• Title/Summary/Keyword: Chemical Plant Safety Management

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Investigation of Ingredients and Hazardous Substances in Disinfectants Used against COVID-19 and Some Livestock Diseases (코로나바이러스감염증-19와 일부 가축전염병 방역소독제품의 함유성분 및 유해물질 조사)

  • Kim, DongHyun;Lim, Miyoung;Lee, Kiyoung
    • Journal of Environmental Health Sciences
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    • v.46 no.4
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    • pp.470-479
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    • 2020
  • Objectives: The Coronavirus Disease 2019 (COVID-19) pandemic has caused the death of 740,000 people around the world as of August 12, 2020. Foot-and-Mouth Disease, Avian Influenza, and African Swine Fever are serious livestock diseases. Government agencies in Korea have provided ingredient information and usage instructions for disinfectants used to counter those infectious diseases. The purpose of this study was to provide information on the chemical ingredients in disinfectant products used against COVID-19 and certain livestock diseases. Methods: We collected information from the Korean government. The Central Disaster Management Headquarters and Central Disease Control Headquarters provided information on disinfectant products used against COVID-19. The Animal and Plant Quarantine Agency of Korea provided information on efficacy-certified disinfectant products for use against selected livestock diseases. Health hazard and environmental hazard information on the ingredients in the disinfectants was collected from the Korea Occupational Safety & Health Agency's Material Safety Data Sheets, and toxicity value information was collected from United States Environmental Protection Agency's CompTox Chemicals Dashboard. Results: There were 76 COVID-19 disinfectant products in use, and the most common ingredients were benzalkonium chloride (51%), alkylbenzyl dimethyl ammonium (30%), and ethanol (3%). There were 216 livestock disease disinfectant products comprised of 89 acidic, 88 oxidic, 30 aldehydic, three alkaline, and six other products. Among the 49 active ingredients used in the disinfectants that were investigated, health and environmental hazard information was provided for many of them, but only 20 chemicals had official toxicological information. Conclusion: Since the disinfectants included numerous chemicals, an understanding of their chemical characteristics could be critical to prevent unintended human or environmental exposure.

A Study on the Fabrication of Multi-Walled Nanotubes (MWCNT) Based Thin Film and Chemical Sensor Operation Characteristics (Multi-Walled Carbon Nanotubes (MWCNT) 인쇄박막의 제작과 화학센서 동작 특성에 관한 연구)

  • Noh, Jae Ha;Choi, Junseck;Ko, Dongwan;Seo, Joonyoung;Lee, Sangtae;Jung, Jung-Yeul;Chang, Jiho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.33 no.3
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    • pp.181-185
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    • 2020
  • Hazardous and noxious substance (HNS) detection sensors were fabricated using multi-walled carbon nanotubes (MWCNTs) and various binder materials for ion batteries. To obtain uniformly printed films, the printing precision according to the substrate cleaning method was monitored, and the printing paste mixing ratio was investigated. Binders were prepared using styrene butadiene rubber + carboxymethyl cellulose (SBR+CMC), polyvinylidene fluoride + n-methyl-2-pyrrolidene (PVDF+NMP), and mixed with MWCNTs. The surface morphology of the printed films was examined using an optical microscope and a scanning electron microscope, and their electrical properties are investigated using an I-V sourcemeter. Finally, sensing properties of MWCNT printed films were measured according to changes in the concentration of the chemical under the various applied voltages. In conclusion, the MWCNT printed films made of (SBR+CMC) were found to be feasible for application to the detection of hazardous and noxious chemicals spilled in seawater.

Process Risk Assessment for a Batch Condensation Reaction of Polyester Resin using K-PSR Technique (K-PSR 기법을 활용한 회분식 폴리에스터 축합반응에서의 공정 위험성 평가 연구)

  • Park, Kyung-Min;Lee, Dong-Kyu;Lee, Haakil;Lee, Joon-Man;Ahn, Won-Sool
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.3
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    • pp.35-42
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    • 2019
  • Risk assessment and analysis for a medium-to-small sized chemical plant that manufactures a polyester resin by the process of batch-type condensation reaction was conducted using K-PSR technique which is one of the risk assessment methods used to implement the Process Safety Management System (PSM). K-PSR is a risk assessment technique developed by KOSHA to compensate for difficulties caused by the lack of infrastructure of medium-to-small sized chemical plants in the re-evaluation. To apply the K-PSR technique, the entire process of a selected chemical palnt was classified in two review sections, i.e., the condensation reaction process and the dilution/filtration process, and the potential risks of the process about these review sections were identified and classified based on the four guide-words (release, fire.explosion, process trouble, and injury). As the results of the research, refer to recommend of risk rating has been confirmed that non-destructive testing of old facilities and the preparation of LOTO procedures for the electrical equipments are necessary as specific measures to prevent the risk of release and fire.explosion. It was also shown that pressure gauges and thermometers should be installed on the hot-oil supply piping to minimize the process trouble, and exhausting hood should be installed to prevent potential injury.

Discussions on Pesticides Production and Supply in Korea (농약의 생산과 소비의 실태에 관한 고찰)

  • Bai Dai Han
    • Korean journal of applied entomology
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    • v.17 no.2 s.35
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    • pp.115-123
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    • 1978
  • Present status on the pesticides production, supply, manufacture and pests control in Korea are summarized. The data in the past several years (1971-76) are analyzed to find out the problems and solutions for the further development of plant protection and pesticide industry in Korea. Since the acreages of crop plantation and the quantities of pesticides uses are already near to the stage of plateau, pesticide formulation with imported technical grade should be modified by local synthesis with imported quality. The government pesticides management act and regulations must be modernized urgently in connection with the synthesis. formulation, tests, registration, quality control. price and supply system as well as the safety use of pesticides. Recommendation concerning acceptable daily intakes(ADI) and residue limits must be established for the strengthning pesticide safety use and plant protection activities as soon as possible. The use of fungicide-insectide mixture in dust formulation must be authorized and practiced immediately for the labor saving and one-hit cooperative mass control of rice disease and insect pests, especially. At present, serious considerations on pesticide safety use and integrated pest control are strongly urged to help the farmers, to save the industries and to keep the nature as it is required.

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The Environmental Impact Quotient on Fruit and Vegetables Pesticides in Korea (국내 과채류에 등록된 농약에 대한 환경영향지수)

  • Oh, Kyeong-Seok;Lee, Byung-Moo;Sung, Ha-Jung;Oh, Hong-Gyu;Ihm, Yang-Bin;Kyung, Kee-Sung
    • The Korean Journal of Pesticide Science
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    • v.7 no.2
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    • pp.123-130
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    • 2003
  • The Environmental Impact Quotient(EIQ) has been used to organize the extensive toxicological and soil residue data available on some fruit vegetables pesticides into a usable form for field use. It addresses a majority of the environmental concerns that are encountered in agricultural systems including farm worker, consumer, ecological and environmental safety. The EIQ made use of the rating system by using the EIQ equation. The EIQ of pesticides registered for oriental melon was higher than that of other in terms of farm worker, consumer and environmental safety. Pesticides registered for red pepper showed highest EIQ in ecosystem. The EIQ decreased in order of insecticide> fungicide> herbicide> plant growth regulator. The environment Impact Quotient for the pesticides registered in fruit and vegetables decrease gradually.

Analysis of Occurrence Type of Physiological Disorder to Soil Chemical Components in Ginseng Cultivated Field (인삼 재배지의 토양 화학성에 따른 생리장해 유형 분석)

  • Hyun, Dong-Yun;Yeon, Byeong-Yeol;Lee, Seong-Woo;Kang, Seung-Weon;Hyeon, Geun-Soo;Kim, Young-Cheol;Lee, Kwang-Won;Kim, Seong-Min
    • Korean Journal of Medicinal Crop Science
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    • v.17 no.6
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    • pp.439-444
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    • 2009
  • This study was to set the guidelines of soil chemical components in order to assure the safety and quality of the panax ginseng from physiological disorder. The disorder symptoms appeared on the leaf with yellow spot, atrophy, yellow-brown spot, also showed red skin and rough skin of the root. Occurrence type of physiological disorder in cultivated field divided into two types : type I 'such as, yellow spot' consist of single disorder symptom; type II 'such as, yellow spot and yellow-brown spot' consist of two or more different disorder symptoms. The individual contribution of soil properties to the occurrence type was as follows ; The yellow spot was affected by Na > $NO_3$-N > salinity (EC) in soil. The same results was observed in red skin. Atrophy was affected by $NO_3$-N > salinity (EC) > Ca > Mg. Rough skin was affected by $P_2O_5$>pH>Organic material > K. It showed positive associated to $P_2O_5$, pH and K, but negative associated to organic matter. Simultaneous occurrence of two different disorder, including cases which yellow spot and yellow-brown spot, those were affected by $NO_3$-N > salinity (EC) > Na > Mg. In the case of atrophy plus yellow-brown spot, those also were affected by in the order : $NO_3$-N > salinity (EC) > Ca > Mg > Na. Red-rough skin was affected in the order : salinity (EC) > $NO_3$-N > K > Na. Soil chemical components appear to be related to occurrence of physiological disorder, particularly in salinity (EC) and $NO_3$-N. The salinity (EC) and $NO_3$-N were negative related to plant growth. In addition, exchangeable cation capacity play critical roles in attributing to complex occurrence of physiological disorder.

An Evaluation of the Fire and Explosion Effect by BTX released in a Chemical Plant (화학공장에서의 BTX누출에 의한 화재$\cdot$폭발 영향 평가)

  • Park Ki-Chang;Kim Byung-Jick
    • Journal of the Korean Institute of Gas
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    • v.4 no.3 s.11
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    • pp.9-18
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    • 2000
  • Accident analysis are useful in the design stage of chemical plants and their surrounding structures. Also, analysis results are required for safety management of existing plants. In this paper, the fire and explosion effect by BTX released was evaluated. The computer program was prepared for accident analysis and adopted for evaluating the magnitude of fire (pool fire) and explosion (UVCE) effect. The thermal radiation was used as a measure of fire magnitude and the overpressure as a measure of explosion magnitude. And probit analysis was made for each case. As a case study, benzene tank model was used. The simulation results of explosion of benzene showed that the damage within 20 meters from the accident spot was severe and the damage beyond 60 meters was negligible. The simulation results of fire of benzene showed that the damage in summer is bigger than that in winter. And the damage of city located inland seems to be bigger than that of city in seaside. And thermal radiation effects was negligible beyond 40 meters-distance from the accident spot.

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Assessment of Heavy Metal(loid)s Pollution in Arable Soils near Industrial Complex in Gyeongsang Provinces of South Korea

  • Kim, Yong Gyun;Lee, Hyun Ho;Park, Hye Jin;Hong, Chang Oh
    • Korean Journal of Soil Science and Fertilizer
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    • v.51 no.2
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    • pp.128-141
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    • 2018
  • Industrial complex releasing huge amounts of dusts, fumes and wastewater containing heavy metal(loid)s could be a source of heavy metal(loid)s pollution in arable soil. Heavy metal(loid)s pollution in arable soil adversely affect crops safety, subsequently human being. Hence, it is important to accurately assess the heavy metal(loid)s pollution in soil using pollution indices. The objectives of this study are 1) to compare assessment methods of heavy metal(loid)s pollution in arable soils located near industrial complex in Gyeongsang provinces and 2) to determine the relationship between concentration of plant available heavy metal(loid)s and chemical properties of soil. Soil samples were collected from 85 sites of arable lands nearby 10 industrial complex in Gyeongsang provinces. The average total concentration of all heavy metal(loid)s of the studied soils was higher than that of Korean arable soils but did not exceed the warning criteria established by the Soil Environmental Conservation Act of Korea. Only six sites of arable soils for the total concentration of As, Cu and Ni exceeded the warning criteria (As: $25mg\;kg^{-1}$, Cu: $150mg\;kg^{-1}$, Ni: $100mg\;kg^{-1}$). The contamination factor (CF) and geoaccumulation index ($I_{geo}$) of the heavy metal(loid)s in arable soils varied among the sampling sites, and the average values of As and Cd were relatively higher than that of other metals. Results of integrated indices of As and Cd in arable soils located near industrial complex indicated that some arable soils were moderately or heavily polluted. The plant available concentration of heavy metal(loid)s was negatively related to the soil pH and negative charge of soil. Available Cd, Pb, and Zn concentrations had relatively high correlation coefficient with pH and negative charge of soil when compared with other heavy metal(loid)s. Based on the above results, it might be a good soil management to control pH with soil amendments such as lime and compost to reduce phytoavailability of heavy metal(loid)s in arable soil located near industrial complex.

Evaluation of Low Toxic and Residual Toxicity of Pesticides Registrated on Sweet Pepper Greenhouse to Orius strigicollis (으뜸애꽃노린재 성충에 대한 착색단고추에 등록된 농약의 저독성 및 잔류독성 평가)

  • Choi, Byeong-Ryeol;Park, Hyung-Man;Kim, Jeong-Hwan;Lee, Si-Woo
    • Korean journal of applied entomology
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    • v.46 no.3
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    • pp.415-423
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    • 2007
  • For the development of integrated pest management system by harmonizing biological and chemical control, some experiments were carried out to select low toxic pesticides and to evaluate residual toxicity to natural enemies. Leaf dipping method and body dipping method were set up for evaluating toxicity to minute pirate bug, Orius strigicollis adult. We had tested 52 kinds of pesticides (33 insecticides, 19 fungicides) commonly used to control greenhouse insects, mites, and disease pests to natural enemies at the recommended concentration. Fourteen insecticides by body dipping method, 12 insecticides by leaf dipping method and 19 fungicides were selected as low toxic pesticides to O. strigicollis adult. After insecticide spraying at recommending dose on the sweet pepper plant, we examined residual effect of insecticides by introducing natural enemies on different days. Safety interval for introduction of O. strigicollis adult was established according to residual toxicity of pesticides. Safety insecticides at one day after treatment were pyraclofos, methomyl, thiodicarb, esfenvalerate bifenthrin, alpha-cypermethrin, etofenprox, fenvalerate, imidacloprid, acetamiprid, abamectin, emamectin benzoate, spinosad, indoxacarb. However, residual toxicity of nee-nicotinoids last up to 21 days to O. strigicollis adults.

Design and Implementation of an HNS Accident Tracking System for Rapid Decision Making (신속한 의사결정을 위한 HNS 사고이력관리시스템 설계 및 구현)

  • Jang, Ha-Lyong;Ha, Min-Jae;Jang, Ha-Seek;Yun, Jong-Hwui;Lee, Eun-Bang;Lee, Moon-jin
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.23 no.2
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    • pp.168-176
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    • 2017
  • HNS accidents involve large-scale fires and explosions, causing numerous human casualties and extreme environmental pollution in the surrounding area. The widespread diffusion of effects should be prevented through rapid decision making. In this study, a high-quality, standardized, and digitized HNS accident databases has been generated based on the HNS standard code proposed. Furthermore, the HNS Accident Tracking System (HATS) was applied and implemented to allow for systematic integration management and sharing. In addition, statistical analysis was performed on 76 cases of domestic HNS accident data collected over 23 years using HATS. In Korea, an average of 3.3 HNS accidents occurred each year and major HNS accident factors were Springs (41 %), Aprons (51 %), Chemical Carriers (49 %), Crew's Fault (45 %) and Xylenes (12 %). (The number in parentheses is the percentage of HNS accident factors for each HNS accident classification)