• Title/Summary/Keyword: Chemical Durability

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A Study on the Resistance of Chemical Attack for Cement Mortar (시멘트 모르터의 내약품성에 대한 고찰)

  • 문한영;김성수;유정훈;윤희경
    • Proceedings of the Korea Concrete Institute Conference
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    • 1996.10a
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    • pp.183-188
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    • 1996
  • The durability of concrete structures decrease due to deterioration of concrete when they are constructed in marine or pollutional environments. In this study, the mortar specimens made from the five different types of cement were immersed in artificial seawater and four kinds chemical solution, and were measured the change of compressive strength and weight. The results show that the longer the immersed days are, the more the compressive strength reduction is. It has been remarked that the resistance of slag cement and ground granulated blast-furnace slag is excellent in chemical attack.

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Glass Formation and Dissolution Characteristics of K2O-CaO-SiO2-P2O5 (K2O-CaO-SiO2-P2O5계 유리의 형성 및 용출특성)

  • Yoon Tae Min;Yoon Young Jin;Lee Yong Soo;Kang Won Ho
    • Korean Journal of Materials Research
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    • v.14 no.1
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    • pp.67-72
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    • 2004
  • The glass-forming conditions are investigated in the $K_2$O-CaO-$SiO_2$ $-P_2$$O_{5}$ system with 10~65 mole% of$ P_2$$O_{5}$. Thermal properties and dissolution properties were investigated according to variation of the SiO and KO contents in selected compositions. The glass formation condition was determined when $K_2$O/$P_2$$O_{5}$ mole ratio 0~0.24, $SiO_2$/($SiO_2$+$P_2$$O_{5}$ ) mole ratio 0~0.29, and CaO/$P_2$$O_{5}$ mole ratio 0~1.00. In the result of the thermal properties, the glass transition temperature($T_{g}$) and softening temperature($T_{s}$ ) were gradually shifted to the lower temperature range with increase of $K_2$O contents. The maximum value of the chemical durability was shown in $K_2$$PO_2$$O_{5}$ mole ratio 0.17 when the $SiO_2$ contents were changed, and $K_2$O was fixed at 10 mole%. Hence the change of the $K_2$O/$P_2$$O_{5}$ mole ratio was found that a new main factor of the chemical durability.

The Quality Properties of Mortar for Using Hydraulic Modification Sulfur as Admixture for Cement (개질유황을 시멘트 대체 혼화재로 사용하기 위한 모르타르의 품질특성)

  • Kim, Ki-Hyung;Shin, Do-Chul;Jung, Ho-Jin;Lee, Jae-Nam;Kim, Byiung-Kwon
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.6 no.2
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    • pp.81-88
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    • 2011
  • This study ascertained the possibility of use of sulfur abstracted from waste sulfur as a construction material through modification process and manufacturing high efficiency modification sulfur with superior quality on dispersibility and hydrophilic in normal temperature. Mechanic, behavior and chemical durability of mortar with added modification sulfur. The results of the study are as follows. The fluidity of mortar mixed with modification sulfur and compressive strength decreased as ratio of mixing of them increases. Flexural, tensile and bond strength of the mortar are also improved and shrinkage of it increases. Especially chemical durability of the mortar showed excellent resistance with the increase of ratio of mixing. Therefore this research has confirmed the modification sulfur can be used as a addmixture for cement.

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Thermal Durability of Neon Transformer with Diluent Mixing Ratio (증량제 혼합비율에 따른 네온변압기의 열내구성 평가)

  • Hong, In Kwon;Jeon, Gil Song;Lee, Seung Bum
    • Applied Chemistry for Engineering
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    • v.26 no.4
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    • pp.452-457
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    • 2015
  • The physical properties, such as the heat resistance and thermal durability of the temperature difference fatigue resistance should be excellent when preparing an epoxy type resin for a neon transformer housing. In this study, 50 wt% of $SiO_2$ and silica were selected as a reinforcement and diluent filler for epoxy type resins, respectively. Thermal conductivity and thermal stability were measured as the mixing ratio varied upon the particle sizes. The optimal amount of the mixed silica was 50 wt%. Thermal stability was improved with increasing the amount of larger silica particles. The optimal mixing ratio of differently sized silica particles was 28/3 : 14/18 : 8/10 mesh = 1 : 1 : 1. From these results, it is thought that neon transformer is producible which has excellent thermal durability.

An Experimental Study on the Durability Properties of Repair Mortar for Sewer Spread with Liquefied Antibiotic (액상 항균제를 도포한 하수시설용 단면복구재의 내구특성에 관한 실험적 연구)

  • Lee Dong-Heck;Jang Jae-bong;Na Chul-Sung;Cho Bong-Suk;Kim Jae-hwan;Kim Moo-Han
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2005.05a
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    • pp.211-214
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    • 2005
  • Recently, Deterioration of the concrete sewer concrete structures by biochemical corrosion has been issued and a development of the inhibition system of corrosion that has been demanded. The sulfuric acid may react with the hardened cement paste and originate expansive products which can induce swelling and breakless of concrete. Also, a sulphuric acid reacts with calcium hydroxide to from $CaSO_4\;\cdot\;2H_2O$. This reaction accounts for consumption of the calcium hydroxide present in hardened cement paste. In this study, To present from biochemical corrosion of the sewer repair mortar that was spread with liquefied antibiotic and then its experimental properties were experimentally investigated and to estimate the effect of absorbed condition of restorative mortar, the number of coating times and coating contents with antibiotic on the durability properties of restorative mortar spread with antibiotics. Also, testing items such as carbonation depth, choloride ion penetration depth and chemical resistance was tested to estimate the durability properties in third study. In results, the novellus bacillus inhabiting in sewer concrete structures was restrained by antibiotics developed in this study. And carbonation depth, choloride ion penetration depth and chemical resistance of restorative mortar spread with antibiotics was superior to that of plain mortar.

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A Study on Improvement of Chemical Durability in the $Na_2O$-CaO-$SiO_2$ System Glass ($Na_2O$-CaO-$SiO_2$ 계 유리의 내화학적 성질 향상에 관한 연구)

  • Kim, Jong-Ock;Park, Won-Kyu;Lim, Dae-Young;Kim, Moon-Ki
    • The Journal of Natural Sciences
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    • v.8 no.2
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    • pp.111-118
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    • 1996
  • In order to improve the chemical durability of glass in the $Na_2O$-CaO-$SiO_2$ system, it was investigated in the effect of $B_2O_3$ and ZnO addition and changing amount of each composition, $Na_2O$, $Al_2O_3$, $Li_2O$. In this minimize the change of softening point of glass was as follow.(wt%)$B_2O_3$:3.36%, ZnO:2.88%, $Na_2O$:9.93%, $Al_2O_3$, $Li_2O$:0.19%, $SiO_2$:70.56%, CaO:11.22%, $K_2O$:0.14%

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Engineering Properties of Self-healing Smart Grouting Method (자기치유 기능을 이용하는 SSG공법의 공학적 특성)

  • Moon, In-Jong;Kim, Byoung-Il;Heo, June;Choi, Yong-Sung;Choi, Yong-Ki
    • Journal of the Korean Geotechnical Society
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    • v.32 no.3
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    • pp.29-37
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    • 2016
  • SSG (self-healing smart grouting) method, which is developed recently, has the characteristics such as an improvement of durability and waterproofing, prevention of leaching and pollution. In this study, we performed several tests such as gel-time measurement, uniaxial compression test, permeability test, fish poison test and chemical resistance test to compare the engineering properties of SSG with the other chemical grouting method (LW, SGR). As results of tests, the SSG method has low possibility of groundwater and ground pollution caused by leaching, furthermore, it has advantages like long/short term waterproofing, strength and durability. Therefore the SSG method can be applicable in the fields as an alternative of existing chemical grouting methods with problems.

Environmental Impact Review and Improvement of Durability of Silicasol-cement Grout Material (실리카졸 약액의 환경영향성 검토 및 내구증진방안)

  • Lee, Byungho;Kim, Younghun;Chun, Byungsik
    • Journal of the Korean GEO-environmental Society
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    • v.11 no.12
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    • pp.13-18
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    • 2010
  • This study was made on the fact that the environmental impact and durability of the recently developed alkali silicasol chemical grout material. The grout material used for this study was designed to understand its environmental impact and durability through the SEM, chemical resistance test, leaching test, permeability test. In order to compare with the engineering characteristics regarding alkali silicasol grout material and sodium silicate grout material. As a result of SEM, the surface and internal tissues of alkali silicasol grout material could be identified to be denser than those of sodium silicate. As a result of leaching test the adaptability was identified as grout material as it had proved to be an ecological material owing to the total amount of the element to be leached being extremely little. As a result of permeability test it is judged that it is possible to apply the silicasol to the site in the place requiring the water cut-off as the silicasol.

Studies on AlF3-(Mg+Sr+Ba)F2-P2O5 Glasses III. Chemical Durability (AlF3-(Mg+Sr+Ba)F2-P2O5 유리에 관한 연구 제3보 : 화학적내구성)

  • 김정은;이종근
    • Journal of the Korean Ceramic Society
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    • v.24 no.4
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    • pp.321-328
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    • 1987
  • The chemical durability of six alumino fluorophosphate glass samples studied. The composition of glass varied with MgF2 content from 0 to 12.5wt% in 30AlF3-2MgF2-(50-x)MF2-10P2O5(M; Sr, Ba). Samples were maintained in distilled water at 95$^{\circ}C$ from 1 to 100hrs. Weight loss, pH change and leached elements of the solution, and IR transmittance of samples were measured and also their surfaces were observed by SEM. Chemical durabilities of these samples were increased with increasing MgF2 contents. The following various properties were increased rapidly up to 10 hours after that changed slowly. The sample after leached at 95$^{\circ}C$ during 100 hrs showed 0.5mg/$\textrm{cm}^2$ in weight loss. The pH of leached solution is 6.2 and concentration of Mg, Sr, and Ba element of that leached solution were 24,115 and 125 ppm, respectively. The infrared transmittance of leached sample decreased 7% compare to unleached one. And also SEM photomicrograph and EDS analysis showed that the corrosion of samples were decreased with respect to increasing MgF2 content.

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Quantitative Evaluation for Effectiveness of Consolidation Treatment by Using the Chemical of Ethyl Silicate Series for the Sandstone in Yeongyang (영양 사암을 대상으로 한 에틸실리케이트 계열 처리제의 강화효과 평가)

  • Lee, Jang-Jon;Han, Min-Su;Song, Chi-Young;Jun, Byung-Kyu;Do, Min-Hwan
    • 보존과학연구
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    • s.30
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    • pp.125-136
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    • 2009
  • Stone cultural heritages in Korea have a severe damages from chemical and biological weathering because most of them have been situated in outdoors without any suitable protection systems, and this in turn causes deformation and structural damage. To counteract these problems and increase durability, various kinds of conservation materials are used in the conservation and restoration treatments. However until now there are not many practical and technological experiments on this subject. This paper attempts quantitative evaluation of effectiveness about chemical of ethylsilicate based resin for sandstone in Yeongyang-gun. It takes a long time to evaluate durability and side effect after conservation materials treatment. So we use artificial weathering through freezing§ thawing experimental method. As a result of this experiment, porosity and absorptance increased, and elastic wave speed, elastic modules, unconfined compression strength and tensile strength decreased more than before. This study plans to make a scientific method study about weathering factor and mechanism, and to deduce correlation between artificial weathering and natural weathering.

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