Browse > Article
http://dx.doi.org/10.5012/jkcs.2011.55.6.1012

Colloidal-Chemical Parameters of Petroleum-collecting and Dispersing Surfactants Based on Vegetable Oil Acid Fractions and 2-(Chloromethyl) Oxirane  

Asadov, Ziyafaddin H. (Institute of Petrochemical Processes of Azerbaijan National Academy of Sciences)
Ahmadova, Gulnara A. (Institute of Petrochemical Processes of Azerbaijan National Academy of Sciences)
Rahimov, Ravan A. (Institute of Petrochemical Processes of Azerbaijan National Academy of Sciences)
Mammadova, Khuraman A. (Institute of Petrochemical Processes of Azerbaijan National Academy of Sciences)
Publication Information
Journal of the Korean Chemical Society / v.55, no.6, 2011 , pp. 1012-1017 More about this Journal
Abstract
Novel surfactants have been synthesized by catalytic chloropropoxylation reaction of carboxylic acid fractions of sunflower, olive, cottonseed, soya-bean, castor and corn oils with 2-(chloromethyl)oxirane. Colloidal-chemical parameters as well as petroleum-collecting and petroleum-dispersing capacities of the synthesized chloropropoxylate esters having heterochain of various lengths have been determined. Influence of carboxylic acid fractions composition and length of chloroxypropylene chain on petroleum-collecting and dispersing capacities has been revealed.
Keywords
Nonionic surfactants; Chloropropoxylates; Fatty acids; Petroleum-collecting;
Citations & Related Records

Times Cited By SCOPUS : 0
연도 인용수 순위
  • Reference
1 Asadov, Z. H.; Aga-zade, A. D.; Ahmadova, G. A.; Zarbaliyeva, I. A.; Eyubova, S. K.; Salamova, N. V.; Isayeva, M. Z. Oil industry 2004, 4, 116.
2 Ahmadova, G. A. Processes Petrochem. Oil Refin. 2004, 19, 15.
3 Rosen, M. J. Surfactants and Interfacial Phenomena, 3rd ed., John Wiley and Sons: New York, 2004.
4 Humbatov, H. H.; Dashdiev, R. A. Application of Surfactants for Liquidation of Accidental Crude Oil Spills on the Water Surface; Elm Publishers: Baku, 1998.
5 Murphy, D. S.; Rosen, M. J. J. Phys. Chem. 1988, 92, 2870.
6 Clark, R. B.; Frid, Ch.; Attrill, M. Marine Pollution; Clarendon Press: Oxford, 1997.
7 Adamovich, B. A.; Derbichev, A. G. B.; Dudov, V. I. Chem. Pet. Eng. 2008, 44, 38.   DOI
8 Atta, A. M.; Abdel-Rauf, M. E.; Maysour, N. E.; Abdul-Rahiem, A. M.; Abdel-Azim, A. A. J. Polymer Res. 2006, 13, 39.   DOI
9 Lepain, A. O. U.S. Patent 4224152, 1980.
10 Varadaraj, R.; Robbins, M. L.; Bock, J.; Pace, S. J. U.S. Patent 6011072, 2000.
11 Lessard, R. R.; Demarco, G. Spill Science Technology Bulletin 2000, 6, 59.   DOI
12 Gaaseidnes, K.; Turbeville, J. Pure Appl. Chem. 1999, 71, 95.   DOI
13 Ahmadova, G. A. Processes Petrochem. Oil Refin. 2007, 29, 16.
14 Asadov, Z. H.; Ahmadova, G. A.; Rahimov, R. A. Materials Innovations Research 2010, 14, 327.   DOI
15 Myers, D. Surfaces, Interfaces and Colloids: Principles and Applications, 2nd ed.; John Wiley & Sons: New York, 1999.
16 Ahkmadova, G. A. Azerbaijan Chemical Journal 2006, 3, 136.