• Title/Summary/Keyword: Charge Exchange

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Expansion of the equilibrium constants for the temperature range of 300K to 20,000K

  • Kim, Jae Gang
    • International Journal of Aeronautical and Space Sciences
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    • v.17 no.4
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    • pp.455-466
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    • 2016
  • Chemical-kinetic parameters of the equilibrium constants to evaluate the reverse rate coefficients in the shock layer of a blunt body and the expanding flows are derived for the temperature range from 300 K to 20,000 K. The expanded equilibrium constants for the chemical reactions of the dissociation, ionization, associative ionization, and neutral and charge exchange reactions of the atmospheric species and carbon materials are proposed in the present work. In evaluating the equilibrium constants, the inter-nuclear potential energies of the molecular species are calculated by the analytical potential function of the Hulburt-Hirschfelder model, and the parameters of the analytical model are determined from the semi-classically calculated RKR potentials. The electronic states and energies of the atoms are calculated by the electronic energy grouping model, and the rovibrational states and energies of each electronic states of the molecules are evaluated by the WKB method. The expanded equilibrium constants for 31 types of the reactions are provided for the best curve-fit functions, and the recombination reaction rate coefficients evaluated from the present equilibrium constants are compared with existing measured values.

Separation of Lithium Isotopes by Tetraazamacrocycles Tethered to Merrifield Peptide Resin

  • Jeon, Youn-Seok;Jang, Nak-Han;Kang, Byung-Moo;Jeon, Young-Shin;Kim, Chang-Suk;Choi, Ki-Young;Ryu, Hai-Il
    • Bulletin of the Korean Chemical Society
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    • v.28 no.3
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    • pp.451-456
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    • 2007
  • Tetraazamacrocyclic ion exchangers tethered to Merrifield peptide resin (DTDM, TTTM) were prepared and the ion exchange capacity of these was characterized. The isotope separation of lithium was determined using breakthrough method of column chromatography. The isotope separation coefficient was strongly dependent on the ligand structure by Glueckauf's theory. We found that the isotope separation coefficients were increased as the values of distribution coefficients were increased. In this experiment the lighter isotope, 6Li was enriched in the resin phase, while the heavier isotope, 7Li in the solution phase. The ion radius of lighter isotope, 6Li was shorter than the heavier isotope, 7Li. The hydration number of lithium ion with the same charge became small as mass number was decreased. Because 6Li was more strongly retained in the resin than 7Li, the isotopes of lithium were separated with subsequent enrichment in the resin phase.

Development Process for Slit Mask Exchanger Mechanism Prototype (SMEM-P) of the Giant Magellan Telescope Multi-object Astronomical and cosmological Spectrograph (GMACS)

  • Lee, Hye-In;Cook, Erika;Ji, Tae-Geun;Byeon, Seoyeon;Pak, Suehee;Cynthia, Froning;Marshall, Jennifer;Depoy, Darren L.;Pak, Soojong
    • The Bulletin of The Korean Astronomical Society
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    • v.43 no.1
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    • pp.68.4-69
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    • 2018
  • GMACS is one of the instruments for the Giant Magellan Telescope (GMT) which will provide wide field, multi-object, moderate resolution spectroscopy of faint targets. KHU (Kyung Hee University) is in charge of control software of GMACS. As a first step, the Slit Mask Exchange Mechanism Prototype (SMEM-P) will be used as a preliminary example to make development process between electronics and high level software. Recently, we have developed a sample program to communicate with low level devices via EtherCAT. It is expected to be a mockup design for software and control system of GMACS. In this poster, we show the development process and test operation results of control software for SMEM-P.

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Examination Criteria on the Compliance of Multimodal Transport Document in the ISBP (ISBP상의 복합운송서류의 일치성에 관한 심사기준)

  • Jeon, Soon-Hwan
    • International Commerce and Information Review
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    • v.7 no.4
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    • pp.219-243
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    • 2005
  • The Purpose of this Article is to analyze the examination criteria on the compliance of multimodal transport document in the ISBP. When the goods are taken in charge by the multimodal transport operator, he shall issue a multimodal transport document which, at the option of the consignor, shall be in either negotiable or non-negotiable form. The multimodal transport document shall be signed by the multimodal transport operator or by a person having authority from him. When the multimodal transport document is presented by the beneficiary to the bank in the letter of credit operations, the bank should examinate the bill of exchange and/or shipping documents, including multimodal transport document. There are two rules in connection with examination of the documents in the letter of credit operations. One is the "Uniform Customs and Practice for Documentary Credits(UCP 500)" approved by the Banking Commission in March 10, 1993, the other is the "International Standard Banking Practice for the Examination of Documents under Documentary Letters of Credits(ISBP)" approved by the ICC Banking Commission in October 2002. Therefore, this Article has studied the multimodal transport document presented under documentary credits on the basis of the UCP 500 and the ISBP it reflects.

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Enhanced ICRF Heating of H-mode Plasmas in KSTAR

  • Kim, Sun-Ho;Wang, Son-Jong;Ahn, Chan-Yong;Kim, Sung-Kyew
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.317-317
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    • 2011
  • Enhanced ICRF (Ion Cyclotron Range of Frequency) ion heating of H-mode D(H) plasma will be tried in 2011 KSTAR experimental campaign. Minority heating is a main ion heating scheme in the ICRF. Its efficiency increases as the hydrogen minority ratio increases in deuterium plasmas. And it should be sustained at a lower level than the critical minority ratio. Consequently, it is important to elevate the critical ratio to maximize ion heating and it is possible by increasing the ion temperature or parallel wave number (k${\parallel}$) of the antenna. Increasing the k${\parallel}$ is not a good approach since the coupling efficiency decreases exponentially with regard to k${\parallel}$ as well. So the remaining method is to increase ion temperature by using NB (Neutral Beam). Ion heating fraction of NB increases as the electron temperature increases. Therefore, we will try to heat electron by using ECH together with NB ion heating before ICRF power injection. The ICRF heating efficiency will be compared with respect to several NB+ECH+ICRF heating combinations through several diagnostics such as XICS (Xray Imaging Crystal Spectroscopy), CES (Charge Exchange Spectroscopy) and neutron measurement. The theoretical background and the experimental results will be presented in more detail in the conference.

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Monte Carlo Simulation for Particle Behavior of Recycling Neutrals in a Tokamak Diverter Region

  • Kim, Deok-Kyu;Hong, Sang-Hee;Kihak Im
    • Nuclear Engineering and Technology
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    • v.29 no.6
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    • pp.459-467
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    • 1997
  • The steady-state behavior of recycling neutral atoms in a tokamak edge region has been analyzed through a two-dimensional Monte Carlo simulation. A particle tracking algorithm used in earlier research on the neutral particle transport is applied to this Monte Carlo simulation in order to perform more accurate calculations with the EDGETRAN code which was previously developed for a two-dimensional edge plasma transport in the authors' laboratory. The physical model of neutral recycling includes charge-exchange and ionization interactions between plasmas and neutral atoms. The reflection processes of incident particles on the device wall are described by empirical formulas. Calculations for density, energy, and velocity distributions of neutral deuterium-tritium atoms have been carried out for a medium-sized tokamak with a double-null configuration based on the KT-2 conceptual design. The input plasma parameters such as plasma density, ion and electron temperatures, and ion fluid velocity are provided from the EDGETRAN calculations. As a result of the present numerical analysis, it is noticed that a significant drop of the neutral atom density appears in the region of high plasma density and that the similar distribution of neutral energy to that of plasma ions is present as frequently reported in other studies. Relations between edge plasma conditions and the neutral recycling behavior are discussed from the numerical results obtained herein.

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Use of Inner Ionomer Solution in Preparing Membrane-Electrode Assembly (MEA) for Fuel Cells and Its Characterization

  • Seo, Seok-Jun;Woo, Jung-Je;Yun, Sung-Hyun;Park, Jin-Soo;Moon, Seung-Hyeon
    • Korean Membrane Journal
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    • v.10 no.1
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    • pp.46-52
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    • 2008
  • Optimization of ionomer solution was conducted in order to improve the performance of MEAs in PEMPC. The interface between membrane and electrodes in MEAs is crucial region determining fuel cell performance as well as ORR reaction at cathode. Through the modification of Nafion ionomer content at the interface between membrane and electrodes, an optimal content was obtained with Nafion 115 membranes. Two times higher current density was obtained with the outer Nafion sprayed MEA compared with the non-sprayed one. In addition, the symmetrical impedance spectroscopy mode (SM) exhibited that the resistances of membrane area, proton hydration, and charge transfer decreased as the outer Nafion is sprayed. From the polarization curves and SM, the highest current density and the lowest resistance was obtained at the outer ionomer content of $0.15\;mg\;cm^{-2}$.

A New Maximum Inductive Power Transmission Capacity Tracking Method

  • Ameri, Mohammad Hassan;Varjani, Ali Yazdian;Mohamadian, Mustafa
    • Journal of Power Electronics
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    • v.16 no.6
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    • pp.2202-2211
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    • 2016
  • In certain applications, such as IPT-based EV charger (IPTEC), any variation in alignment and distance between pickup and charger primary leads to a change in leakage and magnetic impedance magnitudes. The power transmission capacity is not always at the maximum level because of these variations. This study proposes a new low-cost tracking method that achieves the Maximum Inductive Power Transmission Capacity (MIPTC). Furthermore, in the proposed method, the exchange of information between load and source is not required. For an application such as IPTEC, the load detected by the IPTEC varies continuously with time because of the change in state of the charge. This load variation causes a significant variation in IPT resonant circuit voltage gain. However, the optimized charging output voltage should be kept constant. From the analysis of the behavior of the IPT circuit at different working frequencies and load conditions, a MIPTC operation point that is independent of load condition can be identified. Finally, the experimental results of a developed prototype IPT circuit test show the performance of the proposed method.

A Pilot Study on a Strategic Development Plan for a National Branch Library (국가도서관 지역분관의 발전전략 모형 연구 - 국립세종도서관을 중심으로 -)

  • Yoon, Hee-Yoon;Chang, Durk Hyun
    • Journal of the Korean Society for Library and Information Science
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    • v.50 no.2
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    • pp.197-213
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    • 2016
  • This study aims at suggesting mid- and long-term development plan (vision, core values, strategic goals and functional performances, major tasks and detailed action plans for each strategy, organizational and human resources management, shared responsibility with the National Library of Korea which is main library in collection and services of policy information, and cooperation and collaborative exchange programs) for the National Library of Korea, Sejong. This study is based on the appropriateness that the library should enhance its visibility through focusing on the role as the specialized library in charge of public policy information services if it wished to ensure the identity of a branch of the National library of Korea for the comprehensive collection, preservation, and nationwide services of public policy information.

Molecular Pharmacological Interaction of Phenylbutazone to Human Neutrophil Elastase

  • Kang, Koo-Il
    • The Korean Journal of Physiology and Pharmacology
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    • v.2 no.3
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    • pp.385-393
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    • 1998
  • Human neutrophil elastase (HNElastase, EC 3.4.21.37), a causative factor of inflammatory diseases, was purified by Ultrogel AcA54 gel filtration and CM-Sephadex ion exchange chromatography. HNElastase was inhibited by phenylbutazone in a concentration dependent manner up to 0.4 mM, but as the concentration increased, the inhibitory effect gradually diminished. Binding of phenylbutazone to the human neutrophil elastase caused strong Raman shifts at 200, 440, and 1194 $cm^{-1}$. The peak at 1194 $cm^{-1}$ might be evidence of the presence $of\;-N=N-{\Phi}$ radical. The core area of the elastase, according to the visual molecular model of human neutrophil elastase, was structurally stable. A deeply situated active center was at the core area surrounded by hydrophobic amino acids. Directly neighboring the active site was one positively charged atom and two atoms carrying a negative charge, which enabled the enzyme and the drug to form a strong interaction. Phenylbutazone may form a binding, similar to a key & lock system to the atoms carrying opposite charges near the active site of the enzyme molecule. Furthermore, the hydrophobicity of the surrounding amino acid near the active site seemed to enhance the binding strength of phenylbutazone. Binding of phenylbutazone near the active site may cause masking of the active site, preventing the substrate from approaching the active site and inhibiting elastase activity.

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