• Journal of the Korean Magnetics Society
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• v.6 no.5
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• pp.294-297
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• 1996

We have carried out a $^{31}P$ nuclear magnetic resonance (NMR) study on the electrooptic material $KTiOPO_{4}(KTP)$. From the spin -lattice relaxation time ($T_{1}$) measurements at 17.9 MHz in the temperature range 77-390 K, two phase transitions associated with the change of the dominant charge carriers were observed and the activation energies were obtained in each phase.

• Journal of Magnetics
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• v.5 no.3
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• pp.73-75
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• 2000

Undoped and Cr-doped samples of electrooptic material KTiOPO$_4$ were studied by $^{31}$P nuclear magnetic resonance (NMR). Spin-lattice relaxation time ($T_1$) measurements manifested phase transition behaviors that are attributed to changes in the dominant charge carriers in different temperature ranges.

• Bulletin of the Korean Chemical Society
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• v.35 no.2
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• pp.546-550
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• 2014

Relative reactivity of various carbonyl and acid derivatives in MPV-type (Meerwein-Ponndorf-Verley) reduction with an DIBAL(F) model has been studied via DFT and MP2 methods. Free energies of initial adduct formation (-Gadd) of DIBAL(F) model and carbonyls are in the order of amide < ester < aldehyde < ketone < acid chloride; in the alan-amide adduct, the developed positive charge at carbonyl carbon is expected to be stabilized by amide resonance, but in the acid chloride adduct it is destabilized by inductive effect of chloride. However the TS barrier energies (${\Delta}G_{TS}$) for the MPV-type hydride reduction of the carbonyl adducts are in the order of aldehyde < ketone < acid chloride << ester < amide; presumably decreasing order of electrophilicity of carbonyl carbon at adducts, which is well correlated with experimental data. It is noted that the relative reactivity of carbonyl derivatives in MPV-type reduction with DIBAL(X) is not governed by the alan-adduct formation energies, but follows the order of electrophilicity of carbonyl carbon of transition states.

• Macromolecular Research
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• v.12 no.5
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• pp.484-489
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• 2004

We have prepared a phenothiazine-based nonlinear optical (NLO) chromophore that displays a fairly high microscopic nonlinearity through intramolecular charge transfer. The phenothiazine unit plays important roles of contributing its high electron donating ability and connecting the resonance pathway through a conjugative effect in the cyclized ring adjacent to the aromatic ring. Theoretical calculations and an absorption spectroscopic study provided useful information concerning the microscopic nonlinearity of the chromophores. We investigated the electro-optic (EO) properties of the guest-host systems in amorphous polycarbonate containing the synthesized chromophores at different concentrations under different poling temperatures. A real-time pole and probe method provided a much greater amount of information regarding how the EO properties can arise and how they can be optimized.

• Journal of the Korean Ceramic Society
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• v.28 no.3
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• pp.179-188
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• 1991

The semiconducting BaTiO3 ceramics used in this study were sintered in the reducing atomosphere(hydrogen gas) and neutral atmosphere(nitrogen gas), then were heat-treated in air to vary defect concentrations. In this experiment, the correlations between the composition analysis and electrical characteristics of these samples were investigated. When the BaTiO3 ceramics were sintered in N2 atmosphere, it was observed that the Ba contents near the interface were lower than that of the grain center, and these samples showed superior PTCR effects. From analysis of the resistivities of grains and grain boundaries by CIRM(Complex Impedance Resonance Method), it was confirmed that the PTCR effects were caused by the resistivity of grain boundaries. And from measurement of the capacitance at each temperature, the samples sintered in N2 atmosphere show the increase of room temperature resistance and the decrease of capacitance as a result of the increase of the charge depletion layers. This phenomenon agrees well with the cation deficiencies in the analytical results.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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• 2015.10a
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• pp.59-60
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• 2015

Wireless power transfer is a technique that supplies the necessary power to the various electronic devices over the air without wires. The technology is classified as near-field wireless power transfer technology using inductive coupling and far-field wireless power transfer technology using antenna. In this paper, RTLS tag for high-precision positioning and wireless power transfer module was designed in order to solve the power supply problem for facility management. was designed for high-precision positioning is possible RTLS tags and wireless charging. The wireless charging pad provides the capability to charge up to four devices using he magnetic resonance system.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.31 no.2 s.257
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• pp.202-207
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• 2007

In order to understand the phenomena of combustion instability, an experimental study was conducted at the moderate pressure and ambient temperature conditions. The flame behavior and the pressure fluctuations were measured in a dump combustor. Various types of combustion modes occurred in accordance with the equivalence ratio and the fuel supplying conditions. The fluctuation of pressure, heat release and equivalence ratio were measured by piezoelectric pressure sensor, high speed Intensified Charge Coupled Device (HICCD) camera and gas chromatography respectively. Two representative modes were self-excited pressure oscillations at the resonance of combustion chamber (200Hz) and instabilities related to the modulated fuel flow rate through the fuel holes (10Hz). It is found that, especially in an unchoked fuel flow condition, the modulation of the fuel flow rate affects the characteristics of flame behavior and pressure fluctuations in a lean premixed flame.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.58 no.11
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• pp.2247-2252
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• 2009

Since the dimensions of MEMS gyroscope are very small compared to those of conventional gyroscope, MEMS gyroscope should be able to measure charge of pico-coulomb caused by very small change of electrodes gap. However, feed-through signal from driving electrodes to the sensing electrodes due to the electromagnetic coupling is much greater than the sensing signal, which degrades the sensitivity of MEMS gyroscope. This paper introduces the feed-through noise canceling technique using dummy port and confirms the feasibility of feed-through noise canceling experimentally. Experimental results shows that, when driving signal is 6 Vpp, 30 kHz, feed-through signal of vacuum packaged Si Gyroscope decreases from -53.2 dBm to -77.1 dBm by using feed-through reduction technique. Q-factor that could not be measured without noise reduction is measured to be about 2500 and resonance frequency to be 7.018 kHz.

• Proceedings of the KAIS Fall Conference
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• 2003.06a
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• pp.267-270
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• 2003

All artificial infernal organs which are using electric energy supply energy with inductive couple. Transcutaneous energy transmission system enhance survival chance of the patients and quality of life by reducing volume and mass. In this research, we used both tune in transmission system in state of fixing cycle in order to increase the voltage gain and the current gain and to reduce effect of leakage inductance. Also to maximize the effect of resonance, a constant frequency duty cycle control method is used. Test is progressed with litz wire which is set up with various sizes of core to minimize size of converter. This research aimed in analysis of transcutaneous energy transmission system and in measuring of stability and efficiency of Lithium-ion battery charge which are using transmitted energy.

• Bulletin of the Korean Chemical Society
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• v.22 no.4
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• pp.367-371
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• 2001

Lithium inserted into artificial carbon has been synthesized as a function of the Li concentration. The characteristics of these prepared compounds were determined from the studies using X-ray diffraction(XRD), solid nuclear magnetic resonance (NM R) spectrophotometric and differential scanning calorimeter(DSC) analysis. X-ray diffraction showed that lower stage intercalation compounds were formed with increasing Li concentration. In the case of the AG3, most compounds formed were of the stage 1 structure. Pure stage 1 structural defects of artificial graphite were not observed. 7Li-NMR data showed that bands are shifted toward higher frequencies with increasing lithium concentration; this is because non-occupied electron shells of Li increased in charge carrier density. Line widths of the Li inserted carbon compounds decreased slowly because of nonhomogeneous local magnetic order and the random electron spin direction for located Li between graphene layers. The enthalpy and entropy changes of the compounds can be obtained from the differential scanning calorimetric analysis results. From these results, it was found that exothermic and endothermic reactions of lithium inserted into artificial carbon are related to the thermal stability of lithium between artificial carbon graphene layers.