• Title/Summary/Keyword: Chemical Aging Ratio

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Propellant Aging Characteristics According to Aluminum Contents (알루미늄 함량에 따른 추진제 노화 특성)

  • Jeong, Jae-Yun;Park, Jung-Ho
    • Journal of the Korean Society of Propulsion Engineers
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    • v.24 no.4
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    • pp.66-72
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    • 2020
  • In this report, the post-curing and chemical aging ratio of propellants are described according to several aluminum contents. Under the same curing conditions, it was confirmed that the post-curing period of propellant having the aluminum content of 18 wt% was longer than the propellant having the 2 wt% of aluminum. On the other hand, in the chemical aging ratio analysis including post-curing, the propellant having the 18 wt% of aluminum was confirmed that the chemical aging proceeds slowly compared to the propellant having an aluminum content of 2 wt%.

Effect of Aging Period on Chromatic, Chemical and Organoleptic Properties of Burley Leaf Tobacco (버어리종 잎담배의 숙성기간이 색상, 화학성분 및 끽미에 미치는 영향)

  • 안대진;정기택;이종률;제병권;조수헌
    • Journal of the Korean Society of Tobacco Science
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    • v.26 no.1
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    • pp.35-42
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    • 2004
  • This study was carried out to examinate the effect of aging period on chromatic, chemical and organoleptic characteristics, and to evaluate of optimum aging period for each grade in burley leaf tobacco. The leaf tobaccos were produced in 2000, and threshed, redried and packed in carton box under the current methods. Four grades of processed leaf(A3T, B1T, C1W and D3W) were stored during 24 months (May 10, 2001 to April 31, 2003) in warehouse of Chungju Leaf Tobacco Processing Factory. The leaf tobaccos were sampled at three month intervals for analysis of chromatic, chemical and organoleptic properties. pH values of four grades, and Yellow(b) of A3T and BIT were also significantly decreased during the aging. Filling values, tar, nicotine and CO contents of tobacco smoke, and puff number of cigarettes were not significantly changed during the aging. Positive correlation coefficients were significantly observed between irritation of the calculated attributes from contents of volatile oil components in leaf tobacco and that of the panel sensory attributes. The ratio of maximum change in irritation attribute was larger than that in taste attribute during aging. The calculated irritations of 18~24 months aging for A3T and B1T were significantly lower than zero-aging, while those of C1W and D3W were not significant among aging periods. The panel irritations of 12~15 months aging for four grades were low tendency. The results suggest that decrease of aging period for thin leaf from 21~24 to 12~15 months may be beneficial to save storage cost in burley tobacco.

Effect of Aging Period on Chromatic, Chemical and Organoleptic Properties of Flue-cured Leaf Tobacco (황색종 잎담배의 숙성기간이 색상, 화학성분 및 끽미에 미치는 영향)

  • 정기택;안대진;이종률;제병권
    • Journal of the Korean Society of Tobacco Science
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    • v.26 no.1
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    • pp.27-34
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    • 2004
  • This study was carried out to examinate the effect of aging period on chromatic, chemical and organoleptic characteristics, and to evaluate of optimum aging period for each grade in flue-cured leaf tobacco. The leaf tobaccos were produced in 2000, and threshed, redried and packed in carton box under the current methods. Four grades of processed leaf(A3O, B1O, C1L and D3L) were stored during 24 months(May 10, 2001 to April 31, 2003) in warehouse of Chungju Leaf Tobacco Processing Factory. The leaf tobaccos were sampled at three month intervals for analysis of chromatic, chemical and organoleptic properties. Yellow(b), pH values and total sugar contents of four grades were significantly decreased during the aging. Filling values, tar, nicotine and CO contents of tobacco smoke, and puff number of cigarettes were not significantly changed during the aging. Positive correlation coefficients were significantly observed between taste and irritation of the calculated attributes from contents of volatile oil components in leaf tobacco and those of the panel sensory attributes. The ratio of maximum change in taste attribute was larger than that in irritation attribute during aging. The optimum aging periods estimated by taste for A3O, B1O, C1L and D3L were 17.8, 14.9, 10.8, and 9.8 months, respectively. The thin leaf(Primings and Cutters) undergo satisfactory aging earlier as compared to bodied leaf(Leaf and Tips). The results suggest that decrease of aging period for thin leaf from 18~21 to 9~12 months may be beneficial to save storage cost in flue-cured tobacco.

Effects of Chemical Admixture on the Paste Fluidity and Mortar Strength Development of High Chloride Cement (염소 고함유시멘트의 페이스트 유동성과 모르타르 강도발현성에 미치는 화학 혼화제의 영향)

  • Jeong, Chan-Il;Park, Soo-Kyung;Lee, Eui-Hak;Lee, Kyung-Hee
    • Journal of the Korean Ceramic Society
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    • v.44 no.1 s.296
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    • pp.23-31
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    • 2007
  • To examine the effects of chemical admixture on the fluidity and strength development of high chloride cement, experiments were conducted in which lignosulfonate (LS), naphthalenesulfonate (NS), and polycorboxylate (PC) were each added in standard and excessive amounts, and the results were as follows. 1. Because adding KCl to NS causes a decrease in flow, adding PC is better in maintaining high cement fluidity. 2. When cement contained much chloride comes in contact with water, hydration begins 4 h after contact and securing workability becomes difficult, but by adding PC, workability can be secured to 10 h. 3. The bound water ratio and compressive strength in aging 3 days occupy $70\sim80%$ of those in aging 28 days, and the early compressive strength increases not only by adding KCl, but also by chemical admixture. 4. Although compressive strength development is excellent in NS, PC, if NS is added excessively, hydration becomes slow and while the pore structures become slightly minute, the strength development decreases due to severe setting retardation.

Effects of mixture of improved Meju, Korean traditional Meju and Natto on soybean paste fermentation (재래 및 개량메주와 납두의 배합이 된장 발효에 미치는 영향)

  • Joo, Hyun-Kyu;Oh, Kyun-Teak;Kim, Dong-Hyun
    • Applied Biological Chemistry
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    • v.35 no.4
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    • pp.286-293
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    • 1992
  • This study was investigated on the change of physico-chemical properties at various mixture ratio of improved Meju and Natto during the aging of soybean paste. pH was increased on the improved Meju with increasing the mixture ratio of Natto, but pH was decreased in Korean traditional Meju. Change of nitrogen compound was 3 times higher and aging was faster in increased ratio of Korean traditional Meju than that of improved Meju. Brown color was not changed as compared to the initial stage, however the value of brown color was higher in the Korean traditional Meju than that of other group. In sensory evaluation, the mixture ratio of improved Meju, Korean traditional Meju and Natto (48 : 48 : 5) was the best acceptables.

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Effect of Aging on the Chemical Forms and Phytotoxicity of Arsenic in Soil (비소 오염기간이 토양 내 비소의 존재형태와 식물독성에 미치는 영향)

  • Yang, Woojin;Jho, Eun Hea;Im, Jinwoo;Jeong, Seulki;Nam, Kyoungphile
    • Journal of Soil and Groundwater Environment
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    • v.21 no.3
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    • pp.82-87
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    • 2016
  • This study investigates effects of an aging period on arsenic (As) chemical forms in soils and phytotoxicity using artificially As-contaminated soils with a range of As concentrations (0-300 mg/kg) and aging periods (0 and 3 months). A sequential extraction procedure showed that the increasing As concentration in soils increased the ratio of non-specifically and specifically bound As, which are known to be bioavailable. This resulted in increasing As uptake by tomatoes with increasing As concentration (R2=0.87 for exponential fitting); however, the seed germination was not sensitive to the As concentrations of the soil samples. The seed germination was also statistically similar in the soils with 75 and 150 mg-As/kg regardless of the aging period. The time taken until the seed germination (i.e., lag phase), on the other hand, decreased from 10 d to 3 d with aging for 3 months. This can be attributed to the decreased amount of bioavailable As with aging. Overall, this study shows that when the toxic effects of the As-contaminated soils are assessed using tomato plants, it is better to use more sensitive methods than seed germination such as the As accumulation or the lag phase for seed germination.

Properties of Nimonic 80A Alloy with Change in the Chemical Compositions and Heat Treatment Paths (화학조성 및 열처리경로 변화에 따른 Nimonic 80A 합금의 특성)

  • Choi Byong-Kang;Jeong Hae-Yong;Bae Cha-Hurn
    • Korean Journal of Materials Research
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    • v.15 no.12
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    • pp.773-779
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    • 2005
  • Properties of Ni-base superalloys of Nimonic 80A alloy system were investigated by the observation of microstructures, precipitates ana hardness as a function of the chemical compositions ana the paths of heat treatment. The higher hardness values showed, the higher Ti/Al ratio among high compositions of Cr and Co element. The lower (Ti+Al) and Fe contents decreased in the same Ti/Al ratio, the higher hardness values showed. This results are considered that coherent deformation was increased with increasing Ti/Al ratio. Hardness showed higher value when Cr contents was $18 wt\%$ less than $21wt\%Cr$. In $3.15 wt\%$Co alloy, $\gamma'$ phase was very fine as around 50nm and, its volume fraction and hardness showed the highest value by 2step-aging treatment.

Effect of Water and Aluminum Sulfate Mole Ratio on Pore Characteristics in Synthesis of AlO(OH) Nano Gel by Homogeneous Precipitation (균일침전에 의한 AlO(OH) 나노 겔 합성에서 물/황산알루미늄의 몰 비가 세공특성에 미치는 영향)

  • Choe, Dong-Uk;Park, Byung-Ki;Lee, Jung-Min
    • Journal of the Korean Ceramic Society
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    • v.43 no.9 s.292
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    • pp.564-568
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    • 2006
  • AlO(OH) nano gel is used in precursor of ceramic material, coating material and catalyst. For use of these, not only physiochemical control for particle morphology, pore characteristic and peptization but also studies of synthetic method for preparation of advanced application products were required. In this study, AlO(OH) nano gel was prepared through the aging and drying process of aluminum hydroxides gel precipitated by the hydrolysis reaction of dilute NaOH solution and aluminum sulfate solution. In this process, optimum synthetic condition of AlO(OH) nano gel having excellent pore volume as studying the effect of water and aluminum sulfate mole ratio on gel precipitates has been studied. Water and aluminum sulfate mole ratio brought about numerous changes on crystal morphology, surface area, pore volume and pore size. Physiochemical properties were investigated as using XRD, TEM, TG/DTA, FT-IR, and $N_2$ BET method.

Determination of New Parameter for Materials Degradation Using Continuous Indentation Testing Technique (연속압입 시험기법을 이용한 석유화학설비 경년손상의 새로운 평가변수 고찰)

  • Jang, Jae-Il;Choi, Yeol;Son, Dongil;Lee, Yun-Hee;Kwon, Dongil;Kim, Jeoung-Tae
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.26 no.5
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    • pp.881-889
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    • 2002
  • Newly developed continuous indentation technique has made nondestructive assessment of tensile properties possible. The present study was undertaken to determine new parameters for indicating time-dependent material degradation of petro-chemical plant. Continuous indentation tests were performed for Cr-Ni steel and Cr-Mo steel which are widely used as facilities of petro-chemical plant. From the results, it was found that yield strength and tensile strength cannot be used as general degradation parameters because the changes in the strengths with aging time didn't show any tendency. On the other hand, work hardening exponent and yield ratio showed consistent tendency with increasing aging time. Therefore, nam attention of this work was paid on them as new degradation parameters, and the in-field applicability of the parameters was evaluated and discussed.

Study on the Properties of Flexible Polyurethane Foam at the Aging Condition (연질 폴리우레탄 폼의 노화 특성 연구)

  • Kim, Chang-Bum;Kim, Sangbum
    • Journal of the Korean Institute of Gas
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    • v.16 no.6
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    • pp.123-127
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    • 2012
  • In order to establish the cause of the deformation of polyurethane foam, compression set was measured according to the aging temperature and time. FT-IR, TGA, DSC and DMA were used for investigating the cause of deformation of aged PUF. The results of FT-IR and TGA reveals that no structure change occurred during deformation of PUF. Resilience of aged PUF was reduced by the increase of reduction ratio in storage modulus over the glass transition temperature of hard segment.