• Title/Summary/Keyword: Chemical Processes

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A Study on Knowledge Representation for Recognizing Hazardous States in Chemical Processes (화학공정의 위험상태 인식을 위한 지식 표현에 관한 연구)

  • 안대명;황규석
    • Journal of the Korean Society of Safety
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    • v.11 no.3
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    • pp.104-111
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    • 1996
  • A system was developed that could predict hazardous states for safe operation of chemical plants. This system aimed to prevent hazards of chemical processes from misoperation before real operation. In this study, a data base was organized which consisted of all hazards in the chemical processes. The structure of process was represented by signed direct graph(SDG) of NODEs and ARCs. Each NODE and ARC have property variables ; connected structure and state of processes etc. The hazards that could be occurred in processes were divided into two classes ; one is by operation of unit and the other is by hazardous materials. Using Hazardous States Transition Network, we could recognize transition progress of process states.

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Types & Characteristics of Chemical Substances used in the LCD Panel Manufacturing Process (LCD 제조공정에서 사용되는 화학물질의 종류 및 특성)

  • Park, Seung-Hyun;Park, Hae Dong;Ro, Jiwon
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.29 no.3
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    • pp.310-321
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    • 2019
  • Objectives: The purpose of this study was to investigate types and characteristics of chemical substances used in LCD(Liquid crystal display) panel manufacturing process. Methods: The LCD panel manufacturing process is divided into the fabrication(fab) process and module process. The use of chemical substances by process was investigated at four fab processes and two module processes at two domestic TFT-LCD(Thin film transistor-Liquid crystal display) panel manufacturing sites. Results: LCD panels are manufactured through various unit processes such as sputtering, chemical vapor deposition(CVD), etching, and photolithography, and a range of chemicals are used in each process. Metal target materials including copper, aluminum, and indium tin oxide are used in the sputtering process, and gaseous materials such as phosphine, silane, and chlorine are used in CVD and dry etching processes. Inorganic acids such as hydrofluoric acid, nitric acid and sulfuric acid are used in wet etching process, and photoresist and developer are used in photolithography process. Chemical substances for the alignment of liquid crystal, such as polyimides, liquid crystals, and sealants are used in a liquid crystal process. Adhesives and hardeners for adhesion of driver IC and printed circuit board(PCB) to the LCD panel are used in the module process. Conclusions: LCD panels are produced through dozens of unit processes using various types of chemical substances in clean room facilities. Hazardous substances such as organic solvents, reactive gases, irritants, and toxic substances are used in the manufacturing processes, but periodic workplace monitoring applies only to certain chemical substances by law. Therefore, efforts should be made to minimize worker exposure to chemical substances used in LCD panel manufacturing process.

Molecular Level Detection of Heavy Metal Ions Using Atomic Force Microscope (원자간인력현미경을 이용한 분자수준의 중금속 이온 검출)

  • Kim, Younghun;Kang, Sung Koo;Choi, Inhee;Lee, Jeongjin;Yi, Jongheop
    • Clean Technology
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    • v.11 no.2
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    • pp.69-74
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    • 2005
  • A metal ion detector with a submicron size electrode was fabricated by field-induced AFM oxidation. The square frame of the mesa pattern was functionalized by APTES for the metal ion detection, and the remaining portion was used as an electrode by the self-assembly of MPTMS for Au metal deposition. The conductance changed with the quantity of adsorbed copper ions, due to electron tunneling between the mobile and surface electrodes. The smaller electrode has a lower limit of detection due to the enhancement in electron tunneling through metal ions that are adsorbed between the conductive-tip (mobile) and the surface (fixed) electrode. This two-electrode system immobilized with different functional groups was successfully used in the selective adsorption and detection of target materials.

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A modified simulated annealing search algorithm for scheduling of chemical batch processes with CIS policy

  • Kim, Hyung-Joon;Jung, Jae-Hak
    • 제어로봇시스템학회:학술대회논문집
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    • 1995.10a
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    • pp.319-322
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    • 1995
  • As a trend toward multi-product batch processes is increasing in Chemical Process Industry (CPI), multi-product batch scheduling has been actively studied. But the optimal production scheduling problems for multi-product batch processes are known as NP-complete. Recently Ku and Karimi [5] have studied Simulated Annealing(SA) and Jung et al.[6] have developed Modified Simulated Annealing (MSA) method which was composed of two stage search algorithms for scheduling of batch processes with UIS and NIS. Jung et al.[9] also have studied the Common Intermediate Storage(CIS) policy which have accepted as a high efficient intermediate storage policy. It can be also applied to pipeless mobile intermediate storage pacilities. In spite of these above researches, there have been no contribution of scheduling of CIS policy for chemical batch processes. In this paper, we have developed another MSA for scheduling chemical batch processes with searching the suitable control parameters for CIS policy and have tested the this algorithm with randomly generated various scheduling problems. From these tests, MSA is outperformed to general SA for CIS batch process system.

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Pervaporative Butanol Fermentation Using a New Bacterial Strain

  • Park, Chang-Ho
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.1 no.1
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    • pp.1-8
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    • 1996
  • Fermentation processes for the production of butanol had an economic importance in the first part of this century. Today butanol is commercially produced from the Oxo reaction of propylene because relatively low priced propylene during the cracking of petroleum. Efforts have been made during the past decade or two to improve the productivity of butanol fermentation processes. It includes strain improvements, continuous fermentation processes, cell immobilization and simultaneous product separation. This review introduces a new butanol fermentation process using pervaporative product separation and a new bacterial strain producing less amount of organic acids. This review also compares the new process with chemical processes. This kind of new fermentation process may be able to compete with the chemical synthesis of butanol and revitalize the butanol fermentation process.

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Biological Hydrogen Production Processes (생물학적 수소생산 공정)

  • Shin, Jong-Hwan;Park, Tai Hyun
    • Korean Chemical Engineering Research
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    • v.44 no.1
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    • pp.16-22
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    • 2006
  • Biological hydrogen production processes are more environment-friendly and less energy intensive than thermochemical and electrochemical processes. The biological process can be divided into two categories: photosynthetic hydrogen production and hydrogen production by dark fermentation. Photosynthetic process produces hydrogen mainly from water and reduces $CO_2$ simultaneously. Dark fermentation is a dark and anaerobic process that produces hydrogen by fermentative bacteria from organic carbon. The article presents a survey of biological hydrogen production processes.

Colloidal-Chemical Parameters of Petroleum-collecting and Dispersing Surfactants Based on Vegetable Oil Acid Fractions and 2-(Chloromethyl) Oxirane

  • Asadov, Ziyafaddin H.;Ahmadova, Gulnara A.;Rahimov, Ravan A.;Mammadova, Khuraman A.
    • Journal of the Korean Chemical Society
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    • v.55 no.6
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    • pp.1012-1017
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    • 2011
  • Novel surfactants have been synthesized by catalytic chloropropoxylation reaction of carboxylic acid fractions of sunflower, olive, cottonseed, soya-bean, castor and corn oils with 2-(chloromethyl)oxirane. Colloidal-chemical parameters as well as petroleum-collecting and petroleum-dispersing capacities of the synthesized chloropropoxylate esters having heterochain of various lengths have been determined. Influence of carboxylic acid fractions composition and length of chloroxypropylene chain on petroleum-collecting and dispersing capacities has been revealed.

Iterative identification methods for ill-conditioned processes

  • Lee, Jietae;Cho, Wonhui;Edgar, Thomas F.
    • 제어로봇시스템학회:학술대회논문집
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    • 1997.10a
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    • pp.1762-1765
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    • 1997
  • Some ill-conditioned processes are very sensitive to small element-wise uncertainties arising in classical element-by-element model identifications. For such processes, accurate identification of simgular values and right singular vectors are more important than theose of the elements themselves. Singular values and right singular vectors can be found by iteraive identification methods which implement the input and output transformations iteratively. Methods based on SVD decomposition, QR decomposition and LU decomposition are proposed and compared with the Kuong and Mac Gregor's method. Convergence proofs are given. These SVD and QR mehtods use normal matrices for the transformations which cannot be calculated analytically in general and so they are hoard to apply to dynamic processes, whereas the LU method used simple analyitc transformations and can be directly applied to dynamic processes.

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