• Title/Summary/Keyword: Chemical Reactor

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A Study on Performance Evaluation for the Bio-retention Non-point Source Pollution Treatment System (생물 저류 방법 적용을 통한 비점오염원 처리시설의 성능평가에 관한 연구)

  • Lee, Jang-Soo;Park, Yeon-Soo;Cho, Wook-Sang
    • Clean Technology
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    • v.19 no.3
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    • pp.295-299
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    • 2013
  • This study was purposed and performed to evaluate removal efficiency of non-point source pollution in the process and system based on bio-retention design criteria regulated by EPA. Basic Column Reactors (BCR) were prepared for optimal determinations of inflow rate of first rainfall runoff and composition and ratio of soil layers. Removal efficiencies of non-point source pollution from synthetic runoff and real first rainfall runoff, directly sampled from motor way and parking lot, were analyzed, respectively. Removal efficiency of SS, BOD, COD, T-N, and T-P were all shown to be more than 80%.

바이오매스 구성성분 중 리그닌의 전환에 관한 연구

  • Yun, Seong-Uk;Lee, Byeong-Hak
    • 한국생물공학회:학술대회논문집
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    • 2000.11a
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    • pp.733-736
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    • 2000
  • Lignin is usable as fuels and heavy oil additives if depolymerized to monomer unit, because the chemical structures are similar to high octane materials found in gasoline. In this study, the solvent-phase thermal cracking(solvolysis) of lignin was performed at the various temperature and time in a laboratory tubular reactor. Conversion yield was measured for the properties of thermal cracking and liquefaction reaction of lignin. Highest conversion yield when acetone was used as thermal cracking solvent was 55.5% at $350^{\circ}C$, 50minutes and highest tar generation were $260{\sim}350mg/g\;{\cdot}\;lignin$ at $250^{\circ}C$, and highest conversion yield after tar removal was 76.88% at $300^{\circ}C$, 30minutes. Conversion yield, product compositions and amounts were determined by tar degradation yield.

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The Effect on the Steam Gasification Reaction of Low-Rank Coal Mixed with Waste Catalysts (저급 석탄과 혼합한 폐촉매의 수증기 가스화 반응에 미치는 영향)

  • Kwak, Jaehoon;Seo, Seokjin;Lee, Sojung;Song, Bungho;Sohn, Jung Min
    • Transactions of the Korean hydrogen and new energy society
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    • v.23 no.6
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    • pp.647-653
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    • 2012
  • We have investigated the kinetics and activity of waste catalysts for steam-lignite gasification. Waste catalysts I, II, III and reference $K_2CO_3$ were used and physical mixed with a coal. The gasification experiments were carried out with the low rank coal loaded with 1 wt% and 5 wt% catalyst at the temperature range from 700 to $900^{\circ}C$ using thermobalance reactor. It was observed that the carbon conversion reached almost 100% regardless of the kinds of catalysts at $900^{\circ}C$. The shortest time to reach the designated conversion was obtained for 1 wt% waste catalyst II and 5 wt% $K_2CO_3$ at $900^{\circ}C$. The gasification reaction rate constant increased with increasing the temperature. Highest rate constant was obtained with $K_2CO_3$ at $900^{\circ}C$. The lowest activation energy was 69.42 kJ/mol for 5 wt% waste catalyst II. The waste catalyst had an influence on the reduction of activation energy.

The Characteristics of Two Phase Flow by Non-Newtonian Fluid for Vertical Up-ward in a Tube (수직 상향유동 배관에서 비뉴톤유체에 의한 2상류의 유동특성)

  • Cha K.O.;Kim J. G.;Che K.S.
    • Journal of the Korean Institute of Gas
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    • v.2 no.4
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    • pp.53-59
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    • 1998
  • Flow pattern of air-water two phase flow depends on the conditions of pressure drop, void fraction, and channel geometry. Drag reduction in the two phase flow can be applied to the transport of crude oil, phase change systems such as chemical reactor, pool and boiling flow, and to present cavitation which occurs in pump impellers. But the research on drag reduction in two phase flow is not intensively investigated. Therefore, experimental investigations have been carried out to analyze the drag reduction produced and void fraction by Co-polymer(A611p) addition in the two phase flow system. We find that the maximum point position of local void friction moves from the wall of the pipe to the center of the pipe when polymer concentration increases. Also we find that the polymer solution changes the characteristics of the two phase flow. And then we predict that it is closely related with the drag reduction.

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Control of Airborne Organic Pollutants Using Plug-Flow Reactor Coated With Carbon Material-Titania Mixtures Under Visible-Light Irradiation

  • Jo, Wan-Kuen;Kang, Hyun-Jung;Kim, Mo-Keun
    • Journal of Environmental Science International
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    • v.22 no.10
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    • pp.1263-1271
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    • 2013
  • Graphene oxide (GO)-titania composites have emerged as an attractive heterogeneous photocatalyst that can enhance the photocatalytic activity of $TiO_2$ nanoparticles owing to their potential interaction of electronic and adsorption natures. Accordingly, $TiO_2$-GO mixtures were synthesized in this study using a simple chemical mixing process, and their heterogeneous photocatalytic activities were investigated to determine the degradation of airborne organic pollutants (benzene, ethyl benzene, and o-xylene (BEX)) under different operational conditions. The Fourier transform infrared spectroscopy results demonstrated the presence of GO for the $TiO_2$-GO composites. The average efficiencies of the $TiO_2$-GO mixtures for the decomposition of each component of BEX determined during the 3-h photocatalytic processes were 26%, 92%, and 96%, respectively, whereas the average efficiencies of the unmodified $TiO_2$ powder were 3%, 8%, and 10%, respectively. Furthermore, the degradation efficiency of the unmodified $TiO_2$ powder for all target compounds decreased during the 3-h photocatalytic processes, suggesting a potential deactivation even during such a short time period. Two operational conditions (air flow entering into the air-cleaning devices and the indoor pollution levels) were found to be important factors for the photocatalytic decomposition of BEX molecules. Taken together, these results show that a $TiO_2$-GO mixture can be applied effectively for the purification of airborne organic pollutants when the operating conditions are optimized.

Operation diagnostic based on PCA for wastewater treatment (PCA를 이용한 하폐수처리시설 운전상태진단)

  • Jun Byong-Hee;Park Jang-Hwan;Chun Myung-Geun
    • Journal of the Korean Institute of Intelligent Systems
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    • v.16 no.3
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    • pp.383-388
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    • 2006
  • SBR is one of the most general sewage/wastewater treatment processes and, particularly, has an advantage in high concentration wastewater treatment like sewage wastewater. A Kernel PCA based fault diagnosis system for biological reaction in full-scale wastewater treatment plant was proposed using only common bio-chemical sensors such as ORP(Oxidation-Reduction Potential) and DO(Dissolved Oxygen). During the SBR operation, the operation status could be divided into normal status and abnormal status such as controller malfunction, influent disturbance and instrumental trouble. For the classification and diagnosis of these statuses, a series of preprocessing, dimension reduction using PCA, LDA, K-PCA and feature reduction was performed. Also, the diagnosis result using differential data was superior to that of raw data, and the fusion data show better results than other data. Also, the results of combination of K-PCA and LDA were better than those of LDA or (PCA+LDA). Finally, the fault recognition rate in case of using only ORP or DO was around maximum 97.03% and the fusion method showed better result of maximum 98.02%.

Numerical Simulation on the Spreading and Heat Transfer of Ex-Vessel Core Melt in a Channel (전산해석을 이용한 원자로 노심 용융물의 노외 거동 및 열전달 특성 분석)

  • Ye, In-Soo;Ryu, Chang-Kook;Ha, Kwang-Soon;Song, Jin-Ho
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.35 no.4
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    • pp.425-429
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    • 2011
  • In the unlikely of nuclear reactor meltdown, the leaked core melt or corium must be contained in a device called core-catcher so that the corium can be cooled and stabilized. The ex-vessel behavior of corium involves complex physical and chemical mechanisms of flow propagation, heat transfer, and reactions with sacrificial substrates. In this study, the detailed characteristics of corium flow and heat transfer were investigated by using a commercial CFD code for VULCANO VE-U7 test reported in the literature. The volume-of-fluid (VOF) model was used to predict the interfacial surface formation of corium and the surrounding air, and the discrete ordinate model was adopted to calculate radiation between corium and the surroundings. It was found that cooling via radiation through the top surface of corium had a dominant effect on the temperature and viscosity profiles at the front of the corium flow.

Fuzzy PD plus I Controller of a CSTR for Temperature Control

  • Lee, Joo-Yeon;So, Hye-Rim;Lee, Yun-Hyung;Oh, Sea-June;Jin, Gang-Gyoo;So, Myung-Ok
    • Journal of Advanced Marine Engineering and Technology
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    • v.39 no.5
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    • pp.563-569
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    • 2015
  • A chemical reaction occurring in CSTR (Continuous Stirred Tank Reactor) is significantly affected by the concentration, temperature, pressure, and reacting time of materials, and thus it has strong nonlinear and time-varying characteristics. Also, when an existing linear PID controller with fixed gain is used, the performance could deteriorate or could be unstable if the system parameters change due to the change in the operating point of CSTR. In this study, a technique for the design of a fuzzy PD plus I controller was proposed for the temperature control of a CSTR process. In the fuzzy PD plus I controller, a linear integral controller was added to a fuzzy PD controller in parallel, and the steady-state performance could be improved based on this. For the fuzzy membership function, a Gaussian type was used; for the fuzzy inference, the Max-Min method of Mamdani was used; and for the defuzzification, the center of gravity method was used. In addition, the saturation state of the actuator was also considered during controller design. The validity of the proposed method was examined by comparing the set-point tracking performance and the robustness to the parameter change with those of an adaptive controller and a nonlinear proportional-integral-differential controller.

Evaluation of Fatigue Life on Alloy 617 Base Metal and Alloy 617/Alloy 617 Weld Joints under Low Cycle Fatigue Loading (저사이클피로 하중하의 Alloy 617 모재와 용접부재에 대한 피로 수명 평가)

  • Dewa, Rando Tungga;Kim, Seon-Jin;Kim, Woo-Gon;Kim, Min-Hwan
    • Journal of Power System Engineering
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    • v.18 no.5
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    • pp.122-128
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    • 2014
  • Generally, the mechanical components and structures are joined by many welding techniques, and therefore the welded joints are inevitable in the construction of structures. The Alloy 617 was initially developed for high temperature applications above $800^{\circ}C$. It is often considered for use in aircraft and gas turbines, chemical manufacturing components, and power generation structures. Especially, the Alloy 617 is the primary candidate for construction of intermediate heat exchanger (IHX) on a very high temperature reactor (VHTR) system. In the present paper, the low cycle fatigue (LCF) life of Alloy 617 base metal (BM) and the gas tungsten arc welded (GTAWed) weld joints (WJ) are evaluated by using the previous experimental results under strain controlled LCF tests. The LCF tests have been performed at room temperature with total strain ranges of 0.6, 0.9, 1.2 and 1.5%. The LCF lives for the BM and WJ have been evaluated from the Coffin-Manson and strain energy based life methods. For both the BM and WJ, the LCF lives predicted by both Coffin-Manson and strain energy based life methods was found to well coincide with the experimental data.

A Performance Evaluation of the Highly Efficient Coagulation System for the Treatment of Overflows from Primary Clarifier in WWTP (강우시 하수처리장 일차침전지 월류수 처리를 위한 고효율응집시스템의 적용성 평가)

  • Gwon, Eun-Mi;Oh, Seok-Jin;Kim, Heung-Seup;Cho, Seung-Ju;Lee, Seung-Chl;Ha, Sung-Ryong;Lim, Chea-Hoan;Park, Ji-Hoon;Kang, Seon-Hong
    • Journal of Korean Society of Water and Wastewater
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    • v.25 no.3
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    • pp.391-398
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    • 2011
  • This study is to develop highly efficient coagulation system(HECS) that runs treatment with a short retention time to cover the overflow in the rain, which coagulation, mixing and settling are contacted in a single reactor and to estimate the applicability. Setting up 100ton/day-size pilot scale plant, the results of continuous operation in case of runoff, maintaining 20 minute-retention time at optimum chemical injection condition(Alum 100mg/L, Polymer 1.0mg/L) shows the highest removal efficiency(Turbidity 93.1%, TCODcr 80.6%, BOD 81.8%, SS 92.5%, TN 72.3% and T-P 87.3%). It was estimated that the large amount of cost for separate sewage system and the size of area for system instruction can be reduced if the HECS is applied for CSOs treatment because the HECS is so compact and quickly. When we see the results, HECS from this study could be able to treat the pollutant quickly within a short retention time only with coagulant and polymer, which could show high applicability.