• Title/Summary/Keyword: Chemical Engineering

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Isolation and Synthesis of Tryptamine Derivatives from a Symbiotic Bacterium Xenorhabdus nematophilus PC

  • Paik, Seung-Uk;Park, Myung-Kwang;Jhun, Seong-Hoon;Park, Heai-Ku;Lee, Chun-Soo;Cho, Bum-Rae;Byun, Hong-Sik;Choe, Seok-Burm;Suh, Seong-Il
    • Bulletin of the Korean Chemical Society
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    • v.24 no.5
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    • pp.623-626
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    • 2003
  • Nematophin and its analog incorporating tryptamine unit have been isolated and characterized from strain XRPC of a symbiotic bacterium Xenorhabdus nematophilus, which was newly isolated from Korean entomopathogenic nematodes. The stereoselective synthesis of these compounds was accomplished, and the relative configurations were determined. Nematophin exhibited potent antibacterial activities over several strains of methicillin-resistant S. aureus (MRSA) comparable to those of vancomycin.

Improved performance of polyamide nanofiltration membranes by incorporating reduced glutathione during interfacial polymerization

  • Jiao, Zhiwei;Zhou, Linjie;Wu, Mengyuan;Gao, Kang;Su, Yanlei;Jiang, Zhongyi
    • Korean Journal of Chemical Engineering
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    • v.35 no.12
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    • pp.2487-2495
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    • 2018
  • Inspired by the specific amino acid sequence Asn-Pro-Ala (NPA) of water channel aquaporins (AQPs), we fabricated polyamide (PA) nanofiltration (NF) membranes by introducing reduced glutathione (GSH) in interfacial polymerization (IP) method. Fourier transform infrared spectroscopy (ATR-FTIR), X-ray photoelectron spectrometry (XPS), scanning electron microscope (SEM), atomic force microscopy (AFM), zeta potential and static water contact angle measurement were employed to characterize the chemical composition, morphology, electronegativity and hydrophilicity of the NF membranes. The water flux of GSH/PIP-TMC NF membrane reached $32.00L\;m^{-2}h^{-1}$ at 0.2 MPa, which was approximately twice than that of pristine PIP-TMC NF membrane when the ratio of GHS to piperazidine (PIP) was 40% during IP process. More water channels were built as GSH was embedded into PA layer. The fabricated NF membranes also took on potent rejection for dyes and $Na_2SO_4$. This study presents a simple and facile method to simulate water channels-based biological materials which may find potential application in water treatment.

Effect of Thermal Treatment on the Performance and Nanostructures in Polymer Solar Cells with PTB7-Th:PC71BM Bulk Heterojunction Layers

  • Lee, Sooyong;Seo, Jooyeok;Jeong, Jaehoon;Lee, Chulyeon;Song, Myeonghun;Kim, Hwajeong;Kim, Youngkyoo
    • Current Photovoltaic Research
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    • v.5 no.3
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    • pp.69-74
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    • 2017
  • Here we report the influence of thermal treatment on the performance of high efficiency polymer solar cells with the bulk heterojunction films of poly[4,8-bis(5-(2-ethylhexyl)thiophen-2-yl)benzo[1,2-b:4,5-b'] dithiophene-alt-3-fluorothieno[3,4-b]thiophene-2-carboxylate] (PTB7-Th) and [6,6]-phenyl $C_{71}$ butyric acid methyl ester ($PC_{71}BM$). The crystalline nanostructure of PTB7-Th:$PC_{71}BM$ layers, which were annealed at three different temperatures, was investigated by employing synchrotron radiation grazing incidence X-ray diffraction (GIXD) technique. Results showed that the device performance was slightly reduced by thermal annealing at $50^{\circ}C$ but became significantly poor by thermal annealing at $100^{\circ}C$. The poor device performance by thermal annealing was attributed to the collapse in the crystalline nanostructure of PTB7-Th in the PTB7-Th:$PC_{71}BM$ layers as evidenced by the GIXD measurements that exhibited huge reduction in the intensity of PTB7-Th (100) peak even at $50^{\circ}C$.