• Title/Summary/Keyword: Changes of state of water

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Development of Constitutive Model for the Prediction of Behaviour of an Unsaturated Clayey Soil (불포화 점성토의 거동예측을 위한 구성식 개발)

  • 송창섭;장병욱
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.38 no.3
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    • pp.101-110
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    • 1996
  • The aim of the work described in this paper is to develope a constitutive model for the prediction of an unsaturated clayey soil and to confirm the application of the model. To this end a series of suction controlled isotropic and triaxial compression tests are conducted on clayey soils. Matric suction is controlled by the axis translation technique using high air entry ceramic disk. Total volume change, air and water volume changes are measured by the device made for the experiment. The specimens are compacted by dynamic compaction using a half of Proctor compaction energy with the water contents of 5% drier than the optimum moisture contents. From test results, volume changes and deviator stresses are analyzed at each state and their relationships are formulated. And the application of the model to clayey soils is confirmed by the comparison between test and predicted results. During drying-wetting and loading-unloading processes for isotropic states, the agreement between predicted and test results are satisfactory. And predicted deviator stresses are well agreed with the test results in shearing process, but volumetric strain is not well agreed with the test results in high suctions.

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Effects of Surface Charges on Hydrophobicity and Surface Potential Decay with Various Surface States of Silicone Rubber for Outdoor Insulator (옥외용 실리콘 절연재료의 발수성에 미치는 표면전하의 영향과 표면 상태에 따른 표면전위 감쇠)

  • 연복희;박충렬;허창수
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.8
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    • pp.678-686
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    • 2002
  • This paper presents the effects of accumulation of surface charges on hydrophobic level and the changes of surface potential decay with various artificial environment treatments on high temperature vulcanized (HTV) silicone rubber used for outdoor insulating material. For this study, the charging apparatus by corona discharge, in which grid electrode was installed between the main corona and ground electrode, was used. From this study, it was found that the accumulation of surface charges above a critical surface potential on silicone insulating materials could lead to the temporary loss of surface hydrophobicity. In addition, corona stress and water absorption stress increase the decay rate of surface charges of HTV silicone rubber, while ultraviolet (UV) stress causes longer decay time. We could conclude that the effects of surface charges on hydrophobicity level and the changes of surface state by various artificial treatments were found through a trend of surface potential decay.

Preliminary Diagnosis for Pulsing Simulation of Low Trophic Ecosystem by Environmental Changes in Coastal Area (연안해역의 환경변화에 따른 저차 생태계 Pulsing Simulation 예비 진단)

  • Lee, Dae-In
    • Journal of Environmental Impact Assessment
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    • v.21 no.3
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    • pp.461-468
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    • 2012
  • In general, long-term changes of ecological factors take a pulse form in which they interact with other factors and go through a repeated increasing and decreasing cycle. The coupling of the two approaches the grid model and the box model in ecological modeling can lead to an in-depth understanding of the environment. The study analyzes temporal variations of major storages with an energy system model that formulizes effectively the relationships among nutrients, phytoplankton, and zooplankton in the Yellow Sea and the East China Sea. An increase of light intensity and standing stock of nutrient increase the magnitude and frequency of pulsing. Also, an immense reduction of nutrient concentration can cause extinction of the pulsing and bring about a steady state. It is concluded that the nutrient loads in freshwater discharge from the Yangtze affect the cycles of major ecological components as well as water quality variables and play an important role in the marine ecosystem.

Environmental and Socioeconomic Determinants of Grain Virtual Water Trade: An Empirical Analysis using Decomposition and Decoupling Model

  • Golden Odey;Bashir Adelodun;Seulgi Lee;Kyung Sook Choi
    • Proceedings of the Korea Water Resources Association Conference
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    • 2023.05a
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    • pp.394-394
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    • 2023
  • The world's sustainable growth is being severely hampered by the inefficient use of water resources. Despite the widely acknowledged importance of trade in global and regional water and food security, societal reliance on local production as well as international trade remains inadequately assessed. Therefore, using South Korea as a case study, this study fills in this research gap by applying the virtual water concept, the logarithmic mean divisia index (LMDI) method, and the Tapio decoupling model. The virtual water concept was used to estimate South Korea's net virtual water trade for major grain crops from 1992 to 2017. Then, the LMDI method was utilized to assess the driving factors causing changes in net virtual water trade. Lastly, the Tapio decoupling model was used to investigate the decoupling relationships between economic growth and the driving factors of net virtual water trade. Results showed that South Korea remains a net importer of virtual water flows with respect to grain crops, with an average import of 16,559.24 million m3 over the study period. In addition, the change in net virtual water trade could be attributed to water intensity effect, product structure effect, economic effect, and population effect. However, water intensity and economic effects were the major decisive factors for decrease and increase in net virtual water trade respectively, while the population and product structure effects had minor positive influences on the net virtual water trade. Furthermore, water intensity and economic growth showed a strong decoupling in most periods, while the decoupling state between product structure and economic growth was observed as expansive negative decoupling. Likewise, population size and economic growth showed a weak decoupling in most periods. The results reveal South Korea's status as it concerns the virtual water trade of grain crops, thus providing valuable insights into the sustainability of trade activities for the management of local water resources.

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Effects of Temperature on Flocculation Kinetics Using Fe(III) Coagulant in Water Treatment (정수처리시 Fe(III) 응집제를 사용한 응집동력학에 대한 온도의 영향)

  • 강임석
    • Journal of Environmental Science International
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    • v.4 no.2
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    • pp.181-194
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    • 1995
  • Flocculation kinetics using ferric nitrate as a coagulant to coagulate kaolin clay in water was examined as a tool to investigate the effect of low temperature under tightly controlled treatment conditions. Both the particle size distribution data obtained from Automatic Image Analysis (AIA) system and the on-line measurement of the degree of turbidity fluctuation in a flowing suspension by Photometric Dispersion Analyzer (PDA) were used to measure flocculation kinetics. Results show that cold water temperature had a pronounced detrimental effect on flocculation kinetics. For improving flocculation kinetics at low water temperature, maintaining constant pOH to adjust water chemistry for temperature changes was found to be partially effective only in the more acidic pH range studied.

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Dynamic Analysis of Structure-Fluid-Soil Interaction Problem of a Bridge Subjected to Seismic-Load Using Finite Element Method (유한요소법을 이용한 지진하중을 받는 교량의 구조물-유체-지반 동적 상호작용해석)

  • You, Hee-Yong;Park, Young-Tack;Lee, Jae-Young
    • Journal of The Korean Society of Agricultural Engineers
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    • v.50 no.4
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    • pp.67-75
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    • 2008
  • In construction facilities such as bridges, the fluid boundary layer(or water film) is formed at the structure-soil interface by the inflow into the system due to rainfall or/and rising ground-water. As a result, the structure-soil interaction(SSI) state changes into the structure-fluid-soil interaction(SFSI) state. In general, construction facilities may be endangered by the inflow of water into the soil foundation. Thus, it is important to predict the dynamic SFSI responses accurately so that the facilities may be properly designed against such dangers. It is desired to have the robust tools of attaining such a purpose. However, there has not been any report of a method for the SFSI analyses. The objective of this study is to propose an efficient method of finite element modelling using the new interface element named hybrid interface element capable of giving reasonable predictions of the dynamic SFSI response. This element enables the simulation of the limited normal tensile resistance and the tangential hydro-plane behaviour, which has not been preceded in the previous studies. The hybrid interface element was tested numerically for its validity and employed in the analysis of SFSI responses of the continuous bridge subjected to seismic load under rainfall or/and rising ground-water condition. It showed that dynamic responses of the continuous bridge resting on direct foundation may be amplified under rainfall condition and consequently lead to significant variation of stresses.

Enhancement of Hydroxylamine Reactivity of Bacteriorhodopsin at High Temperature

  • Sonoyama, Masashi;Mitaku, Shigeki
    • Journal of Photoscience
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    • v.9 no.2
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    • pp.299-301
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    • 2002
  • Recent denaturation experiments of bacteriorhodopsin (bR) in the dark and under illumination at high temperatures revealed that irreversible thermal bleaching occurs above ~ 70°C and the preceding reversible structural changes in the dark above 60°C are closely related to irreversible photobleaching observed in the same temperature range (Yokoyama et al. (2002). J Biochem. 131,785). In this study, structural properties of bacteriorhodopsin (bR) at high temperatures were extensively probed by hydroxylamine reactivity with the Schiff base in the dark and hydrogen-deuterium (H-D) exchange in the peptide groups. In the Arrhenius plot from kinetics measurements of the hydroxylamine reaction, a good linear relationship between the reaction time constant and the inverse of the absolute temperature was observed below 60°C, while significant increase started above 60°C, suggesting that remarkable increase in water accessibility of the Schiff base in the temperature region. FT-IR spectroscopic studies on the H-D exchange suggested increase in the deuterium exchanges rate of the peptide hydrogen in the same temperature region.

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Measurement of the displacement current using Kuhn-type LB film apparatus (Kuhn형 LB막 누적장치에서의 변위전류 측정)

  • Song, K.H.;Park, T.G.;Park, K.H.;Kwon, Y.S.;Kang, D.Y.
    • Proceedings of the KIEE Conference
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    • 1993.07b
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    • pp.1200-1202
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    • 1993
  • There are many methods to investigate the physical properties of monolayers formed at the air-water interface. Among them, the displacement current method is appropriate for the investigation of the dynamic behavior of monolayers. The measuring system of displacement current method was constructed at home-made Kuhn type LB deposition apparatus using aluminium plate electrode. The currents induced by the dynamic motion of molecules were measured when the molecules were pressed by barrier. To verify the measuring system, we used 4-octyl -4'-(5-carboxy-pentamethyleneoxy)-azobenzene molecules which has two remarkable variations of surface pressure of monolayer at the air-water interface. We can detect the two peaks of displacement currents which shows that the orientations of molecules are changed greatly at the state of these two remarkable changes of surface pressure.

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A Comparative Study on the Bio-kinetics of Suspended Sludge and Attached Sludge (막미생물과 부유미생물의 kinetics 비교 연구)

  • Lee, Jeoung Su;Lee, Tae Kyoo
    • Journal of Korean Society of Water and Wastewater
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    • v.12 no.4
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    • pp.59-69
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    • 1998
  • Biological treatment systems generally can be divided into two main classes of a suspended sludge process and attached one like a fluidized bed reactor. These process are considered to bring remarkable change in species composition of microorganisms, due to difference of a state of biofilm, a concentration and diffusion velocity of dissolved oxygen, a concentration and diffusion velocity of substance or poisonous matter. The change of species composition bring different treatment result for influence factors like F/M ratio, DO concentration, pH or poisonous matter. This study is to investigate the reaction characteristics of both microorganisms, namely, a suspended sludge and attached sludge, through the changes of pH, temperature and substance concentration.

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The influence of marine algae on iodine speciation in the coastal ocean

  • Carrano, Mary W.;Yarimizu, Kyoko;Gonzales, Jennifer L.;Cruz-Lopez, Ricardo;Edwards, Matthew S.;Tymon, Teresa M.;Kupper, Frithjof C.;Carrano, Carl J.
    • ALGAE
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    • v.35 no.2
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    • pp.167-176
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    • 2020
  • Iodine exists as a trace element in seawater, with total iodine being generally constant at about 0.45-0.55 μM. Almost all of this iodine occurs in two main forms: iodate and iodide. Iodate is the thermodynamically stable form under normal seawater conditions, and thus should be the only iodine-containing species in the water column. However, iodate concentrations are found to vary considerably, being generally greater at depth and lower at the surface, while iodide concentrations follow the reverse pattern, being anomalously accumulated in the euphotic zone and decreasing with depth. The fact that iodide concentrations follow a depth dependence corresponding to the euphotic zone suggests that biological activity is the source of the reduced iodine. Nonetheless, the nature and source of iodate reduction activity remains controversial. Here, using a combination of field and laboratory studies, we examine some of the questions raised in our and other previous studies, and seek further correlations between changes in iodine speciation and the presence of marine macro- and microalgae. The present results indicate that microalgal growth per se does not seem to be responsible for the reduction of iodate to iodide. However, there is some support for the hypothesis that iodate reduction can occur due to release of cellular reducing agents that accompany cell senescence during phytoplankton bloom declines. In addition, support is given to the concept that macroalgal species such as giant kelp (Macrocystis pyrifera) can take up both iodide and iodate from seawater (albeit on a slower time scale). We propose a mechanism whereby iodate is reduced to iodide at the cell surface by cell surface reductases and is taken up directly as such without reentering the bulk solution.