• Title/Summary/Keyword: Charge/discharge test

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A study on the preparation of phthalocyanine optoelectric thin films (프탈로시아닌계 광전도성 유기박막의 제조에 관한 연구)

  • 박구범;조기선;이덕출
    • Electrical & Electronic Materials
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    • v.7 no.5
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    • pp.409-416
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    • 1994
  • A double layered photoreceptor using phthalocyanine dye was made by dip-coating method. The under cutting layer(UCL) was coated with A1$\_$2/O$\_$3/ or polyamide, and the charge generation layer(CGL) was formed by .tau.-type metal-free phthalocyanine. The oxadiazole was used as a charge transport layer(CTL) and polycarbonate and poly(vinyl butyral) was employed as a host polymer. The .tau.-H$\_$2/Pc had an absorption peak around 780nm, which coincided with the emitting wavelengths of GaAlAs diode lasers. Maximum charge acceptance of CTL that gives thickness of 12.mu.m was -900V by corona charge of -6.0kV. In photo-induced discharge measurements, residual potential was less than -20V and sufficient for ordinary use, and sample films using of poly(vinyl butyral) was showed good charge retention. In printing test, drum that was employed polycarbonate as a host polymer showed the good print quality.

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A Basic Study on the Application of Partial Discharge Test on Low-voltage Electrical and Electronic Devices (저압용 전기전자기기에 부분방전시험의 적용을 위한 기초연구)

  • Kil Gyung-Suk;Song Jae-Yong;Moon Seung-Bo;Cha Myung-Soo;Hwang Don-Ha;Kang Dong-Sik
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.6
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    • pp.586-590
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    • 2006
  • This paper deals with the application of a partial discharge (PD) test on low-voltage electrical and electronic devices, which is recently being accepted as a non-destructive and a effective dielectric test method. A comparative analysis combined with the Withstand Voltage Test (WVT) specified in IEC standards was carried out on low-voltage insulation transformers. The results showed that the WVT causes insulation degradation of the specimen during the test by applying high voltage. However, the PD test can be performed in ranges from 30 % to 50 % of the test voltage specified in the WVT. Therefore, the PD test is successfully applicable for a non-destructive test method on low-voltage electrical and electronic devices as a replacement of the WVT.

Synthesis of Silicon-Carbon by Polyaniline Coating and Electrochemical Properties of the Si-C|Li Cell

  • Doh, Chil-Hoon;Kim, Seong Il;Jeong, Ki-Young;Jin, Bong-Soo;An, Kay Hyeok;Min, Byung Chul;Moon, Seong-In;Yun, Mun-Soo
    • Bulletin of the Korean Chemical Society
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    • v.27 no.8
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    • pp.1175-1180
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    • 2006
  • Si-C composites were prepared by the carbonization of polyaniline (PAn) coated on silicone powder. The physical and electrochemical properties of the Si-C composites were characterized by particle-size analysis, X-ray diffraction, scanning electron microscopy, and battery electrochemical tests. The average particle size of Si was increased by the coating of Pan but somewhat reduced by the carbonization to give silicone-carbon composites. The co-existence of crystalline silicone and amorphous-like carbon was confirmed by XRD analyses. SEM photos showed that the silicone particles were well covered with carbonaceous materials, depending on the PAn content. Si-C$\mid$Li cells were fabricated using the Si-C composites and tested using galvanostatic charge-discharge. Si-C$\mid$Li cells gave better electrochemical properties than Si|Li cells. Si-C$\mid$Li cells using Si-C from HCl-undoped precursor PAn showed better electrochemical properties than precursor PAn doped in HCl. The addition of an electrolyte containing 4-fluoroethylene carbonate (FEC) increased the initial discharge capacity. Also, another electrochemical test, the galvanostatic charge-discharge test with GISOC (gradual increasing of the state of charge) was carried out. Si-C(Si:PAn = 50:50 wt. ratio)|Li cell showed 414 mAh/g of reversible specific capacity, 75.7% of IIE (initial intercalation efficiency), 35.4 mAh/g of IICs (surface irreversible specific capacity).

An Experimental Study on the Charging/Discharging Characteristics and Safety of Lithium-Ion Battery System for Submarine Propulsion (잠수함 추진용 리튬이온전지 충방전 특성 및 안전성 확보를 위한 실험적 연구)

  • Kim, Beomseog;Sohn, Seung hyun;Kang, Seokjoong
    • Journal of the Society of Naval Architects of Korea
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    • v.58 no.4
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    • pp.225-233
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    • 2021
  • Conventional submarine propulsion batteries have mainly used lead acid batteries, which have proved relatively safe, but in recent years, research on mounting lithium-ion batteries to improve the underwater operation capability of submarines is underway in advanced countries such as Japan. Korea has world-class technology in the development of electric vehicles and lithium-ion batteries for energy storage, but fire safety accidents continue to occur in electric vehicles and energy storage lithium-ion batteries. In order to mount the lithium-ion battery in a submarine, it is necessary to check the safety as well as whether the performance is improved compared to the lead acid battery. Through the charge/discharge experiment of this lithium-ion battery module unit, it was possible to measure how much performance was improved compared to the lead acid battery. Safety tests were conducted on the lithium-ion battery module assuming that it was mounted on a submarine, and it was confirmed that safety was secured when applied to a submarine. Since many modules are mounted on actual submarines, it has been confirmed that it can be applied to submarine systems by simulating charge/discharge characteristics through Hardware-in-the Loop(HILS). Through the results of this study, the application of lithium-ion batteries to submarines is expected to significantly improve the sustainability of underwater operations.

Performance and Charging-Discharging Behavior of AGM Lead Acid Battery according to the Improvement of Bonding between Active Material/Substrate using Sand-Blasting Method (Sand-Blasting법을 이용한 활물질/기판간 결합력 향상에 따른 AGM 연축전지의 성능 및 충방전 거동)

  • Kim, Sung Joon;Lim, Tae Seop;Kim, Bong-Gu;Son, Jeong Hun;Jung, Yeon Gil
    • Korean Journal of Materials Research
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    • v.31 no.2
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    • pp.75-83
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    • 2021
  • To cope with automobile exhaust gas regulations, ISG (Idling Stop & Go) and charging control systems are applied to HEVs (Hybrid Electric Vehicle) for the purpose of improving fuel economy. These systems require quick charge/discharge performance at high current. To satisfy this characteristic, improvement of the positive electrode plate is studied to improve the charge/discharge process and performance of AGM(Absorbent Glass Mat) lead-acid batteries applied to ISG automotive systems. The bonding between grid and A.M (Active Material) can be improved by applying the Sand-Blasting method to provide roughness to the surface of the positive grid. When the Sand-Blasting method is applied with conditions of ball speed 1,000 rpm and conveyor speed 5 M/min, ideal bonding is achieved between grid and A.M. The positive plate of each condition is applied to the AGM LAB (Absorbent Glass Mat Lead Acid Battery); then, the performance and ISG life characteristics are tested by the vehicle battery test method. In CCA, which evaluates the starting performance at -18 ℃ and 30 ℃ with high current, the advanced AGM LAB improves about 25 %. At 0 ℃ CA (Charge Acceptance), the initial charging current of the advanced AGM LAB increases about 25 %. Improving the bonding between the grid and A.M. by roughening the grid surface improves the flow of current and lowers the resistance, which is considered to have a significant effect on the high current charging/discharging area. In a Standard of Battery Association of Japan (SBA) S0101 test, after 300 A discharge, the voltage of the advanced AGM LAB with the Sand-Blasting method grid was 0.059 V higher than that of untreated grid. As the cycle progresses, the gap widens to 0.13 V at the point of 10,800 cycles. As the bonding between grid and A.M. increases through the Sand Blasting method, the slope of the discharge voltage declines gradually as the cycle progresses, showing excellent battery life characteristics. It is believed that system will exhibit excellent characteristics in the vehicle environment of the ISG system, in which charge/discharge occurs over a short time.

Analysis and Comparison of Switching Losses and Temperature using Si and SiC devices applied in Two Stage AC-DC Converter for Battery Pack Testing System (배터리팩 시험기를 위한 2단 구성 AC-DC 컨버터의 Si와 SiC의 손실 및 온도 비교 분석)

  • Seong, Ho-Jae;Choi, Hyeong-Jun;Hong, Seok-Jin;Hyun, Seung-Wook;Won, Chung-Yuen
    • Proceedings of the KIPE Conference
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    • 2016.07a
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    • pp.397-398
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    • 2016
  • This paper analyzes switching losses, efficiency and temperature depending on Si and SiC devices applied in two stage AC-DC converter. To evaluate the charge and discharge performance and stability of the battery pack, there is a need for a battery pack testing system. To do battery charge and discharge experiment used in battery pack test, A topology, two stage AC-DC converter, has been built. SiC devices more decrease switching losses than that of Si. Also, cooling system was applied in Si and SiC devices. When using SiC devices, it can be confirmed that the size of heat sink is reduced for small loss.

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A Study on the Effect of Pressure upon A.C Partial Discharge in Insulating Oil (제어유의 문류품분효전에 미치는 형력의 영향)

  • Sang-Hoon Kook
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.32 no.7
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    • pp.227-233
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    • 1983
  • Noticing that action of gaseous phase in insulating oil concerns to the discharging characteristics, I investigated the smalness pressure effects on quantity of the partial discharge and discharging pulse frequency. Tests are carried out between the niddle points in insulating oil at pressure being changed by gradual charge of inert gas Ar. At pressure as low as of 0.1-0.5 torr pulse frequency and maximum partial discharge reach peak while at pressure haigher than 20 torr no pulse is observed. The fact that pulse frequency has peak value at certain presure, which is changed either by charging Ar or by adding oil, implies that the action of gaseous phase depends on pressure. Test results are that partial discharge pulse are governed by pressure of Ar-charged oil, and less partial discharge pulses correspond to smaller bubbles whereas more partial descharge pulses correspond to larger bubbles.

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Electrochemical double layer capacitors with PEO and Sri Lankan natural graphite

  • Jayamaha, Bandara;Dissanayake, Malavi A.K.L.;Vignarooban, Kandasamy;Vidanapathirana, Kamal P.;Perera, Kumudu S.
    • Advances in Energy Research
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    • v.5 no.3
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    • pp.219-226
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    • 2017
  • Electrochemical double layer capacitors (EDLCs) have received a tremendous interest due to their suitability for diverse applications. They have been fabricated using different carbon based electrodes including activated carbons, single walled/multi walled carbon nano tubes. But, graphite which is one of the natural resources in Sri Lanka has not been given a considerable attention towards using for EDLCs though it is a famous carbon material. On the other hand, EDLCs are well reported with various liquid electrolytes which are associated with numerous drawbacks. Gel polymer electrolytes (GPE) are well known alternative for liquid electrolytes. In this paper, it is reported about an EDLC fabricated with a nano composite polyethylene oxide based GPE and two Sri Lankan graphite based electrodes. The composition of the GPE was [{(10PEO: $NaClO_4$) molar ratio}: 75wt.% PC] : 5 wt.% $TiO_2$. GPE was prepared using the solvent casting method. Two graphite electrodes were prepared by mixing 85% graphite and 15% polyvinylidenefluoride (PVdF) in acetone and casting n fluorine doped tin oxide glass plates. GPE film was sandwiched in between the two graphite electrodes. A non faradaic charge discharge mechanism was observed from the Cyclic Voltammetry study. GPE was stable in the potential windows from (-0.8 V-0.8 V) to (-1.5 V-1.5 V). By increasing the width of the potential window, single electrode specific capacity increased. Impedance plots confirmed the capacitive behavior at low frequency region. Galvanostatic charge discharge test yielded an average discharge capacity of $0.60Fg^{-1}$.

Electrochemical Characteristics of $LaNi_5$ Electrode Fabricated by Ni and Cu Electroless Plating Techniques (Ni 및 Cu무전해 도금법에 의해 제조한 $LaNi_5$ 전극의 전기화학적 특성)

  • Yi Su Youl;Lee Jae-Bong
    • Journal of the Korean Electrochemical Society
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    • v.3 no.2
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    • pp.121-126
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    • 2000
  • The effect of electroless Ni and Cu plating on $LaNi_5$, $AB_5$ type hydrogen storage alloy was investigated by the various electrochemical techniques such as constant current charge-discharge test, cyclic voltammeoy, and a.c. impedance spectroscopy. Scanning electron microscopy and X-ray diffraction test were conducted for phenomenological logical analyses. Cyclic Voltammetry results show that activation characteristics, cycle life and reaction ,rate were improved through electroless Ni and Cu plating. Compared with bare $LaNi_5$ the charge transfer resistance of electrode was greatly reduced as charge-discharge cycle increases. Therefore, electroless Ni and Cu plating on $LaNi_5$ alloy tends to accelerate the early activation, increasing the cyclic lift of electrode.

Performance Characteristics of Water-Chilling Heat Pump Using CO2 on Variation of Refrigerant Charge Amount (냉매 충전량에 따른 CO2용 수냉식 열펌프의 성능 특성에 관한 연구)

  • Son, Chang-Hyo;Yu, Tae-Guen;Jang, Seong-Il;Oh, Hoo-Kyu
    • Journal of Advanced Marine Engineering and Technology
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    • v.31 no.5
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    • pp.558-566
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    • 2007
  • The performance characteristics of water-chilling heat pump using $CO_2$ with respect to variation of refrigerant charge amount was investigated experimentally. An experimental apparatus is consisted of a compressor, a gas cooler, an expansion valve, an evaporator and a liquid receiver. All heat exchangers used in the test rig are counter-flow-type heat exchangers with concentric dual tubes, which are made of copper. The gas cooler and the evaporator consist of 6 and 4 straight sections respectively arranged in parallel, each has 2400 mm length. The experimental results summarize as the followings : As the refrigerant charge ratio of $CO_2$ heat pump system increases, the discharge pressure and compressor ratio increases, but mass flow rate of refrigerant decreases. Also the compressor work increases with the increase of refrigerant charge ratio. However, the heating and cooling capacity of $CO_2$ heat pump decreases as the refrigerant charge ratio increases. The maximum heating COP of $CO_2$ heat pump system presented at 0.25 refrigerant charge ratio. It is possible to confirm the optimum charge ratio of $CO_2$ heat pump system by the viewpoint of heating COP.