• Title/Summary/Keyword: Changes of state of water

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Preparation and Characterization of Polypyrrole Electroactive Actuators (Polypyrrole를 이용한 전기활성 구동기의 제조 및 특성)

  • 박정태;최혁렬;김훈모;전재욱;남재도
    • Polymer(Korea)
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    • v.25 no.6
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    • pp.826-832
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    • 2001
  • In this study, PPy/gold/mylar type electroactive bi-layer actuator was prepared by the electrochemical polymerization of pyrrole onto the gold/mylar film and the actuation characteristics were studied using bending beam method. Conducting polymer-based actuators undergo volumetric changes due to the movement of dopant ions into the film during the electrical oxidation process. The bilayer films exhibited different actuation characteristics depending on dopant ion size. It was observed that the relatively small dopant ion (i.e. toluene sulfonate) moved into the PPy film at oxidized state, so volume expanded to result in bending motion. In case of the film having large dopant ion (i.e. dodecylbenzenesulfonate), volume expansion was observed at reduced state. This is due to the incorporation of $Na^+$ counterion with water molecules, while the large dopant ion was fixed in the film due to the limited mobility during tile redox process.

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The Concept of the Future and the New Paradigm of the Fifth Spiral: State, Business, Science, Society and Informatization

  • Sabden, Orazaly
    • The Journal of Asian Finance, Economics and Business
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    • v.5 no.4
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    • pp.173-185
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    • 2018
  • At a turn of the third millennium the world storms and quickly changes. It became difficult to expect what expects us tomorrow. The most important are questions of recovery from the crisis and rescue of mankind from forthcoming global changes: warming of climate, water and food problems, social, economic and political conflicts that are shaking the world and other various cataclysms, accidents, negative processes. It puts before mankind the problem which never solved by our civilization. All this is caused by ignoring of objective economic laws, laws of wildlife and also by violation of cyclic development management's laws. In article the concept of strategy of mankind's survival in XXI and next centuries, the principles of creation of planetary house of universal civilization for post-industrial world based on spirituality scientific and technological revolutions, ecology, space exploration, economy and world safety are considered. Introduction of uniform universal measurement of currency for the whole world in the form of "power" is offered. Important aspect of a research is theoretical postulate on integrated innovative society. The author puts forward a new paradigm of government on a basis of 5 spirals. The basic model of forced development of small and medium business, including 9 projects, is developed.

Postmortem Changes in Muscle of Sea Water Acclimated Tilapia, Oreochromis niloticus (해수순치한 틸라피아 근육의 사후변화)

  • Yoon Ho-Dong;KIM Tae-Jin;KIM Seong-Jun;LEE Jong-Ho
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.29 no.3
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    • pp.279-286
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    • 1996
  • Cultivated tilapia (Oreochromis niloticus) in the fresh water were acclimated to the sea water to improve palatability of the fish meat. Physicochemical properties in the rigor mortis of those fish meats were investigated during storage at $0^{\circ}C,\;10^{\circ}C\;and\;20^{\circ}C$. The faster onset of rigor mortis was occurred in acclimated meat than fresh water cultivated meat. Both meats stored at $0^{\circ}C$ showed faster figro mortis than at $10^{\circ}C\;and\;20^{\circ}C$. Significant difference was not observed between the breaking strength and the rigor index. The breaking strength reached maximum over 12hrs after death and then gradually declined, and the rigor index was slowly increased and reached maximum over 18hrs after postmortem. Low temperature and acclimation to the sea water affected the degradation of adenosine triphosphate (ATP), accumulation of inosine monophosphate (IMP) or lactate. These results suggest that the palatability of tilapia muscle cultivated in the fresh water could be improved by acclimation to the sea water which induces the prerigor at the early state of postmortem and the physical changes of fish muscle.

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Comparison of Toxic Effects of Mercury, Copper and Zinc on Photosystem II of Barley Cholroplasts (보리 엽록체의 광계 II에서 수은, 구리 및 아연의 저해효과 비교)

  • 전현식
    • Journal of Plant Biology
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    • v.36 no.3
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    • pp.195-201
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    • 1993
  • The room temperature fluorescence induction of chloroplasts was utilized as a probe to locate the site of inhibition by mercury, copper and zinc on PS II by mercury. Inhibitory effect of Hg2+ on electron transport activity was notable as compared with Cu2+ and Zn2+. At concentrations of HgCl2 over 50 $\mu$M, activities of PS II and whole-chain electron transport decreased more than 70%, while that of PS I decreased about 10~30%. This suggests that PS II is more susceptible to Hg2+ than PS I is. In the presence of diphenylcarbazide (DPC), 50 $\mu$M HgCl2 inhibited the reduction of dichlorophenolindophenol (DCPIP) about 50%. Addition of heavy metals induced marked decrease in maximal variable fluorescence/initial fluorescence [(Fv)m/Fo], but no changes in Fo. With various concentrations of heavy metals, changes of chlorophyll a fluorescence emitted by PS II showed gradual decrease in photochemical quenching (qQ), which indicates an increase in reduced state of electron acceptor, QA. Especially, the addition of HgCl2 caused a notable decrease of qQ. In the presence of 50 $\mu$M CuCl2, energy-depended quenching (qE) was completely reduced, whereas in the presence of 50 $\mu$M CuCl2 and ZnCl2 it was still remained. The above results are discussed on the effects of mercury in relation to water-splitting system and plastoquinone (PQ) shuttle system.

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THE CASPIAN SEA LEVEL, DYNAMICS, WIND, WAVES AND UPLIFT OF THE EARTH'S CRUST DERIVED FROM SATELLITE ALTIMETRY

  • Lebedev, S.A.;Kostianoy, A.G.
    • Proceedings of the KSRS Conference
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    • v.2
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    • pp.973-976
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    • 2006
  • The oscillations of the Caspian Sea level represent a result of mutually related hydrometeorological processes. The change in the tendency of the mean sea level variations that occurred in the middle 1970s, when the long-term level fall was replaced by its rapid and significant rise, represents an important indicator of the changes in the natural regime of the Caspian Sea. Therefore, sea level monitoring and long-term forecast of the sea level changes represent an extremely important task. The aim of this presentation is to show the experience of application of satellite altimetry methods to the investigation of seasonal and interannual variability of the sea level, wind speed and wave height, water dynamics, as well as of uplift of the Earth’s crust in different parts of the Caspian Sea and Kara-Bogaz-Gol Bay. Special attention is given to estimates of the Volga River runoff derived from satellite altimetry data. The work is based on the 1992-2005 TOPEX/Poseidon (T/P) and Jason-1 (J-1) data sets.

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The Study of Thermal Decomposition of Polyacids by Differential Thermal Analysis: Ammonium Paratungstate (示差熱分析에 依한 Poly 酸의 熱分析의 硏究)

  • YungPil Ahn
    • Journal of the Korean Chemical Society
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    • v.7 no.1
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    • pp.1-5
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    • 1963
  • The thermal decomposition process of ammonium paratungstate $5(NH_4)_2O{\cdot}12WO_3{\cdot}5H_2O$ was analysed by the methods of thermogravimetric analysis, differential thermal analysis, quantitative analysis of the ammonia which is released during heating and X-ray powder diffraction in air and in vacuo. There are several endothermic peaks which indicate release of ammonia and exothermic peaks which indicate crystal growth and oxidation of decomposed prodects in air. After water is driven off the ammonia is released at intervals corresponding to the endothermic peaks. The highest temperature at which ammonia is released is about $420^{\circ}C$ in air and $480^{\circ}C$ in vacuo. In air the crystal structure of paratungstate is conserved up to a temperature of $300^{\circ}C$ at which the remaining ammonia is about 4 mols. At $320^{\circ}C$ the remaining ammonia becomes less than 2 mols and the paratungstate structure changes into the amorphous state. After that ${\gamma}$ oxide is produced and is oxidized to ${\alpha}$ oxide in the temperature range of 400-$500^{\circ}C$ in air. In vacuo however the endothermic peaks and structural changes occur at lower temperatures and the structure of ${\gamma}$ oxide is conserved up to temperatures higher than $500^{\circ}C$.

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Simulation of Circulation and Water Qualities on a Partly Opened Estuarine Lake Through Sluice Gate (배수갑문을 통해 부분 개방된 하구호에서의 순환과 수질모의)

  • 서승원;김정훈;유시흥
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.14 no.2
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    • pp.136-150
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    • 2002
  • To improve the water quality of the recently constructed Siwhaho, sluice gates were operated to allow free exchange of water with the sea. This estuarine lake connected to the outer sea through narrow gates is affected mainly by flushing by gate operation and river flows and wind forcing sometimes. As a predicting tool far the water qualities, a three-dimensional finite volume model CE-QUAL-ICM is incorporated into a finite element hydrodynamic model, TIDE3D. In coupling these two different modules, a new error minimization technique is applied by considering conservation of mass. Model tests for one year after calibration and validation using field observation show that eutrophication and other biological changes reach quasi-steady state after initial 60 days of simulation, thus it would be necessary to consider moderate ramp up option to remove initial uncertainties due to cold start option. Sediment-water interaction might not be a concern in the long-term simulation, since its effect is negligible. Simulated results show the newly applied scheme can be applied with satisfaction not only fur lessening of eutrophic processes in an estuarine lake but also looking for some active circulation to improve water quality.

A Role of Central NELL2 in the Regulation of Feeding Behavior in Rats

  • Jeong, Jin Kwon;Kim, Jae Geun;Kim, Han Rae;Lee, Tae Hwan;Park, Jeong Woo;Lee, Byung Ju
    • Molecules and Cells
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    • v.40 no.3
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    • pp.186-194
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    • 2017
  • A brain-enriched secreting signal peptide, NELL2, has been suggested to play multiple roles in the development, survival, and activity of neurons in mammal. We investigated here a possible involvement of central NELL2 in regulating feeding behavior and metabolism. In situ hybridization and an immunohistochemical approach were used to determine expression of NELL2 as well as its colocalization with proopiomelanocortin (POMC) and neuropeptide Y (NPY) in the rat hypothalamus. To investigate the effect of NELL2 on feeding behavior, 2 nmole of antisense NELL2 oligodeoxynucleotide was administered into the lateral ventricle of adult male rat brains for 6 consecutive days, and changes in daily body weight, food, and water intake were monitored. Metabolic state-dependent NELL2 expression in the hypothalamus was tested in vivo using a fasting model. NELL2 was noticeably expressed in the hypothalamic nuclei controlling feeding behavior. Furthermore, all arcuatic POMC and NPY positive neurons produced NELL2. The NELL2 gene expression in the hypothalamus was up-regulated by fasting. However, NELL2 did not affect POMC and NPY gene expression in the hypothalamus. A blockade of NELL2 production in the hypothalamus led to a reduction in daily food intake, followed by a loss in body weight without a change in daily water intake in normal diet condition. NELL2 did not affect short-term hunger dependent appetite behavior. Our data suggests that hypothalamic NELL2 is associated with appetite behavior, and thus central NELL2 could be a new therapeutic target for obesity.

Study on effects and strategies of Korean tuna purse seine fishery affected by conservation management measures of Western and Central Pacific Fisheries Commission (중서부태평양수산위원회 보존관리조치가 우리나라 다랑어선망어업에 미친 영향과 향후 대응 방안)

  • LEE, Mi-Kyung;LEE, Sung-Il;LEE, Chun-Woo;KIM, Doo-Nam;KU, Jeong-Eun
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.52 no.3
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    • pp.197-208
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    • 2016
  • The WCPFC CMMs related to tropical tunas have been strongly restricting fishing capacity and operating activities of main fisheries, especially purse seine fishery. In terms of changes in fishing trend by implementing relevant measures of FAD set, the number of FAD set by Korean purse seine fleet showed a decreasing pattern with the lowest level of FAD set proportion among major distant water fishing nations. With regards to the FAD closure, there was no significant change in fishing effort but a drop in catch, especially bigeye tuna during the period of FAD closure. Moreover, it showed closely similar trends between the number of FAD set and bigeye tuna catch. In terms of measures related to the high sea area including a ban on fishing on the HSP and limitation of fishing days on the high sea by flag state, proportions of catch and effort on the high sea had sharply declined after implementing those measures. As relevant measures are expected to be strengthened, it should pay attention to change of coastal nations policies and focus on improving fishing efficiency of unassociated school set with multi-pronged efforts.

Submarine Environmental Characteristics of Porewater around Deok-Jeok Island, Yellow Sea (황해 덕적도 주변 해양 공극수의 환경특성)

  • 한명우;박용철
    • Journal of Environmental Science International
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    • v.1 no.1
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    • pp.77-88
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    • 1992
  • Distribution patterns of the chemical species, contained or dissolved in the sediments and porewater, were studied from the submarine environments around Deok-Jeok Island, Yellow Sea. The sediments in the study area are predominantly composed of medium to coarse sands, and consequently of very low organic carbon (0.003%) -0.26%o dry weight sediments). As opposed to the strong enrichment of porewater with nutrients and heavy metals in the ordinarily muddy, organic-rich sediillents, the porewater enrichment is not intense in this sandy, organic-poor sediments: porewater phosphate is enriched to the maximum of only seven (average two) times over that in the bottom water. Concentrations of the heavy metals dissolved in porewater show a bit greater enrichment than the nutrient: Zn shows the lowest enrichment (7 times that of the bottom water) and Mn the highest (450 times that of the bottom water). However, these enrichments of the chemical species in porewater are the natural consequences of decomposition of the organic matter in sediments, and still fall short in the magnitude of those in the muddy, organic-rich sediments. Mining of the sands in the study area may pose a threat to the seawater quality as it causes a large scale porewater discharge to the bottom water. The additional supply of the nutrients by this discharge may develop an eutrophic state and, in consequence, an excessive nitrification of the water column. Since the residence times of the nutrients are much longer than those of the heavy metals, a long-term monitoring of the concentration changes in the porewater nutrients is very important to assess the potential deterioration of the seawater associated with the sand mining in the study area.

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