• Title/Summary/Keyword: Chemical Erosion

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Assessment of Mass Fraction and Melting Temperature for the Application of Limestone Concrete and Siliceous Concrete to Nuclear Reactor Basemat Considering Molten Coree-Concrete Interaction

  • Lee, Hojae;Cho, Jae-Leon;Yoon, Eui-Sik;Cho, Myungsug;Kim, Do-Gyeum
    • Nuclear Engineering and Technology
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    • v.48 no.2
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    • pp.448-456
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    • 2016
  • Severe accident scenarios in nuclear reactors, such as nuclear meltdown, reveal that an extremely hot molten core may fall into the nuclear reactor cavity and seriously affect the safety of the nuclear containment vessel due to the chain reaction caused by the reaction between the molten core and concrete. This paper reports on research focused on the type and amount of vapor produced during the reaction between a high-temperature molten core and concrete, as well as on the erosion rate of concrete and the heat transfer characteristics at its vicinity. This study identifies themass fraction and melting temperature as the most influential properties of concrete necessary for a safety analysis conducted in relation to the thermal interaction between the molten core and the basemat concrete. The types of concrete that are actually used in nuclear reactor cavities were investigated. The $H_2O$ content in concrete required for the computation of the relative amount of gases generated by the chemical reaction of the vapor, the quantity of $CO_2$ necessary for computing the cooling speed of the molten core, and the melting temperature of concrete are evaluated experimentally for the molten core-concrete interaction analysis.

Pad Surface Characteristics and their Effect on Within Wafer Non-Uniformity in Chemical Mechanical Polishing (화학 기계적 연마에서 패드표면 특성이 웨이퍼 불균일도에 미치는 영향)

  • Jeong, Suk-Hoon;Lee, Hyun-Seop;Jeong, Moon-Ki;Shin, Woon-Ki;Lee, Sang-Jik;Park, Boum-Young;Kim, Hyoung-Jae;Jeong, Hae-Do
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.58-58
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    • 2009
  • Uniformity related issues in chemical mechanical polishing (CMP) are within wafer non-uniformity (WIWNU), wafer to wafer non-uniformity (WTWNU), planarity and dishing/erosion. Here, the WIWNU that originates from spatial distribution of independent variables such as temperature, sliding distance, down force and material removal rate (MRR) during CMP, relies to spatial dependency. Among various sources of spatial irregularity, hardness and modulus of pad and surface roughness in sources for pad uniformity are great, especially. So, we investigated the spatial variation of pad surface characteristics using pad measuring system (PMS) and roughness measuring system. Reduced peak height ($R_{pk}$) of roughness parameter shows a strong correlation with the removal rate, and the distribution of relative sliding distance onwafer during polishing has an effect on the variation of $R_{pk}$ and WIWNU. Also, the results of pad wear profile thorough developed pad profiler well coincides with the kinematical simulation of conditioning, and it can contribute for the enhancement of WIWNU in CMP process.

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Estimation of Nitrate Leaching Rates for a Small Rural Watershed Using a Distributed Watershed Model (분포형 유역모델을 이용한 농촌지역 소유역의 질산성 질소 지하침출량 평가)

  • Park, Min-Hye;Park, Sunhwa;Kim, Hyun-Koo;Hwang, Jong-Yeon;Kim, Tae-seung;Chung, Hyen Mi;Cho, Hong-Lae;Lee, Taehwan;Koo, Bhon K.;Park, Yun Hee
    • Journal of Korean Society on Water Environment
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    • v.33 no.6
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    • pp.661-669
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    • 2017
  • A distributed watershed model CAMEL (Chemicals, Agricultural Management and Erosion Losses) was applied to a small rural watershed where intensive livestock farming sites are located to estimate nitrate leaching rates from soil to groundwater. The model was calibrated against the stream flows, and T-N and $NO_3-N$ concentrations were observed at the watershed outlet for three rainfall events in 2014. The simulation results showed good agreement with the observed stream flows ($R^2=0.67{\sim}0.93$), T-N concentrations ($R^2=0.40{\sim}0.58$) and $NO_3-N$ concentrations ($R^2=0.43{\sim}0.65$). The estimated annual nitrate leaching rate of the watershed was 33.0 kg N/ha/yr. The contributing proportions of individual activities to the total nitrate leaching rate of the watershed were estimated for livestock farming, applications of chemical fertilizer, and manure. The simulation results showed that the highest contributor to the nitrate leaching rate of the watershed was chemical fertilizer applications. The simulation period was for one year only, however, and results may vary depending on different conditions. Gathering input data over a longer period of time and monitoring data for calibration is needed. When this has been accomplished, it is expected that this model can be applied to small rural watersheds for evaluating temporal and spatial variations of nitrogen transformations and transport processes.

Effect of Swine Liquid Manure and Phosphorus Application on Chemical Properties and Microbial Population of Italian (제주화산회토지역에서 돈분액비와 인산시용이 이탈리안 라이그라스 재배 토양의 화학적 특성 및 미생물상에 미치는 영향)

  • 김문철;현해남;최대진;문봉춘;고용구;강태숙
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.21 no.4
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    • pp.181-190
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    • 2001
  • This study was conducted to investigate the effect of swine liquid manure(SLM) and phosphorus fertilizer from September, 1998 to July, 1999 on the soil fertility on Italian ryegrass field, Cheju volcanic ash soil. pH(lst investigated), Mg (2nd investigated) and Cu content (2nd investigated) on soil grown by Italian ryegrass were significantly increased by an increase of fertilizer P(P

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A Capillary Electrochromatographic Microchip Packed with Self-Assembly Colloidal Carboxylic Silica Beads

  • Jeon, In-Sun;Kim, Shin-Seon;Park, Jong-Man
    • Bulletin of the Korean Chemical Society
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    • v.33 no.4
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    • pp.1135-1140
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    • 2012
  • An electrochromatographic microchip with carboxyl-group-derivatized mono-disperse silica packing was prepared from the corresponding colloidal silica solution by utilizing capillary action and self-assembly behavior. The silica beads in water were primed by the capillary action toward the ends of cross-patterned microchannel on a cyclic olefinic copolymer (COC) substrate. Slow evaporation of water at the front of packing promoted the self-assembled packing of the beads. After thermally binding a cover plate on the chip substrate, reservoirs for sample solutions were fabricated at the ends of the microchannel. The packing at the entrances of the microchannel was silver coated to fix utilizing an electroless silver-plating technique to prevent the erosion of the packed structure caused by the sudden switching of a high voltage DC power source. The electrochromatographic behavior of the microchip was explored and compared to that of the microchip with bare silica packing in basic borate buffer. Electrophoretic migration of Rhodamine B was dominant in the microchip with the carboxyl-derivatized silica packing that resulted in a migration approximated twice as fast, while the reversible adsorption was dominant in the bare silica-packed microchip. Not only the faster migration rates of the negatively charged FITC-derivatives of amino acids but also the different migration due to the charge interaction at the packing surface were observed. The electrochromatographic characteristics were studied in detail and compared with those of the bare silica packed microchip in terms of the packing material, the separation potential, pH of the running buffer, and also the separation channel length.

Blockfields of Seoraksan National Park: Age and Origin (설악산 국립공원 지역 아고산대의 암괴원의 기원과 연대에 관한 고찰)

  • Kyeong Park
    • Journal of the Korean Geographical Society
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    • v.38 no.6
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    • pp.922-934
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    • 2003
  • On top of several peaks of Seoraksan National Park. many extensive blockfields are found. After initial report was made in year 2000, further field work and analysis of satellite image have been made. Blockfields on top of mountain peaks exhibit evidence of chemical weathering including gnammas and grooves. Also, several lichen colonies larger than 80 cm in diameter have been found on the surface of many blocks. High resolution IKONOS image has been used to delineate the boundary of blockfields which are hard to access during the field trip. Blockfields of Mt. Seoraksan lack fine material necessary for age dating and clay mineral analysis because they experienced long period of wash and erosion during the Holocene. The ages of blockfields seem to be pre-Holocene on the basis of size of lichen colony and weathering pits.

Effects of Acid Treatment of SAPO-34 on the Catalytic Lifetime and Light Olefin Selectivity during DTO Reaction (DTO 반응에서 촉매수명과 경질 올레핀 선택도에 미치는 SAPO-34의 산 처리 효과)

  • Choi, Ki-Hwan;Lee, Dong-Hee;Kim, Hyo-Sub;Park, Chu-Sik;Kim, Young-Ho
    • Applied Chemistry for Engineering
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    • v.26 no.2
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    • pp.217-223
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    • 2015
  • Effects of the post-acid treatment of SAPO-34 sample by hydrochloric acid were investigated to enhance the catalytic performance in DTO reaction. Uniformly sized SAPO-34 samples with cubic-like morphology were prepared by hydrothermal method using TEAOH and DEA as the structure directing agents. It was modified in terms of the HCl concentration and treating time. As a result, the total surface area and micropore volume for the well modified samples increased and the total acid site was somewhat decreased along with the erosion of the external surface. Especially, the catalytic lifetime and light olefins selectivity for acid treated SAPO-0.2 M (3 h) samples were considerably enhanced compared with those of untreated SAPO-34 samples. It indicates that the deactivation by coke formation proceeds mainly at the pore entrance on the external surface. Therefore, the acid treatment was confirmed to be a simple method which can significantly improve the catalytic performance by modifying the external surface of SAPO-34 catalyst.

Weathering Properties and Slope Stability Evaluations of Bedrock under the Chokseongnu Pavilion, Jinjuseong Fortress, Korea (진주성 촉석루 성곽지반의 풍화특성과 사면안정성 평가)

  • Jo, Young-Hoon;Lee, Myeong-Seong;Lee, Sun-Myung;Lee, Chan-Hee
    • Journal of Conservation Science
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    • v.20
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    • pp.89-103
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    • 2007
  • The bedrock beneath the Chokseongnu pavilion consists of sandstone with alternate dark-gray to light-brown siltstone and dark-gray shale of the Jinju Formation, where bedding is well developed toward the Chokseongmun gate. Large to small joints and overbreak from the erosion weathering have been developed in the bedrock. Besides, water leakage from development of discontinuity planes, fragmentation of shale, crack and joint by tree roots are observed on the bedrock. While shale and siltstone showed high sensitivity in physical and chemical weathering, respectively, sandstone indicated the highest weathering sensitivity in both. As the results of structural stability analysis, the whole bedrock has high instability in wedge failures, and especially section No. II slope is more instable than section No. I. Therefore, it is necessary for the bedrock to be strengthened by improvement method for soft foundations and the surface reinforcement. The trees causing mechanical collapse of the bedrock should be also removed and a water flow prevention measure or a water exhaust are required.

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Enhancement of the Life of Refractories through the Operational Experience of Plasma Torch Melter (플라즈마토치 용융로 운전경험을 통한 내화물 수명 증진 방안)

  • Moon, Young Pyo;Choi, Jang Young
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.14 no.2
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    • pp.169-178
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    • 2016
  • The properties of wastes for melting need to be considered to minimize the maintenance of refractory and to discharge the molten slags smoothly from a plasma torch melter. When the nonflammable wastes from nuclear facilities such as concrete debris, glass, sand, etc., are melted, they become acid slags with low basicity since the chemical composition has much more acid oxides than basic oxides. A molten slag does not have good characteristics of discharge and is mainly responsible for the refractory erosion due to its low liquidity. In case of a stationary plasma torch melter with a slant tapping port on the wall, a fixed amount of molten slags remains inside of tapping hole as well as the melter inside after tapping out. Nonmetallic slags keep the temperature higher than melting point of metal because metallic slags located on the bottom of melter by specific gravity difference are simultaneously melted when dual mode plasma torch operates in transferred mode. In order to minimize the refractory erosion, the compatible refractories are selected considering the temperature inside the melter and the melting behavior of slags whether to contact or noncontact with molten slags. An acidic refractory shall not be installed in adjacent to a basic refractory for the resistibility against corrosion.

A Study on the Ecological Restoration Strategies for the Disturbed Landscapes (경관훼손지의 생태적 복구방안에 관한 연구)

  • Kim, Nam-Choon
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.1 no.1
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    • pp.28-44
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    • 1998
  • This study was conducted to suggest the ecological restoration strategies for the disturbed landscapes by theoretical study. Especially, it is aimed to suggest three objectives for restoration by using native plants ; (1) prevention or reduction of wind and water erosion, (2) provision of food and cover for variety of animal species, (3) improvement of the visual or aesthetic quality of disturbed sites. The main results were summarized as follows. 1. Cooperation between restoration ecologists and restoration practitioners is needed to delineate a scientific approach to restoration ; (1) Being aware of published literature that describes similar work and/or establish general principles. (2) Preparedness to carry out proper experiments to test ideas. (3) Preparedness to monitor fundamental parameters in a restoration scheme. (4) Providing information about the behavior of species. (5) Publish results. 2. There are three models of succession in theories of plant succession. The tolerance and facilitation models were recommended to ecological restoration. The inhibition model applies in most secondary succession, but the actual species which are introduced first may inhibit the germination and growth of slower-growing species, or they may prevent the growth of other species whose propagules arrive later. 3. The objectives of erosion control, wildlife habitat provision, and visual quality improvement are not mutually exclusive. However, many revegetation practices in the past have emphasized one of these aspects at the expense of the others. 4. A native plant community can be the model of ecological restoration. By stylization/abstraction of native plant community, trying to learn the most essential characteristics of community types - environmental factors ; dominant, prevalent, and "visual essence" species composition - in order to use such information in restoration. 5. After developing mass/spaces plan, match plant communities to the mass/space plan. In utilizing community grouping, there needs aesthetic ability to understand design elements. 6. Several hydrophytes such as Pennisetum saccharifluous, Themeda triandra, Cirsium pendulum show relatively good germination rates. In case of mesophytes and xerophytes, Arundinella hina, Artemisia princeps, Oenothera odorata and legumes seem to have quick-germinating abilities at barren sites. Pinus thunbergii, Rhus chinensis, Evodia daniellii, Alnus firma and Albizzia julibrissin can be considered as "late succession" woody plants because they show low germinating rates and slow growing habitat. 7. The seeds used for restoration should be collected within a certain radius of where it will be planted. Consideration in genetic issues in the collection and use of germplasm can increase the odds for successful restoration efforts. 8. The useful model in the "drift" pattern occurs so abundantly in naturally evolving landscapes. As one species diminishes in density, a second or third species are increased. Thus, dynamic interactions between species are created. Careful using of "drift phenomenon" in planting was recommended. 9. Virtually no stand of vegetation today is immune from the introduction and/or spreading of exotic species. Therefore, the perpetuation of a restored sites requires conscious monitoring and management. Thus, management would be the most important process in ecological restoration. 10. In order to keep the sites "natural", alternative management strategies would be applied in management ; Atenative management strategies are decelerating successional process, accelerating successional processes or modifying species composition. As management tools, mechanical, chemical, biological or environmental factor manipulation, e.g., fire could be used.

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