jung;Jin, Gyoung-Tae
    • Transactions of the Korean hydrogen and new energy society
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    • v.16 no.3
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    • pp.209-218
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    • 2005
  • To find a suitable metal component in oxygen carrier particles for chemical-looping hydrogen generation system(CLH), oxygen transfer capacities of metal components were compared and Ni has been selected as the best metal component. The proper operating conditions to achieve high hydrogen generation rate have been investigated based on the chemical-equilibrium composition analysis for water splitting reactor. Moreover, suitable compositions of syngas from gasifier of heavy residue to achieve high energy efficiency have been investigated by calculation of heat of reaction. Based on the selected operating conditions, the best configuration of two interconnected fluidized beds system for the chemical-looping hydrogen generator has been investigated as well.

Numerical Analysis of the Chemical Injection Characteristics Using a Low Reynolds Number Turbulence Model

  • Chang, Byong-Hoon;Chang Kyu;Park, Han-Rim
    • Journal of Energy Engineering
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    • v.8 no.1
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    • pp.110-118
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    • 1999
  • In order to protect the nuclear reactor coolant system from corrosion, lithium is injected into the coolant from the chemical injection tank. The present study investigates the chemical injection characteristics of the injection tank using a low Reynolds number turbulence model. Laminar flow analysis showed very little diffusion of the jet and gave incorrect flow and concentration fields. A disk located near the inlet of the injection tank was effective in mixing the chemical additives in the top portion of the tank, and significant reduction in injection time was obtained.

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Hydrolysis of Rice Bran Oil Using Immobilized Lipase in a Stirred-Batch Reactor

  • Murty, V.Ramachandra;Bhat, Jayadev;Muniswaran, P.K.A.
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.7 no.6
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    • pp.367-370
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    • 2002
  • Candida cylindracea lipase was immobilized by adsorption on acid washed glass beads. It was observed that protein loading of the support depends on the size of the particle, with smaller particle containing higher amount of protein per unit weight. Initial reaction rate linearly varied up to enzyme concentration of 17.25 U/mL. Amount of free fatty acids produced was linearly proportional up to the enzyme loading of 1650 $\mu$g/g of bead. Achievement of chemical equilibrium took longer time in the case of less protein loading. Degree of hydrolysis was found to decrease in second and third consecutive batch operations on repeated use of immobilized lipase.

Photocatalytic Membrane Reactor for VOC Decomposition Using Pt-Modified Titanium Oxide Membranes

  • Toshinori Tsuru;no, Takehiro-Kan;Tomohisa Yoshioka;Masashi Asaeda
    • Proceedings of the Membrane Society of Korea Conference
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    • 2004.05a
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    • pp.39-42
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    • 2004
  • Ceramic membranes have attracted a great attention because they have excellent resistance to most organic solvents and can be used over a wide temperature range. Especially, titania (titanium oxide, TiO$_2$) shows excellent chemical resistance and can be used both acidic and alkali solutions, and therefore, titania is one of the most promising materials for the preparation of porous membranes; titania membranes having pore sizes in the range of nanofiltration (NF) to ultrafiltration (UF) membrane have been prepared by the sol-gel process (Tsuru 2001).(omitted)

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