• Title/Summary/Keyword: Chemical Durability

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Studies on AlF3-(Mg+Sr+Ba)F2-P2O5 Glasses I. Glass Forming Ranges of Fluorophosphate System and Its Various Properties (AlF3-(Mg+Sr+Ba)F2-P2O5계 유리에 관한 연구 I. 유리화 범위와 특성)

  • 김정은;이종근
    • Journal of the Korean Ceramic Society
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    • v.24 no.2
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    • pp.117-122
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    • 1987
  • Glass forming ranges in the AlF3-(Mg+Sr+Ba)F2-P2O5 system are studied and ultraviolet transmission, infrared transmission, coefficient of refractive index, thermal expansion coefficient, density and chemical durability of the glasses are determined. Glass forming range is restricted MgF2 0-10wt%, SrF2 10-50wt%, BaF2 10-40wt% in this system. While BaF2 is substituted by SrF2, density and refractive index are decreased, micro hardness and thermal expansion coefficient are increased according to the increasing of SrF2 at fixed MgF2 contents. These samples represent high transmittance(93%) from 400nm to 3800nm and chemical durability of these samples show less than 0.3mg/$\textrm{cm}^2$$.$hy by weightloss.

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Factors Effecting the Strength & Durability of Geopolymer Binder: A Review (지오폴리머의 강도와 내구성에 영향을 미치는 요인에 대한 고찰)

  • On, Jeong-Kwon;Kim, Gyu-Yong;Sasui, Sasui;Lee, Yae-Chan;Eu, Ha-Min
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.4
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    • pp.460-468
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    • 2021
  • Owing to the production of conventional concrete/cement, the climate crises is increasing and is mainly caused greenhouse gas (GHG) emission into the environment by industrial process. To reduce the emission of GHG, and excessive consumption of energy, research on geopolymer binder is increasing as it is environmentally friendly compared to the conventional binders such as Portland cement. The research on improving the strength and durability of geopolymer cement becomes one of the trending researches. Generally, the strength and durability of geopolymer binders are improved by altering alkaline solution & its concentration, the precursor materials and curing temperature & time, which significantly influence the chemical composition and microstructure of geopolymer to which the strength and durability of geopolymers relies. This paper included the detailed discussion on the factors affecting the mechanical properties and durability of geopolymer binder and the influence of reaction mechanism on the strength and durability of geopolymer is also discussed in this paper.

Evaluation of Durability of Cement Matrix Replaced with Limestone Powder (석회석 미분말을 혼합한 시멘트 경화체의 내구성능 평가)

  • Woo-Sik Jang;Kwang-Pil Park
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.12 no.1
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    • pp.102-109
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    • 2024
  • In order to use limestone powder as a material for concrete, the mechanical and durability characteristics of cement matrices manufactured by varying the substitution rate were evaluated. In general, limestone powder did not contribute to the cement hydration reaction, so as a result of the compressive strength test of cement mortar using it, the compressive strength decreased as the substitution rate increased. However, as a result of evaluating the durability performance of cement mortar using limestone powder, such as chloride ion penetration resistance, carbonation resistance, and chemical attack resistance, small particles of limestone powder showed superior results compared to the unsubstituted control mortar due to the micro-filler effect of filling the fine pores inside the cement matrix. Therefore, limestone powder is expected to be used as an effective method for improving the durability of concrete. In this study, the durability was evaluated by changing the mixing amount of limestone powder to 0 %, 5 %, 10 %, and 15 %, but it is judged that it is necessary to study in more detail the effect on the durability by changing the end and mixing amount of limestone powder to various levels in the future.

Durability characteristics of recycled aggregate concrete

  • Saravanakumar, Palaniraj;Dhinakaran, Govindasamy
    • Structural Engineering and Mechanics
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    • v.47 no.5
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    • pp.701-711
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    • 2013
  • People started to replace natural aggregate with recycled aggregate for a number of years due to disposal problem and certain other potential benefits. Though there are number of drawbacks with use of recycled aggregates like lesser modulus of elasticity, low compressive strength, increase in shrinkage, there are results of earlier studies that use of chemical and mineral admixtures improves the strength and durability of recycled concrete. The use of recycled aggregate from construction and demolition wastes is showing prospective application in construction as alternative to natural aggregates. It conserves lot of natural resources and reduces the space required for the landfill disposal. In the present research work, the effect of recycled aggregate on strength and durability aspects of concrete is studied. Grade of concrete chosen for the present work is M50 (with a characteristic compressive strength of 50 MPa). The recycled aggregates were collected from demolished structure with 20 years of age. Natural Aggregate (NA) was replaced with Recycled Aggregate (RA) in different percentages such as 25, 50 and 100 to understand its effect. The experiments were conducted for different ages of concrete such as 7, 14, 28, 56 days to assess the compressive and tensile strength. Durability characteristics of recycled aggregate concrete were studied with Rapid chloride penetration test (as per ASTMC1202), sorptivity test and acid test to assess resistance against chloride ion penetration, capillary suction and chemical attack respectively. Mix design for 50 MPa gives around 35 MPa after replacing natural aggregate with recycled aggregate in concrete mix and the chloride penetration range also lies in moderate limit. Hence it is understood from the results that replacement of NA with RA is very much possible and will be ecofriendly.

Durability of Photocatalytic Cement after Nitric Oxide-Wet-Dry Cycling

  • Lee, Bo Yeon;Kurtis, Kimberly E.
    • Journal of the Korea Institute of Building Construction
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    • v.14 no.4
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    • pp.359-368
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    • 2014
  • Photocatalytic cement has been receiving attention due to its high oxidation power that reduces nitrogen oxide, thus contributing to a clean atmospheric environment. However, there has not yet been a thorough investigation on the effect of photocatalytic reactions on the durability of cementitious material, the parent material. In this study, photocatalytic cement samples were exposed to nitric oxide gas and UV along with cycles of wetting and drying to simulate environmental conditions. The surface of samples was characterized mechanically, chemically, and visually during the cycling. The results indicate that that the photocatalytic efficiency decreased with continued NO oxidation. The pits found from SEM indicated that chemical deterioration, such as acid attack or leaching, did occur. However, this was not confirmed by X-ray diffraction. The hardness was not affected, probably due to the formation of CSH as evidenced by the XRD pattern. In conclusion, it was found that photocatalysis could alter cementitious materials both chemically and mechanically, which could further affect long-term durability.

UNIFICATION OF THERMO-PHYSICS OF MATERIALS AND MECHANICS OF STRUCTURES - TOWARD A LIFE SPAN SIMULATOR OF STRUCTURAL CONCRETE -

  • Maekawa, K.;Ishida, T.
    • Proceedings of the Korea Concrete Institute Conference
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    • 1999.10a
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    • pp.29-46
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    • 1999
  • The performance based design obligates quantitative assessment of required performances by means of transparent and objective science. In this design scheme, simulation of both macro and micro-scale structural behaviors is thought to be a powerful tool. This paper proposes a way how to unify the structural safety and serviceability check method and durability assessment of RC structures. Though component chemical-physical processes are crudely assumed, system dynamics of micro-scale pore structure formation and macro-scale defects and deformation of structures was shown as possible and promising approach in future. The authors understand that the unification of structural and durability design has just started. For further progress and development, predictive tool of structural behaviors from birth to death of concrete under any specified environment and load serves as an essential technicality.

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A Study on the Concrete Surface of Durability Advancement and Performance Improvement for the Siliceous Liguid Type of Spread Waterproofing Material (콘크리트 표층부 내구성 증진 및 성능개선을 위한 규산질계 액상형 도포 방수재의 성능 평가 연구)

  • Kim Jin-Sung;Song Je-Young;Park Jin-Sang;Oh Sang-Keun
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2005.05a
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    • pp.29-32
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    • 2005
  • It is recognised that a permeability waterproof agent have been extensively used for concrete, in these days. In present paper shows effective practical scheme of a permeability waterproof agent in construction market that is to develope durability of concrete structure as apply to job site through the examination physical and chemical property of a permeability waterproof agent. It is indentified that can be maintain waterproofing performance, moreover it makes satisfactory result of permeation resistance as applying siliceous waterproof agent.

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A Study on a Performance evaluation for Quality Liguid Siliceous of waterproof agent using on the concrete Structure (콘크리트구조물에 적용하는 액상형 규산질계 침투성 방수재의 성능평가에 관한 연구)

  • Kang Hyo Jin;Kwon Shi-Won;Oh Sang-Keun
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.05a
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    • pp.184-187
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    • 2004
  • There are many factors that generate the early deterioration of the concrete structure. As the one of the representative factors, we can think an invasion of the water, air and so on. The water and air invade in inside void along the capillarity and they become the cause that the durability like corrosion of layer department due to freezing and thawing, inside steel frame corrosion, and so on blacks. Therefore with covering permeability covering waterproofing material of fluid condition in outer wall, intercepting the deterioration factor due to the infiltration of water from outside and for salt damage of concrete layer department, freezing damage and neutralization, it needs to improve durability of structure. This study separately examined physical and chemical specific of quality liguid siliceous of waterproofing material. Therefore as this applys the construction site, it improves the durability of concrete structure. Further this presents the application plan from the construction market against the new material.

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An Integrated System to Predict Early-Age Properties and Durability Performance of Concrete Structures

  • Wang, Xiao-Yong;Lee, Han-Seung
    • Proceedings of the Korea Concrete Institute Conference
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    • 2010.05a
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    • pp.465-466
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    • 2010
  • In this paper, an integrated system is proposed which can evaluate both the early-age properties and durability performance of concrete structures. This integrated system starts with a hydration model which considers both Portland cement hydration and chemical reactions of supplementary cementing materials (SCM). Based on the degree of hydration of cement and mineral admixtures, the amount of reaction products, the early age heat evolution, chemically bound water, porosity, the early age short-term mechanical behaviors, shrinkage and early-age creep are evaluated as a function of curing age and curing conditions. Furthermore, the durability aspect, such as carbonation of blended concrete and chloride attack, are evaluated considering both the material properties and surrounding environments. The prediction results are verified through experimental results.

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