• 전기전자학회논문지
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• 제19권2호
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• pp.201-209
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• 2015

본 논문에서는 빛에너지 하베스팅을 이용한 MPPT(Maximum Power Point Tracking) 제어 기능을 갖는 배터리 충전기를 제안한다. 제안된 회로는 MPPT를 이용하여 빛 에너지를 PV(photovoltaic) 셀로부터 수확하고, 수확한 에너지를 배터리에 연결하여 충전한다. 배터리 관리 회로에서 출력되는 신호에 따라, 배터리의 충전 상태가 조절된다. MPPT 제어는 PV 셀의 개방회로 전압과 MPP 전압간의 비례관계를 이용하여, 보조(pilot) PV 셀로 하여금 주(main) PV 셀의 MPP를 실시간 추적할 수 있도록 설계하였다. 제안된 회로는 $0.35{\mu}m$ CMOS 공정으로 설계하였으며, 모의실험을 통해 성능을 검증하였다. 설계된 회로의 최대 효율은 86.2%이며 칩 면적은 패드를 포함하여$1.35mm{\times}1.2mm$이다.

• 대한화학회지
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• 제60권4호
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• pp.239-244
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• 2016

안정된 구조로 알려진 산화구리 클러스터(Cu_nO_n, n = 1 - 8)를 이용하여 구리 원자를 규소 원자로 치환하여 Cu_mSiO_m+1 (m = 0 - 7)의 안정된 구조를 최적화하였다. B3LYP/LANL2DZ의 이론수준에서 계산하였으며 중성과 하전된 안정된 구조를 계산하였다. 구리원자를 규소 원자로 치환으로 인한 구조적 변화를 위해 결합길이, 결합각, 그리고 Mulliken 전하를 계산하였다. 클러스터의 상대적 안정성을 구하기 위해 second differences in energy를 계산하였고 전기적 특성을 연구하기 위해 이온화 에너지와 전자친화도 계산을 수행하였다.

• 대한화학회지
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• 제28권6호
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• pp.418-424
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• 1984

Cinnamonitrile의 산-가수분해 반응속도상수를 25$^{\circ}$C, HClO$_4$ 1 ~ 5M의 센산성 용액속에서 UV분광법으로 측정하고 Bunnett관계식에 적용하여 ${\omega}$ = 9.8, ${\omega}^*$ = 0.42 및 ${\phi}$=1.6등의 hydration parameter를 구하였다. 이는 질소원자에 양성자화가 이루어진 짝산에 대하여 속도결정단계에서 친핵체로 물분자가 첨가된 다음에 양성자 전달체로 작용한다는 것을 시사한다. Cinnamonitrile 분자의 궤도함수를 CNDO/2방법으로 계산한 바, 형태이성체의 안정도는 (E)-planar＞(Z)-planar이였으며 음하전의 크기는 $C_8({\beta}){\ll}N$이였고 전이상태에서 물분자는 짝산의 양하전이 큰 $C_7({\alpha}$)원자에 대하여 ${\sigma}$접근함을 알았다. 이상의 결과로 부터, 센산성속에서 cinnamonitrile의 가수분해반응은 특정 산-촉매작용을 수반하는 A-2형의 산-가수분해 반응메카니즘에 의하여 진행됨을 알았다.

• Bulletin of the Korean Chemical Society
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• 제25권9호
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• pp.1314-1320
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• 2004

The adsorption and configuration of CO molecules adsorbed on W (110) and W (100) surfaces have been calculated by the atomic superposition and electron delocalization molecular orbital (ASED-MO) method. Referred to as the ASED-MO method, it has been used in the present study to calculate the geometries, binding energies, vibrational frequencies, orbital energies, reduced overlap population (ROP), and charges. From these results adsorption properties of ${\alpha}$-state and ${\beta}$-state were deduced. The calculated binding energies are in good agreement with the experimental result. On the W (110), the calculated average binding energies are 2.56 eV for the end-on configuration and 3.20 eV for the lying-down configuration. Calculated vibrational frequency is 1927 $cm^{-1}$ at a 1-fold site and 1161 $cm^{-1}$ at a long-bridge (2) site. These results are in reasonable agreement with experimental values. On the W(100) surface, calculated average binding energies of the end-on and the lying-down are 2.54 eV and 4.02 eV respectively. The differences for binding energy and configuration on the surfaces are explained on the basis of surface-atom coordination and atom-atom spacing. In the favored lyingdown CO configuration on the W(110) and W(100) surfaces, 4 ${\sigma}$ and 1 ${\pi}$ donation interactions, coupled with the familiar 5 ${\sigma}$ donation to the surfaces and back-donations to the CO 2 ${\pi}^{\ast}$ orbital, are responsible for adsorption to the surface.

• 한국컴퓨터정보학회논문지
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• 제25권2호
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• pp.105-111
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• 2020

태양 에너지 수집형 무선 센서 네트워크(SP-WSN)는 지속적으로 에너지를 수집할 수 있어 배터리 기반 센서 네트워크의 에너지 제약 문제를 완화할 수 있다. 하지만 고정된 싱크를 사용한다면, 싱크 주변에 위치한 노드들의 에너지 소비가 상대적으로 증가하는 문제, 즉 에너지 사용 불균형 문제는 해결하지 못한다. 따라서 최근의 연구에서는 SP-WSN에 모바일 싱크를 사용하여 에너지 불균형 문제에 접근하고 있다. 한편, 무선 전력 전송 기술 발전에 따라 WSN에서 모바일 싱크가 데이터 수집뿐 아니라 무선 전력 전송을 통한 에너지 충전의 역할도 할 수 있다. 본 논문에서는 무선 전력 전송이 가능한 모바일 싱크와 효율적인 클러스터링 기법(클러스터 헤드 선출 포함)을 이용하여 SP-WSN의 에너지 불균형 문제를 최소화하는 기법을 제안한다. 제안 기법은 클러스터 헤드를 무선 전력 전송을 사용하여 충전시키고, 효과적인 헤드 선출을 통해 헤드 주변 노드의 에너지 핫스팟을 완화시켜, 결과적으로 모바일 싱크로 수집되는 데이터양을 증가시킨다.

• Macromolecular Research
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• 제12권3호
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• pp.276-281
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• 2004

In this study we investigated the spectral properties, including electric absorption, circular and linear dichroism (CD and LD), and fluorescence emission, of DNA in a DNA-branched polyethyleneimine (BPEI) polyplex at various polymer molecular weights (M$\_$w/) and BPEI-amine-to-DNA-phosphate ratios (N/P ratios). All BPEIs exhibited a common N/P dependence in their absorption and CD spectra. At N/P ratios ＜ 1.0, we observed some hyperchromism in the absorption spectrum, red-shifts in CD bands, and decreases in LD intensity and fluorescence intensity of intercalated ethidium. At intermediate N/P ratios, complete collapse of all spectra occurred. As the N/P ratio increased further, the polyplex dissolved in water. From its characteristic CD spectrum obtained under these conditions, we conclude that the DNA exists in a B-like form. The fluorescence and LD intensities never recovered even at high N/P ratios- which indicates that the dissolved polyplex possesses positive charges and the DNA in the polyplex is condensed despite its B-form CD spectrum. The N/P range in which the absorption and CD signals collapsed was wider when the BPEIs M$\_$w/ decreased. In the case where the BPEIs M$\_$w/ was 0.8 k, recovery of the absorption and CD spectral properties at a high N/P ratio was never achieved, which suggests that the molecular weight of the polymer plays an important role in its dissolution at a high N/P ratio.

• 한국태양에너지학회 논문집
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• 제38권4호
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• pp.55-66
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• 2018

nZEH (net-Zero Energy House) is defined as a self-sufficient energy building where the sum of energy output generated from new & renewable energy system and annual energy consumption is zero. The electricity generated by new & renewable energy system with the form of distributed generation is preferentially supplied to electrical demand, and surplus electricity is transmitted back to grid. Due to the recent expansion of houses with photovoltaic system and the nZEH mandatory by 2025, the rapid increase of distributed generation is expected. Which means, we must prepare for an electricity-power accident and stable electricity supply. Also electricity charges have to be reduce and the grid-connected should be operated efficiently. The introduction of ESS is suggested as a solution, so the analysis of the load matching and grid interaction is required to optimize ESS design. This study analyzed the load matching and grid interaction by expected consumption behavior using actual data measured in one-minute intervals. The experiment was conducted in three nZEH with photovoltaic system, called all-electric houses. LCF (Load Cover Factor), SCF (Supply Cover Factor) and $f_{grid}$ (Grid Interaction Index) were evaluated as an analysis indicator. As a result, LCF, SCF and $f_{grid}$ of A house were 0.25, 0.23 and 0.27 respectively; That of B house were 0.23, 0.23, 0.19, and that of C were 0.20, 0.19, 0.27 respectively.

• Journal of Magnetics
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• 제7권1호
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• pp.18-20
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• 2002

The charge structures of (LSMO) and of the combined system $(La_{ 0.6}Sr_{0.4}FeO_3$(LSMO) and of the combined system (La_{0.6}Sr_{0.4}MnO_3)_{0.7}(La_{0.6}Sr_{0.4}/FeO_3)_{0.3}$are investigated by using M$\ddot{o}$ssbauer spectroscopy. The antiferromagnetically ordered $(La_{0.6}Sr_{0.4}FeO_3$(LSFO) has possible charges of Fe^{3+} and Fe^{4+}$, which include a low-spin $Fe^{4+}$ state at and above 230 K. The temperature dependences of the M$\ddot{o}$ssbauer spectra for the $(La_{ 0.6}Sr_{0.4}FeO_3$ system and for the combined $(LSMO)_{ 0.7}(LSFO)_{0.3}$ system are fitted as three sets of Zeeman patterns corresponding to $Fe^{3+}$ and $Fe^{4+} below 230 K. At and above 230 K, the fitted M$\ddot{o}$ssbauer spectra for the combined system are the same in all temperature ranges. Above 230 K, $(La_{0.6}Sr_{0.4}FeO_3$ spectrum consists of two sets of six Lorentzians for $Fe^{3+}$ and one line for low spin $Fe^{4+}$. It is worth noting that large fields are induced in the combined system.

• 한국재료학회지
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• 제12권1호
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• pp.75-81
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• 2002

The ferroelectric properties of Pb(Zr,Ti)O$_3$[PZT] films degrade when the films with Pt top electrodes are annealed in hydrogen containing environment. This is due to the reduction activity of atomic hydrogen that is generated by the catalytic activity of the Pt top electrode. At the initial stage of hydrogen annealing, oxygen vacancies are formed by the reduction activity of hydrogen mainly at the vicinity of top Pt/PZT interface, resulting in a shift of P-E (polarization-electric field) hysteresis curve toward the negative electric field direction. As the hydrogen annealing time increases, oxygen vacancies are formed inside the PZT film by the inward diffusion of hydrogen ions, as a result, the polarization degrades significantly and the degree of P-E curve shift decreases gradually. The direction and the magnitude of the remnant polarization in the PZT film affect the motion of hydrogen ions which determines the degradation of polarization characteristics and the shift in the P-E hysteresis curve of the PZT capacitor during hydrogen annealing. When the remnant polarization is formed in the PZT film by applying a pre-poling voltage prior to hydrogen annealing, the direction of the P-E curve shift induced by hydrogen annealing is opposite to the polarity of the pre-poling voltage. The hydrogen-induced degradation behavior of the PZT capacitor is also affected by the internal field that has been generated in the PZT film by the charges located at the top interface prior to hydrogen annealing.

• 대한가정학회지
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• 제42권3호
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• pp.119-130
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• 2004

The purpose of this study is to estimate the rate of credit card payment for private education. The results of study can be used to improve credit card handling problems of private educational institutes, leading toward improvements in income transparency, increase in tax burden equity and long-term economic welfare improvement for individual households. 424 households out of 586 household that were surveyed in September of 2002 had 1,700 cases private extracurricular education. 67 of the 1,700 cases that did not have expenditure records were removed from the analysis. Only 3.67％ out of 1,633 cases were paid by a credit cards and the amount of credit card payment were only 5.65％ of the total amount spent for private education. The average fee of private educational institutes that allow credit card payment was higher than the fees of private institutes which don't allow a credit card payment or those of private institutes where consumers don't know whether a credit card payment was allowed. The average fee of private education paid by credit cards was 34,465.46 won higher than that paid by cash. Credit card payments to private educational institutions is an important social issue with respect to fair tax collection and tax burden equity since most private educational services operate in fairly small sizes and are offered by the self-employed, and the expense of private education is a fairly large proportion of the household income. It is also important for consumers if credit card acceptance expands alternatives that consumers can choose in private education. Therefore, credit card payment should be encouraged in private extracurricular education. To do this, private education providers should be forced to join a credit card payment service by the National Tax Service. A regulation that prohibits the refusal of credit card payments should be required, and credit card service charges of private education providers should be incrementally decreased. Also, consumer education and public promotions for credit card use instead of cash in paying for private education fees are recommended.