• 제목/요약/키워드: Charged defect

검색결과 29건 처리시간 0.028초

CaO 도가니에 의한 Ti-6Al-4V 합금의 용해와 주조결함 (Melting of Ti-6Al-4V Alloy Using CaO Crucible and Internal Defects of its Casting)

  • 세이주우치다;킨야카나타;나오히로타나카;오사무야나기사와
    • 한국주조공학회지
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    • 제24권6호
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    • pp.314-322
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    • 2004
  • The CaO crucible is expected to serve as a useful tool for melting Ti and its alloys due to its thermodynamic stability. However, tjere still remain problems that need to be resolved in the melting of Ti and its alloys to enable commerical use. The cause of the defects of Ti-6AI-4V alloy castings melted in the CaO crucible were examined and compared with induction skull melting. The key factors of the melting technique using the CaO crucible, affecting the quality of Ti-6AI-4V alloy castings, were investigated. Defects of the Ti-6AI-4V alloy castings are caused by the chemical reduction of CaO by Ti. Pressurizing with argon gas in a vacuum induction chamber is effective for reducing the defects. Preheating of the charged material in the crucible and quick pouring into a mold of lower temperature, just after melting down, are important for produsing sound Ti-6AI-4V castings.

건물 내장용 타일의 하자사례 조사를 통한 개선방향 검토 (Reviewing the Improvement through the Case Study of the Built-in Tiles)

  • 편수정;김종호;이상규;황의철;김규용;남정수
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2019년도 춘계 학술논문 발표대회
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    • pp.145-146
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    • 2019
  • In contemporary residential culture, apartment houses can form individual independent residential areas within narrow territory. By using various building materials compared to the past, apartment house is recognized as an aesthetic space by modern people. However, as the number of cases of tile defects in apartment complexes has surged recently, aesthetic factors and quality of life have been reduced, and hundreds of millions of defects have been charged to builders every year. The tile defects in the apartment complexes of 90 domestic complexes are cracked, lifted, damaged, and dropped off. Most of the tile defects are caused by poor construction, but the defect occurrence rate due to thermal stress mechanism is high. Therefore, this paper investigates the case of tile defects in apartment house and identifies the defects and examines the problems that should be improved to reduce the defects of tiles in the building interior.

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흡수성 차폐막의 치주조직 재생에 혈소판유래 성장인자가 미치는 영향 (The Effect of PDGF-Loaded Biodegradable Membrane on Early Healing Stage in Guided Tissue Regeneration)

  • 류인철;배규현;설양조;구영;이승진;한수부;최상묵;정종평
    • Journal of Periodontal and Implant Science
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    • 제29권3호
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    • pp.507-519
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    • 1999
  • The ultimate objective of periodontal treatment is to stop disease progression and to regenerate destroyed periodontal tissues and thereby regain normal function. Growth factors are naturally found polypetides which stimulate many cellular activities pertaining to wound healing by acting as signal molecule in controlling cell movement, proliferation, and matrix production. Platelet derived growth factor (PDGF) is 28,000-35,000 Da molecular weight dimeric protein with 2 long positively charged polypeptide chains connected by sulfide bonds. The purpose of this study is to evaluate histologically the initial guided tissue regeneration in a periodontal defect f a beagle dog treated with a biodegradable membrane formed with polylactic acid (poly-L-lactic acid) and polyglycolic acid loaded with 200ng/$cm^2$ platelet derived growth factor. 2 beagle dogs were used in he experiment. $5mm{\times}6mm$ alveolar bone defect was formed in upper and lower canines and third premolars and a reference notch was placed. PDGF-BB non-containing membrane was used as control. Each defect was randomly assigned to the test roup or the control group. The dogs were sacrificed 3 weeks after membrane placement. Toluidine blue and multiple staining was done for histological analysis. In the 3 week specimen in the control group, no new one formation could be seen. Small amount f bone resorption below the notch could be seen. In the notch, loose connective tissue with infiltration of inflammatory cells could be seen. Also thin discontinuous new cementum could be seen and the membrane still retained its structure. Where PDGF-BB containing membrane was used, new bone formation could be seen in the notch at weeks and also continuous thin cementum could be seen. PDL cells were observed between new bone and new cementum and some were attached to bone and cementum. These results suggest that new bone and cementum formation seen when PDGF-BB loaded membrane was used was due to inhibition of downgrowth of epithelial cells and also due to continuous release of the growth factor. Further study on the resorption characteristics of the membrane nd the release characteristics of the PDGF-BB is necessary. Also, development of a membrane easier to use clinically is necessary.

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$Li^{+}$ 이온 주입된 $Al_2O_3$의 결함 특성 (Defect center of $Li^{+}$ ion implanted $Al_2O_3$)

  • Kim, Tae-Kyu
    • 한국의학물리학회지:의학물리
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    • 제5권2호
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    • pp.13-20
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    • 1994
  • 본 연구에서는 감마선 조사, 전자선 조사방법에 의한 전자만의 주업 및 이온 주업 후 전자선조사 방법으로 전자들이 주입된 $\alpha$-$Al_2O_3$의 열자극 발광(Thermoluminescence : TL)에 관련된 결함 형태를 조사하였다. 감마선 조사된 $\alpha$-$Al_2O_3$의 열자극 발광 곡선은 380K, 415K, 440K, 460K 및 475K에서 TL peak가 나타났다. 광흡수 스펙트럼과 자외선 photobleaching 결과로부터 감마선 조사된 $\alpha$-$Al_2O_3$의 380K와 475K TL peak는 F center에, 415K TL peak는 $F^{+}$ center에 기인함을 알았다. 전자선 조사방법에 의하여 전자 주입된 $\alpha$-$Al_2O_3$의 열자극 발광 곡선은 380K, 415K, 440K 및 460K TL peak를 가졌고, $Li^{+}$ 이온 주입 후 전자선 조사방법으로 전자들이 주입된 $\alpha$-$Al_2O_3$는 440K에서 TL peak가 나타났다. 전자선 조사방법에 의한 전자만의 주입과 $Li^{+}$ 이온 주입 후 전자선 조사방법으로 전자들이 주입된 $\alpha$-$Al_2O_3$의 열자극 발광 특성은 380K TL peak는 F center에, 440K TL peak는 $F^{+}$ center에 기인함을 보였다.

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Influence of Annealing Temperature on Structural and Thermoelectrical Properties of Bismuth-Telluride-Selenide Ternary Compound Thin Film

  • Kim, Youngmoon;Choi, Hyejin;Kim, Taehyeon;Cho, Mann-Ho
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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    • pp.304.2-304.2
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    • 2014
  • Chalcogenides (Te,Se) and pnictogens(Bi,Sb) materials have been widely investigated as thermoelectric materials. Especially, Bi2Te3 (Bismuth telluride) compound thermoelectric materials in thin film and nanowires are known to have the highest thermoelectric figure of merit ZT at room temperature. Currently, the thermoelectric material research is mostly driven in two directions: (1) enhancing the Seebeck coefficient, electrical conductivity using quantum confinement effects and (2) decreasing thermal conductivity using phonon scattering effect. Herein we demonstrated influence of annealing temperature on structural and thermoelectrical properties of Bismuth-telluride-selenide ternary compound thin film. Te-rich Bismuth-telluride-selenide ternary compound thin film prepared co-deposited by thermal evaporation techniques. After annealing treatment, co-deposited thin film was transformed amorphous phase to Bi2Te3-Bi2Te2Se1 polycrystalline thin film. In the experiment, to investigate the structural and thermoelectric characteristics of Bi2Te3-i2Te2Se1 films, we measured Rutherford Backscattering spectrometry (RBS), X-ray diffraction (XRD), Raman spectroscopy, Scanning eletron microscopy (SEM), Transmission electron microscopy (TEM), Seebeck coefficient measurement and Hall measurement. After annealing treatment, electrical conductivity and Seebeck coefficient was increased by defect states dominated by selenium vacant sites. These charged selenium vacancies behave as electron donors, resulting in carrier concentration was increased. Moreover, Thermal conductivity was significantly decreased because phonon scattering was enhanced through the grain boundary in Bi2Te3-Bi2Te2Se1 polycrystalline compound. As a result, The enhancement of thermoelectric figure-of-merit could be obtained by optimal annealing treatment.

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Cu(In,Ga)$Se_2$ 박막의 Cu 결함 및 In, Ga 비율의 변화에 따른 구조적, 광학적, 전기적 특성 연구 (Structural, optical, and electrical properties on Cu(In,Ga)$Se_2$ thin-films with Cu-defects and In/(In+Ga) ratio)

  • 정아름;김지영;조윌렴;조현준;김대환;성시준;강진규;이동하;남다현;정현식
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2011년도 추계학술대회 초록집
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    • pp.47.1-47.1
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    • 2011
  • We report on a direct measurement of two-dimensional chemical and electrical distribution on the surface of photovoltaic Cu(In,Ga)$Se_2$ thin-films using a nano-scale spectroscopic and electrical characterization, respectively. The Raman measurement reveals non-uniformed surface phonon vibration which comes from different compositional distribution and defects in the nature of polycrystalline thin-films. On the other hand, potential analysis by scanning Kelvin probe force microscopy shows a higher surface potential or a small work function on grain boundaries of the thin-films than on the grain surfaces. This demonstrates the grain boundary is positively charged and local built-in potential exist on grain boundary, which improve electron-hole separation on grain boundary. Local electrical transport measurements with scanning probe microscopy on the thin-films indicates that as external bias is increases, local current is started to flow from grain boundary and saturated over 0.3 V external bias. This accounts for carrier behavior in the vicinity of grain boundary with regard to defect states. We suggest that electron-hole separation at the grain boundary as well as chemical and electrical distribution of polycrystalline Cu(In,Ga)$Se_2$ thin-films.

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부산 관광콘텐츠를 활용한 여행 앱북 <레인보우 부산> 개발 (The Development of A Tour Application Book Using Contents Concerned with Busan Tour)

  • 장은진;윤태수
    • 스마트미디어저널
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    • 제4권4호
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    • pp.93-100
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    • 2015
  • 현재 국내 출판계의 전자책과 앱북 시장은 장르문학인 소설과 웹툰 분야의 매출이 전체의 80%에 이르는 특정분야 매출 편중 현상이 두드러지게 나타나는 상황이다. E-book에서 진화한 앱북은 오프라인에서 주로 판매되는 종이책과는 달리 가독성과 구매의 편리함이 강점이지만 일반화되기에는 대중적 전파력에 있어 시일이 걸린다는 점이 단점으로 작용하기도 한다. 그러한 상황 속에서도 국내 전자책 시장의 매출은 가파르게 성장하고 있으며 현재는 장르문학에 국한되지 않고 출판콘텐츠 분야에서 다양한 실험적 도전이 시행되고 있는 단계라고 할 수 있다. 본 연구는 부산관광콘텐츠를 기반으로 한 최초의 지역콘텐츠 소재 앱북의 기획과 개발과정을 통해 향후 웹 모바일 플랫폼으로서 관광 앱북을 개발하고 기존의 단순한 정보만을 제공하는 앱북의 단점들을 보완하여 유료다운로드를 통한 구매로 이어지는 지속적 사용이 가능한 여행 앱북의 활용 전략을 제안하고자 한다.

Effects of sodium dodecyl sulfate surfactant on up-conversion luminescence of Er3+/Yb3+-codoped NaLa(MoO4)2 nanocolloidal phosphor prepared by pulsed laser ablation in water

  • Kang, SukHyun;Jung, Kyung-Hwan;Kim, Kang Min;Kim, Won Rae;Han, HyukSu;Mhin, Sungwook;Son, Yong;Shim, Kwang Bo;Lee, Jung-Il;Ryu, Jeong Ho
    • Journal of Ceramic Processing Research
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    • 제20권2호
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    • pp.158-163
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    • 2019
  • Er3+/Yb3+-codoped NaLa(MoO4)2 colloidal nanocrystals were synthesized by pulsed laser ablations in de-ionized water and sodium dodecyl sulfate (NaC12H25SO4, SDS) aqueous solution for up-conversion (UC) luminescence bio-labeling applications. The influences of the SDS molecules on the crystallinities, crystal morphologies, crystallite sizes, and UC luminescence properties of the prepared Er3+/Yb3+-codoped NaLa(MoO4)2 colloidal nanocrystals were investigated in detail. Under a 980-nm excitation, the Er3+/Yb3+-codoped nanocolloidal NaLa(MoO4)2 suspension exhibited a weak red emission near 670 nm and strong green UC emissions at 530 and 550 nm, corresponding to the intra 4f transitions of Er3+ (4F9/2, 2H11/2, 4S3/2) → Er3+ (4I15/2). When the SDS solution was used, a smaller average crystallite size, narrower size distribution, and enhanced UC luminescence were observed. These characteristics were attributed to the amphoteric SDS molecules attached to the positively charged Er3+/Yb3+-codoped NaLa(MoO4)2 colloidal nanocrystals, effectively occupying the oxygen defect on their surfaces. The Er3+/Yb3+-codoped nanocrystalline NaLa(MoO4)2 suspension prepared in the SDS solution exhibited a remarkably strong green emission visible to the naked eyes.

팔라디움전극에서 중수소의 전기분해와 수소와 격자결함의 반응에 관한 연구 (A Study on Electrolysis of Heavy Water and Interaction of Hydrogen with Lattice Defects in Palladium Electrodes)

  • Ko, Won-Il;Yoon, Young-Ku;Park, Yong-Ki
    • Nuclear Engineering and Technology
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    • 제24권2호
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    • pp.141-153
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    • 1992
  • 상온핵융합의 실험적 검증을 위하여 가공조건 및 기하학적조건이 다른 7종류의 팔라디움전극을 사용하여 24~28시간, 전류밀도 83~600 mA/$\textrm{cm}^2$의 조건하에 전기분해를 실시하였다. 상기조건 하에서 삼중수소의 농축에 기인한 분리팩타(separation factor)를 측정하였고 핵융합의 부산물일수도 있는 삼중수소 증가량을 측정하였다. 또한 초과열 계 산과 관련된 K(net Faradic efficiency)를 측정하여 산소/중수소 가스의 재결합정도를 조사하였다. 양전자소멸측정장치 및 일정체적 가스주입장치를 이용하여 팔라디움전극에서 격자결함과 수소의 반응 및 거동에 대하여 조사하였다. 전기분해하는 동안 삼중수소 농축현상이 관찰되었으나 핵융합의 증거가 될만한 삼중수소양은 검출되지 않았다. 한편 산소/수소 가스의 재결합 정도는 32%로 나타났다. 이는 재결합과정이 발열반응이므로 전기분해과정에서 핵반응과 관계없이 초과엔탈피가 발생할 수 있음을 의미한다. 양전자소멸측정장치를 이용하여 양전자수명, 양전자소멸밀도, P/W 및 R 파라메터의 측정을 통하여 전극의 격자결함(전위 및 공공)에 수소가 집적 (trap)되며 수소집적은 공공에서 보다 전위에 약간 더 선호하는 것으로 나타났다. 전극의 수소화물형성에 수반하여 대부분 전위가 발생한 것으로 나타났다. 또한 팔라디움수소화물의 등시소둔실험을 통하여 소량의 미소공동 형태의 결함이 존재하는 것으로 추정하였고 그 결함의 크기는 수 $\AA$정도인 것으로 생각된다.

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