• Title/Summary/Keyword: Chemical Accidents

Search Result 477, Processing Time 0.029 seconds

A Study on the Characteristics of Fenton Oxidation of Bisphenol A and Nitrobenzene (비스페놀A와 니트로벤젠의 펜톤 산화분해 특성)

  • Bae, Su-Jin;Kwon, Hee-won;Kim, Ji-young;Hwang, In-Seong;Kim, Young-Hun
    • Journal of Environmental Science International
    • /
    • v.30 no.12
    • /
    • pp.1005-1014
    • /
    • 2021
  • Organic contaminants can be released into water environments due to chemical accidents and exist as dissolved and non-aqueous phase liquids (NAPL). Fenton oxidation was tested for bisphenol A and nitrobenzene as model organic contaminants in dissolved and NAPL states. Fenton oxidation was successfully applied for both of the dissolved and NAPL states of the two pollutants and the results indicated that a quick treatment was needed to reduce the risk from a chemical accidents instead of carrying out oxidation after the contaminants dissolve in water. A set of Fenton reactions were tested under seawater conditions because chemical accidents often occurs in the ocean. Chloride ions act as radical scavengers and inhibit Fenton oxidation. The reaction rate is inversely proportional to salt contents and the reduced reaction rate can be compensated by increasing the quantity of the oxidizing agents. The current study showes that Fenton oxidation could be applied as a quick treatments for organic contaminant in dissolved and NAPL state organic contaminants released as a result of leaks or chemical accidents.

Analysis of Performance Influencing Factor in Chemical Process Industry : A Practical Application (석유화학 산업에서의 수행영향인자 및 근본원인 분석 결과)

  • Yu, Kwang-Soo;Kim, Eun-Jung;Kim, Yong-Soo
    • Journal of the Korean Institute of Gas
    • /
    • v.11 no.2 s.35
    • /
    • pp.60-64
    • /
    • 2007
  • Chemical Process industry in Korea has over 30 year's of history and is likely to face potential incidents. The traditional risk analysis and control system in Chemical Process industry focuses on mechanical defects, overlooking the human performance control. Although development of automation technology and controlling technology was necessary, human decision factor is essential to preventing accidents in the Chemical Process. Almost all serious accidents take place when inappropriate humanperformance and mechanical defects of safety equipments simultaneously occurs. The AHRA(Advanced Human Reliability Analyzer) software has been developed to collect failure data and analyze human error probability (Reliability) in Chemical Process Industry in Korea. This paper describes the HRA analysis result of PIF(Performance Influencing Factor) evaluation, HEP(Human Error Probability) and root cause of accidents by applying a Chemical Process Industry related accident data. This analysis result should present a scheme that, by controlling human error factor other than putting safety management funds into the machinery in plants, can reduce cost and maximize the safety in Chemical Process Industry.

  • PDF

A Study on the Analysis of Chemical Leakage Accidents Using CFD Simulation (CFD 시뮬레이션을 활용한 화학물질 누출사고 분석에 관한 연구)

  • Su-Bin An;Chang-Bong Jang;Kyung-Su Lee;Hye-Ok Kwon
    • Journal of Korean Society of Occupational and Environmental Hygiene
    • /
    • v.33 no.3
    • /
    • pp.346-354
    • /
    • 2023
  • Objectives: Chemical accidents cause extensive human and environmental damage. Therefore, it is important to prepare measures to prevent their recurrence and minimize future damage through accident investigation. To this end, it is necessary to identify the accident occurrence process and analyze the extent of damage. In this study, the development process and damage range of actual chemical leakage accidents were analyzed using CFD. Methods: For application to actual chemical leakage accidents using FLACS codes specialized for chemical dispersion simulation among CFD codes, release rate calculation and 3D geometry were created, and scenarios for simulation were derived. Results: The development process of the accident and the dispersion behavior of materials were analyzed considering the influencing factors at the time of the accident. In addition, to confirm the validity of the results, we compared the results of the actual damage impact investigation and the simulation analysis results. As a result, both showed similar damage impact ranges. Conclusions: The FLACS code allows the detailed analysis of the simulated dispersion process and concentration of substances similar to real ones. Therefore, it is judged that the analysis method using CFD simulation can be usefully applied as a chemical accident investigation technique.

A Study on Accident Response Guidelines for Hazardous Materials(HAZMAT) Transport Vehicle (유해화학물질 수송용 차량의 사고 대응 가이드라인에 관한 연구)

  • Seol, Ji Woo;Yong, Jong Won;Chae, Chung-Keun;Tae, Chan Ho;Ko, Jae Wook
    • Journal of the Korean Institute of Gas
    • /
    • v.19 no.5
    • /
    • pp.87-97
    • /
    • 2015
  • Accidents of HAZMAT transport vehicle are generally dealt by unskilled firefighters. As a result, firefighters became 2nd victims of accidents in some case because of this reason, and it is required to prepare an accident response guidelines against HAZMAT transport vehicle accidents. In this study, risk assessment methods and making methods of guidelines were investigated to make accident response guidelines of HAZMAT transport vehicle accidents. and It identifies hazards and combines with guideword for making guideline items. At last, we determine criteria or detailed methods by referring survey regulations and existed methods.

The Analysis and Classification of Urban Types for Potential Damage from Hazardous Chemical Accidents Using Factor and Cluster Analysis (요인 및 군집분석을 이용한 유해화학물질 사고 잠재적 피해에 대한 도시 유형 분류 및 특성 분석)

  • Lee, Seung Hoon;Ryu, Young Eun;Kim, Kyu Ri;Back, Jong In;Kim, Ho-Hyun;Ban, Yong Un
    • Journal of Environmental Health Sciences
    • /
    • v.46 no.6
    • /
    • pp.726-734
    • /
    • 2020
  • Objectives: The aim of this study was to analyze and classify the characteristics of potential damage from hazardous chemical accidents in 229 administrative units in South Korea by reflecting the social and environmental characteristics of areas where chemical accidents can occur. Methods: A number of indicators were selected through preceding studies. Factor analysis was performed on selected indicators to derive factors, and cluster analysis was performed based on the factor scores. Results: As a result of the cluster analysis, 229 administrative units were divided into three clusters, and it was confirmed that each cluster had its own characteristics. Conclusions: The first cluster, "areas at risk of accident occurrence and spread of damage" was a type with a high potential for accident damage and a high density of hazardous facilities. The second cluster, "Urban infrastructure damage hazard areas" appeared to be a cluster with high urban development characteristics. Finally, the third cluster 'Urban and environmental damage hazard areas' appeared to be a cluster with an excellent natural environment. This study went further from the qualitative discussion related to existing chemical accidents to identify and respond to accident damage by reflecting the social and environmental characteristics of the region. Distinct from the previous studies related to the causes of accidents and the response system, it is meaningful to conduct empirical research focusing on the affected areas by analyzing the possibility of accident damage in reflection of the social and environmental characteristics of the community.

A Study on the Improvement of Chemical Accident Response System in View of the National Disaster Management System (국가재난관리체제 관점의 화학사고 대응체계 개선방안에 관한 연구)

  • Lee, Jae-Seok;Choi, Don-Mook
    • Fire Science and Engineering
    • /
    • v.29 no.5
    • /
    • pp.73-78
    • /
    • 2015
  • Since the hydrofluoric acid spill accident in Gumi in 2012, the current situation has continued to suffer from makeshift responses or feeble national system maintenance in preparing real countermeasures against chemical accidents, regardless of their repeated occurrence and seriousness. Industrial chemical accidents have an enormous ripple effect on the whole country and society. The purpose of this study is to propose ways of establishing directions for the national disaster management system against repeated occurrence of chemical accidents. To achieve this goal, the present study proposed improvement measures of response system for industrial chemical accident through the analysis of the current response system and structural causes of disaster control failure for chemical accidents.

A Study on the Management Method for Preventing Workers' unsafe Behavior in Chemical Plant (화학공장의 근로자 불안전상태 예방을 위한 관리방법에 관한 연구)

  • Baek, Ju Hong;Lim, Dong-Hui;Kim, Min-Seop;Seol, Ji Woo;Yoo, Byung Tae;Ko, Jae Wook
    • Journal of the Korean Institute of Gas
    • /
    • v.26 no.3
    • /
    • pp.1-9
    • /
    • 2022
  • The causes of accidents occurring in chemical plants vary, but 96% of industrial accidents occurring worldwide are caused by workers' unsafe behavior. The International Labour Organization (ILO) has announced 20 elements of workers' anxiety-warning behaviors that occur on multiple occasions at industrial sites in order to warn them of the risk of accidents caused by workers' anxiety-driven behavior, and to prevent industrial accidents, workers' anxiety-driven behavior should be controlled under stress In this study, major types of unsafe behavior were analyzed on the basis of information on the accident investigation history of domestic workspaces in order to find out how workers can manage their unsafe behavior. Based on the results of the analysis of the major anxiety war behavior, the root cause of causing anxiety war behavior was analyzed using the Swiss Cheese Model, and each root cause management method was proposed.

Study on Improvement Measures for Prevention and Countermeasure of Chemical Accident (화학사고 예방 및 대책에 대한 개선방안에 관한 연구)

  • Lee, Deok-Jae;Lee, Tae-Hyung;Shin, Chang-Hyun
    • Fire Science and Engineering
    • /
    • v.30 no.5
    • /
    • pp.137-143
    • /
    • 2016
  • The use of chemicals is increasing due to industrial advancement and diversification. In addition, the number of chemical accidents are increasing at the same time. A multifaceted effort in chemical accidents is needed for efficient prevention and countermeasures. This paper presents, under the current Act, a chemical accident case, including the material safety data sheet (MSDS) through the chemical accident prevention and measures for improvement with regard to research.

Suggestions for Increasing Utilization of KORA for Supporting the Off-site Risk Assessment System (화학사고 장외영향평가 지원 프로그램(KORA)의 활용도 증대를 위한 제언)

  • Kim, Jungkon;Ryu, Jisung;Ryu, Taekwon;Kwak, Sollim;Lim, Hyeongjun;Choi, Woosoo;Jung, Jinhee;Lee, Jieun;Lim, Dongyeon;Yoon, Junheon
    • Journal of Environmental Health Sciences
    • /
    • v.44 no.2
    • /
    • pp.124-132
    • /
    • 2018
  • Objectives: All enterprises intending to install and operate hazardous chemical handling facilities should prepare an off-site risk assessment (ORA) report that evaluates the impact of potential chemical accidents on the surrounding environment and population. This study was conducted to introduce the process of development and the functioning of the Korea Off-site Risk Assessment support tool (KORA) developed by the National Institute of Chemical Safety and to suggest manners to increase its utilization. Additionally, this article provided an overview of KORA. Methods: In order to identify problems with and refinements for KORA, the required items for each phase of KORA were derived by analyzing the Chemical Control Act and related administrative regulations. Results: The functions of KORA made receptor-considered assessment of chemical accidents possible, but several limitations were found in particular phases, such as the analysis of impact range, consideration of sensitive receptors, and assessment of environmental receptors. Conclusion: In this study, we suggested manners to increase the utilization of KORA. It is anticipated that the further research suggested in the study could contribute to the stabilization of the KORA system.

Improved Classification of Fire Accidents and Analysis of Periodicity for Prediction of Critical Fire Accidents (초대형화재사고 예측을 위한 화재사고 분류의 개선 및 발생의 주기성 분석)

  • Kim, Chang Won;Shin, Dongil
    • Journal of the Korean Institute of Gas
    • /
    • v.24 no.1
    • /
    • pp.56-65
    • /
    • 2020
  • Forecasting of coming fire accidents is quite a challenging problem cause normally fire accidents occur for a variety of reasons and seem randomness. However, if fire accidents that cause critical losses can be forecasted, it can expect to minimize losses through preemptive action. Classifications using machine learning were determined as appropriate classification criteria for the forecasting cause it classified as a constant damage scale and proportion. In addition, the analysis of the periodicity of a critical fire accident showed a certain pattern, but showed a high deviation. So it seems possible to forecast critical fire accidents using advanced prediction techniques rather than simple prediction techniques.